High performance electrolyte for the vanadium redox flow battery. Vanadium batteries present a highly-scalable, sustainable solution for storage of renewable electricity, but the technology needs to be improved for robust and efficient operation in the warm Australian climate. This project aims to design and extensively test new high-performance electrolyte compositions with advanced thermal stabilising additives for safe long-term battery operation at 60 °C. New knowledge in materials science a ....High performance electrolyte for the vanadium redox flow battery. Vanadium batteries present a highly-scalable, sustainable solution for storage of renewable electricity, but the technology needs to be improved for robust and efficient operation in the warm Australian climate. This project aims to design and extensively test new high-performance electrolyte compositions with advanced thermal stabilising additives for safe long-term battery operation at 60 °C. New knowledge in materials science and electrochemistry will be generated. The core outcome of the project is a sustainable large-scale energy storage technology ready for immediate application in Australia. This will support the transition of the Australian energy sector to renewables and provide businesses with distributed energy storage solutions.Read moreRead less
Early Career Industry Fellowships - Grant ID: IE230100468
Funder
Australian Research Council
Funding Amount
$450,000.00
Summary
Scalable high-performance electrolytic hydrogen generator. The project aims to demonstrate energy-efficient generation of compressed hydrogen by water electrolysis in a high pressure electrolyser test-rig produced by Melbourne company Energys Australia P/L, using high-performance membrane-electrode assemblies. Innovative electrode architectures, membranes, and method for their high through-put lamination will be developed. New knowledge in catalysis, device fabrication and materials science is e ....Scalable high-performance electrolytic hydrogen generator. The project aims to demonstrate energy-efficient generation of compressed hydrogen by water electrolysis in a high pressure electrolyser test-rig produced by Melbourne company Energys Australia P/L, using high-performance membrane-electrode assemblies. Innovative electrode architectures, membranes, and method for their high through-put lamination will be developed. New knowledge in catalysis, device fabrication and materials science is expected to be generated. The major project outcome is sustainable method for generation of compressed hydrogen at significantly reduced cost as compared to the existing technologies. Benefits include industry-ready processes for electrolyser and hydrogen production that support Australian energy industries.Read moreRead less
Atmospheric Photothermal Oxidation as a New Reaction in the Atmosphere. Atmospheric models provide crucial advice on the current and future impacts of human activity on the atmosphere. This project hypothesizes the presence of a new class of chemical reactions that are unknown in atmospheric science and therefore missing from the best existing models. The reactions require both sunlight and air, and they behave differently to all other types of atmospheric reactions. This project aims to charact ....Atmospheric Photothermal Oxidation as a New Reaction in the Atmosphere. Atmospheric models provide crucial advice on the current and future impacts of human activity on the atmosphere. This project hypothesizes the presence of a new class of chemical reactions that are unknown in atmospheric science and therefore missing from the best existing models. The reactions require both sunlight and air, and they behave differently to all other types of atmospheric reactions. This project aims to characterise these reactions in the lab, understand them with theory, and quantify their global impact through modelling. Expected benefits include new understanding of atmospheric chemistry, more accurate model predictions, and—as a result—better strategies for managing the impacts of human activity on the environment.Read moreRead less
Reactivity and photochemistry of halide anions: atmospheric implications. Bromine and iodine are suspected to be responsible for most of the halogen-induced ozone loss in the stratosphere but are not currently included in atmospheric models due to a paucity of knowledge of the gas-phase chemistry and photochemistry of their anions and radicals. This project will develop and deploy advanced mass spectrometry and laser spectroscopy techniques to enable precision measurements of the reactions and p ....Reactivity and photochemistry of halide anions: atmospheric implications. Bromine and iodine are suspected to be responsible for most of the halogen-induced ozone loss in the stratosphere but are not currently included in atmospheric models due to a paucity of knowledge of the gas-phase chemistry and photochemistry of their anions and radicals. This project will develop and deploy advanced mass spectrometry and laser spectroscopy techniques to enable precision measurements of the reactions and photo-reactions of gas-phase iodide and bromide anions and their oxides. These state-of-the-art measurements of reaction kinetics and products will enable accurate chemical models that predict the impact of bromine and iodine chemistry on ozone levels and will inform future models for global climate.Read moreRead less
High-productivity ammonia electrosynthesis. The aim of this project is to develop and demonstrate high-performance devices for ammonia production from renewables by a scalable electrolysis method. This will be achieved by experimental and modelling investigations of the nitrogen reduction reaction to guide the design of tailor-made cathodes. New knowledge in catalysis and materials science is expected to be generated. The target outcome of the project is a sustainable and affordable ammonia synt ....High-productivity ammonia electrosynthesis. The aim of this project is to develop and demonstrate high-performance devices for ammonia production from renewables by a scalable electrolysis method. This will be achieved by experimental and modelling investigations of the nitrogen reduction reaction to guide the design of tailor-made cathodes. New knowledge in catalysis and materials science is expected to be generated. The target outcome of the project is a sustainable and affordable ammonia synthesis method as an alternative to the current fossil-fuels-based and excessively greenhouse-emitting process. The technology to be developed in this project is anticipated to be of significant benefit to the Australian agriculture sector as a local, on-demand source of low-cost fertilisers.Read moreRead less
Early Career Industry Fellowships - Grant ID: IE230100449
Funder
Australian Research Council
Funding Amount
$453,000.00
Summary
High-performance ammonia electrosynthesis devices. The project aims to develop a robust process for electrosynthesis of ammonia using devices manufactured by Melbourne company Jupiter Ionics P/L and innovative electrolyte components. Towards this aim, tailored ion-shuttling compounds need to be designed and investigated to enable continuous generation of ammonia in scaled-up flow devices. This is expected to generate new knowledge in practical electrochemistry, catalysis and sustainable synthesi ....High-performance ammonia electrosynthesis devices. The project aims to develop a robust process for electrosynthesis of ammonia using devices manufactured by Melbourne company Jupiter Ionics P/L and innovative electrolyte components. Towards this aim, tailored ion-shuttling compounds need to be designed and investigated to enable continuous generation of ammonia in scaled-up flow devices. This is expected to generate new knowledge in practical electrochemistry, catalysis and sustainable synthesis. Key project outcome is a technology for production of ammonia from renewables that is pollution-free and highly scalable in contrast to the current process. Resulting benefit to Australian agriculture businesses is a method for distributed fertiliser generation without the use of fossil fuels.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE200100549
Funder
Australian Research Council
Funding Amount
$384,616.00
Summary
The true impact of fluorinated compounds in the atmosphere. This project aims to improve the underpinning science that is incorporated into atmospheric chemistry models so humanity can better understand, predict and respond to the impact of emitting large volumes of fluorinated compounds. This project expects to challenge assumptions currently used to model the atmospheric chemistry of organic fluorine compounds, as well as to evaluate the environmental impact of replacements. Expected outcomes ....The true impact of fluorinated compounds in the atmosphere. This project aims to improve the underpinning science that is incorporated into atmospheric chemistry models so humanity can better understand, predict and respond to the impact of emitting large volumes of fluorinated compounds. This project expects to challenge assumptions currently used to model the atmospheric chemistry of organic fluorine compounds, as well as to evaluate the environmental impact of replacements. Expected outcomes include a general model of organic fluorine photochemistry and refined atmospheric chemistry models. This should provide significant benefits in that humanity can avoid an environmental disaster and new, environmentally benign products can be developed.Read moreRead less
Sustainable Reversible Polymerisation. This project aims to address the problem of the current lack of efficient chemical recyclability of polymers. For the majority of polymers, no methods exist so far that are scalable and economic at the same time. To reach this aim, we will utilise a mixture of clever chemical concepts with continuous flow engineering. This project expects to generate new knowledge in the area of depolymerisation and chemical recycling methods. The expected outcome of this p ....Sustainable Reversible Polymerisation. This project aims to address the problem of the current lack of efficient chemical recyclability of polymers. For the majority of polymers, no methods exist so far that are scalable and economic at the same time. To reach this aim, we will utilise a mixture of clever chemical concepts with continuous flow engineering. This project expects to generate new knowledge in the area of depolymerisation and chemical recycling methods. The expected outcome of this project is a scalable process and its practical demonstration for full chemical recycling of various polymers used in everyday applications. This will provide a benefit to society as it allows to tackle plastic pollution problems, and creates avenues to green methods in plastic recycling.
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The long-term impact of short-lived, fluorinated pollutants. In 1987, the Montreal Protocol has regulated the manufacture and use of compounds that deplete the ozone layer. Industry has innovated to produce new compounds that do not affect ozone levels, for use in refrigeration and other applications for modern society. We have discovered that the current generation of compounds called hydrofluoroolefins decompose in the atmosphere to produce the worst global warming gas known. We hypothesise th ....The long-term impact of short-lived, fluorinated pollutants. In 1987, the Montreal Protocol has regulated the manufacture and use of compounds that deplete the ozone layer. Industry has innovated to produce new compounds that do not affect ozone levels, for use in refrigeration and other applications for modern society. We have discovered that the current generation of compounds called hydrofluoroolefins decompose in the atmosphere to produce the worst global warming gas known. We hypothesise that other HFOs will also decay into global warming compounds. In this project we will determine the atmospheric consequences of modern refrigerants. Expected benefits include determination the best and worst compounds for environmental impact, and data to guide industry and legislators.Read moreRead less