Reverse engineering nature: metal extraction through mineral replacement. This project aims to find new methods of copper recovery from low grade copper ores, which are currently uneconomic to mine. In nature, at the top of ore deposits and just below the water-table, is a region known as the supergene zone. Here mild oxidizing reactions take place causing primary ore minerals such as chalcopyrite to be replaced by more copper-rich, less refractory minerals. These processes are driven by disso ....Reverse engineering nature: metal extraction through mineral replacement. This project aims to find new methods of copper recovery from low grade copper ores, which are currently uneconomic to mine. In nature, at the top of ore deposits and just below the water-table, is a region known as the supergene zone. Here mild oxidizing reactions take place causing primary ore minerals such as chalcopyrite to be replaced by more copper-rich, less refractory minerals. These processes are driven by dissolution re-precipitation reactions (CDR reactions) and in many CDR reactions, the reaction mechanism, rather than intensive properties such as pressure and temperature, control the nature of the products and the overall reaction process. This project will explore the mechanism and controls on these reactions to see if they can be utilized in the mining industry to economically extract copper from low grade ores.
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Olympic Dam in a Test Tube: Critical Experiments and Theory for Understanding Fe-Cu-U-REE in Hydrothermal Fluids and during Fluid-Rock Interaction. Olympic Dam (OD) is a supergiant Cu-U-Au-Ag-REE ore deposit, containing more than a trillion Australian dollars worth of metals, and hosted by hematite-rich breccia in South Australia. Yet, key aspects of the geochemistry of OD-style deposits remain poorly understood. This project will conduct innovative experiments to address the role for fluorine i ....Olympic Dam in a Test Tube: Critical Experiments and Theory for Understanding Fe-Cu-U-REE in Hydrothermal Fluids and during Fluid-Rock Interaction. Olympic Dam (OD) is a supergiant Cu-U-Au-Ag-REE ore deposit, containing more than a trillion Australian dollars worth of metals, and hosted by hematite-rich breccia in South Australia. Yet, key aspects of the geochemistry of OD-style deposits remain poorly understood. This project will conduct innovative experiments to address the role for fluorine in Fe, U and REE transport at OD, and the role of fluid-rock interaction in generating the unusually oxidised Fe-Cu mineral assemblages and in controlling U grades and distribution. The fundamental information gained will underpin intense on-going research aimed at discovering new OD-style orebodies and at creating new ore-processing technology that are environmentally sustainable and able to access lower-grade ores.Read moreRead less
Hydrothermal remobilisation of base metals and platinum group elements in magmatic nickel deposits. Magmatic nickel sulphide deposits are highly valuable but extremely challenging exploration targets, thought to lack the distinctive geochemical haloes that allow small targets to be identified from sparse drilling. The project will test the potential of hydrothermal remobilisation of nickel, cobalt and platinum group elements to create broad alteration haloes.
Molecular Structure and Transport Properties of Hydrothermal Fluids under Extreme Conditions: Near-Critical, High Salinity, High Pressure and High Volatile Contents. The experimental capabilities, theoretical understanding, and numerical modeling methods developed in this project have broad implication for supporting both well-established (mineral exploration and ore processing) and emerging (geothermal energy; geosequestration) industries of core significance for the future of Australia's econo ....Molecular Structure and Transport Properties of Hydrothermal Fluids under Extreme Conditions: Near-Critical, High Salinity, High Pressure and High Volatile Contents. The experimental capabilities, theoretical understanding, and numerical modeling methods developed in this project have broad implication for supporting both well-established (mineral exploration and ore processing) and emerging (geothermal energy; geosequestration) industries of core significance for the future of Australia's economy. This project also provides access to unique technology developed overseas; this technology will be adapted for the unique challenges faced by Australia, and made available to the broader scientific community via the Australian Synchrotron.Read moreRead less
Hydrogen generation by subsurface iron mineral transformations. Aim
The aim of this project is to elucidate key factors responsible for natural hydrogen generation in Australian subsurface environments.
Significance
Large amounts of this valuable resource are produced naturally with estimates of production rates of this “gold” hydrogen at least 100 times the annual demand for this critical resource.
Expected Outcomes
Based on improved understanding of the source of natural hydrogen, predictive ....Hydrogen generation by subsurface iron mineral transformations. Aim
The aim of this project is to elucidate key factors responsible for natural hydrogen generation in Australian subsurface environments.
Significance
Large amounts of this valuable resource are produced naturally with estimates of production rates of this “gold” hydrogen at least 100 times the annual demand for this critical resource.
Expected Outcomes
Based on improved understanding of the source of natural hydrogen, predictive tools will be developed that will assist in assessing the viability in Australia of hydrogen exploration and engineered retrieval.
Benefits
Ready access to naturally produced hydrogen could enable Australia to replace hydrogen that is currently generated via the use of unabated hydrocarbons.Read moreRead less
The Geochemistry of Tellurium in Hydrothermal Environments and the Gold-Tellurium Association. Gold and base metal mining are some of Australia's principal export earners. Thus, improving the country's mining and geological exploration capabilities will be a considerable economic benefit to the whole community. The results of the project will yield information concerning how gold deposits form, improved techniques for gold exploration, and more environmentally friendly techniques for the process ....The Geochemistry of Tellurium in Hydrothermal Environments and the Gold-Tellurium Association. Gold and base metal mining are some of Australia's principal export earners. Thus, improving the country's mining and geological exploration capabilities will be a considerable economic benefit to the whole community. The results of the project will yield information concerning how gold deposits form, improved techniques for gold exploration, and more environmentally friendly techniques for the processing of gold-telluride ores. Read moreRead less
Deep and smelly: exploring the roles of pressure and sulphur in hydrothermal metal transport. Hot, salty fluids carry metals in the Earth's crust and are responsible for the formation of Australia's mineral wealth. This project combines exciting new experiments with molecular-level simulations to predict metal transport, providing a sound basis for improving mineral exploration models and sustaining discovery of new deposits.
In-situ solubility and speciation studies in super-critical H2O-NaCl-CO2 mixtures using synchrotron radiation. Understanding the physics and chemistry of metals in hypersaline and supercritical solutions represents a major scientific challenge with wide-ranging applications in the fields of mineral processing, economic geology, or CO2 sequestration. The advent of very bright sources of x-rays (synchrotrons) and development of spectroscopic cells that can contain corrosives samples at high pressu ....In-situ solubility and speciation studies in super-critical H2O-NaCl-CO2 mixtures using synchrotron radiation. Understanding the physics and chemistry of metals in hypersaline and supercritical solutions represents a major scientific challenge with wide-ranging applications in the fields of mineral processing, economic geology, or CO2 sequestration. The advent of very bright sources of x-rays (synchrotrons) and development of spectroscopic cells that can contain corrosives samples at high pressure and temperature allow for the first time the in-situ observation of these solutions. This project creates strong link between Australian and French scientists. By sharing the know-how developed at the European Synchrotron Research Facility, we aim to create a world-class facility at the Australian Synchrotron that will open in Melbourne in 2007.Read moreRead less
Microbially induced calcium carbonate precipitation in different substrates. Carbonates in the form of limestone represent an important reservoir of carbon on earth. They are recorded in several natural geological formations as corals, stromatolites, beach rocks. Microbes play an important role in the formation as well as dissolution of carbonates during microbially induced calcium carbonate precipitation (MICP) reactions on different substrates in natural and built environments. Much of our kno ....Microbially induced calcium carbonate precipitation in different substrates. Carbonates in the form of limestone represent an important reservoir of carbon on earth. They are recorded in several natural geological formations as corals, stromatolites, beach rocks. Microbes play an important role in the formation as well as dissolution of carbonates during microbially induced calcium carbonate precipitation (MICP) reactions on different substrates in natural and built environments. Much of our knowledge on MICP is limited due to poor understanding of the reaction kinetics at a molecular level. This project will develop new methods to enable and advance the knowledge of MICP process with profound implications for understanding natural geological formations as well as widen the scope of current engineering applications.Read moreRead less
Transport of metals in vapours and brines: new insights into the formation of the Earth's mineral deposits. Traditional models for the formation of hydrothermal ore deposits assume that aqueous fluids transported the metals. This view is challenged by new observations showing that gold and copper are preferentially enriched in vapours coexisting with salty aqueous fluids in some deposits. This project uses state-of-the-art techniques and develops new instruments to measure experimentally the par ....Transport of metals in vapours and brines: new insights into the formation of the Earth's mineral deposits. Traditional models for the formation of hydrothermal ore deposits assume that aqueous fluids transported the metals. This view is challenged by new observations showing that gold and copper are preferentially enriched in vapours coexisting with salty aqueous fluids in some deposits. This project uses state-of-the-art techniques and develops new instruments to measure experimentally the partitioning of metals between solid, fluid and vapour at temperatures typical for natural ore deposits (350-550C, pressures varying for vapour saturated to 1 kb). By improving our understanding of metal transport within the Earth's crust, these data will lead to improved models and technologies for exploring and processing base and precious metals.Read moreRead less