Unravelling vanadium biogeochemistry in modern marine sediments. This project aims to unravel the biogeochemistry of vanadium in modern marine sediments for use as a tracer of ancient oxygen concentrations in the oceans of the early Earth. This project will generate fundamental knowledge on the behaviour of vanadium in modern marine sediments by applying advanced analytical tools for imaging its concentration and chemical form at ultra-high resolution. This information is critical for accurate i ....Unravelling vanadium biogeochemistry in modern marine sediments. This project aims to unravel the biogeochemistry of vanadium in modern marine sediments for use as a tracer of ancient oxygen concentrations in the oceans of the early Earth. This project will generate fundamental knowledge on the behaviour of vanadium in modern marine sediments by applying advanced analytical tools for imaging its concentration and chemical form at ultra-high resolution. This information is critical for accurate interpretation of the geological record to infer the oxygen concentration of the oceans at various points in Earth's history. This interdisciplinary project will facilitate strong collaboration between Australian and Danish researchers in the field of marine geochemistry and paleoceanography.Read moreRead less
Hydrogen generation by subsurface iron mineral transformations. Aim
The aim of this project is to elucidate key factors responsible for natural hydrogen generation in Australian subsurface environments.
Significance
Large amounts of this valuable resource are produced naturally with estimates of production rates of this “gold” hydrogen at least 100 times the annual demand for this critical resource.
Expected Outcomes
Based on improved understanding of the source of natural hydrogen, predictive ....Hydrogen generation by subsurface iron mineral transformations. Aim
The aim of this project is to elucidate key factors responsible for natural hydrogen generation in Australian subsurface environments.
Significance
Large amounts of this valuable resource are produced naturally with estimates of production rates of this “gold” hydrogen at least 100 times the annual demand for this critical resource.
Expected Outcomes
Based on improved understanding of the source of natural hydrogen, predictive tools will be developed that will assist in assessing the viability in Australia of hydrogen exploration and engineered retrieval.
Benefits
Ready access to naturally produced hydrogen could enable Australia to replace hydrogen that is currently generated via the use of unabated hydrocarbons.Read moreRead less
Integrated nonmetal-metal single-atom catalysis for selective synthesis. Single atom catalysts can achieve the maximum efficiency of active sites for a reaction. This project will develop integrated nonmetal and metal single atom-based catalysts for selective oxidation towards clean production and organic waste conversion to value-added polymers for carbon recycle. The project will result in new functional materials and green catalytic processes for chemical synthesis and waste reduction, and ad ....Integrated nonmetal-metal single-atom catalysis for selective synthesis. Single atom catalysts can achieve the maximum efficiency of active sites for a reaction. This project will develop integrated nonmetal and metal single atom-based catalysts for selective oxidation towards clean production and organic waste conversion to value-added polymers for carbon recycle. The project will result in new functional materials and green catalytic processes for chemical synthesis and waste reduction, and advance fundamental understanding of molecular structure of materials for catalyst design and process engineering for industrial applications. The outcomes will promote the development of chemical industry, waste recycle and green environment in Australia, making significant benefits to economics and society.Read moreRead less
Visualising molecular level detail in single cells and intact tissues. The goal of this project is to deliver a new toolkit for imaging cells at an unprecedented resolution and level of chemical detail. We will expand the capabilities of two existing, but complementary, methods: optical fluorescence microscopy with responsive probes and X-ray fluorescence imaging. Expected outcomes include improved techniques and benchmarks for visualising bacterial and mammalian cells; development of new molecu ....Visualising molecular level detail in single cells and intact tissues. The goal of this project is to deliver a new toolkit for imaging cells at an unprecedented resolution and level of chemical detail. We will expand the capabilities of two existing, but complementary, methods: optical fluorescence microscopy with responsive probes and X-ray fluorescence imaging. Expected outcomes include improved techniques and benchmarks for visualising bacterial and mammalian cells; development of new molecules for elucidating cellular chemistry; better utilisation of valuable synchrotron resources; and greater understanding of the strengths and limitations of current microscopy workflows. Results should benefit the biotechnology sector, and may lead to improved medical, diagnostic, and bioremediation capacity.Read moreRead less
Targeted electrolyte design for high energy aqueous batteries. The Project aims to develop a new generation, high-energy aqueous battery. A range of new aqueous electrolytes with large working window at low concentration will be designed to replace traditional, flammable and toxic organic electrolytes, and; low-cost and multi-electron reaction materials will be developed as high-capacity electrodes to replace traditional intercalation-type materials. The Project will establish the structure-prop ....Targeted electrolyte design for high energy aqueous batteries. The Project aims to develop a new generation, high-energy aqueous battery. A range of new aqueous electrolytes with large working window at low concentration will be designed to replace traditional, flammable and toxic organic electrolytes, and; low-cost and multi-electron reaction materials will be developed as high-capacity electrodes to replace traditional intercalation-type materials. The Project will establish the structure-property relationship for electrolytes and interphases via advanced characterization(s) and computation. The new battery will be safe, energetic and sustainable for the billion-dollar energy storage market for electric vehicle, and smart-grid whilst addressing concurrently battery safety and boosted energy-density.Read moreRead less
Microbially induced calcium carbonate precipitation in different substrates. Carbonates in the form of limestone represent an important reservoir of carbon on earth. They are recorded in several natural geological formations as corals, stromatolites, beach rocks. Microbes play an important role in the formation as well as dissolution of carbonates during microbially induced calcium carbonate precipitation (MICP) reactions on different substrates in natural and built environments. Much of our kno ....Microbially induced calcium carbonate precipitation in different substrates. Carbonates in the form of limestone represent an important reservoir of carbon on earth. They are recorded in several natural geological formations as corals, stromatolites, beach rocks. Microbes play an important role in the formation as well as dissolution of carbonates during microbially induced calcium carbonate precipitation (MICP) reactions on different substrates in natural and built environments. Much of our knowledge on MICP is limited due to poor understanding of the reaction kinetics at a molecular level. This project will develop new methods to enable and advance the knowledge of MICP process with profound implications for understanding natural geological formations as well as widen the scope of current engineering applications.Read moreRead less
Unravelling how aquatic coastal networks regulate nitrogen removal . The aim of this project is to determine the nitrogen removal pathways of the coastal zone using a number of innovative field and modelling approaches. Little is known about how the complex coastal landscape controls trade-offs that maximise nitrogen removal but minimise nitrous oxide (a potent greenhouse gas) emissions. The outcomes of this study will significantly advance our understanding of the coastal zone in regional and g ....Unravelling how aquatic coastal networks regulate nitrogen removal . The aim of this project is to determine the nitrogen removal pathways of the coastal zone using a number of innovative field and modelling approaches. Little is known about how the complex coastal landscape controls trade-offs that maximise nitrogen removal but minimise nitrous oxide (a potent greenhouse gas) emissions. The outcomes of this study will significantly advance our understanding of the coastal zone in regional and global nitrogen budgets. This will provide significant benefits such as a new science-based quantitative framework to facilitate best practice management to reduce terrestrial nitrogen loads and associated downstream impacts such as eutrophication, and reduce nitrous oxide emissions and associated global warming.
Read moreRead less
Impact of melt loss on crustal heat production and Earth geodynamics. This project plans to develop a thermodynamic tool set to calculate the amounts of rare earth elements, thorium and uranium in monazite and link its growth and radiogenic heat budget to rock evolution. Thorium (Th) and uranium (U) produce 83 per cent of the heat in Earth’s continental crust. Vast tracts of high-heat-producing rock from hot, deep parts of the crust defy the notion that such crust is depleted in Th and U. The ca ....Impact of melt loss on crustal heat production and Earth geodynamics. This project plans to develop a thermodynamic tool set to calculate the amounts of rare earth elements, thorium and uranium in monazite and link its growth and radiogenic heat budget to rock evolution. Thorium (Th) and uranium (U) produce 83 per cent of the heat in Earth’s continental crust. Vast tracts of high-heat-producing rock from hot, deep parts of the crust defy the notion that such crust is depleted in Th and U. The causes of high heat production in the deep crust remain unclear. This project will develop a tool set to calculate the Th and U concentration in minerals (eg monazite, zircon) and silicate melt as a function of depth, temperature and rock composition. This tool set would be of great benefit to the geoscience community for better understanding fundamental geodynamic processes.Read moreRead less
Mycobacterial Cholesterol Degradation: A Unique Metabolic Weakness? This project aims to understand the use of the steroid cholesterol as a source of essential metabolic building blocks by bacteria. Cholesterol utilisation is a key feature of many bacterial pathogens which have evolved to survive in niche environments. By understanding the initial step in cholesterol degradation and the bioinorganic and bioorganic chemistry of the metalloenzymes that catalyse it, this work aims to develop strate ....Mycobacterial Cholesterol Degradation: A Unique Metabolic Weakness? This project aims to understand the use of the steroid cholesterol as a source of essential metabolic building blocks by bacteria. Cholesterol utilisation is a key feature of many bacterial pathogens which have evolved to survive in niche environments. By understanding the initial step in cholesterol degradation and the bioinorganic and bioorganic chemistry of the metalloenzymes that catalyse it, this work aims to develop strategies to block this activity. This will turn a key strength of these bacteria into a potent weakness and will generate the proof of principle and knowledge required for the future development of effective strategies to combat pathogenic bacteria.Read moreRead less
Fluid-induced creation and decay of porosity and permeability in minerals. This project aims to investigate the role of hydrothermal fluids in the creation and decay of porosity and permeability in minerals. By developing new experimental techniques and undertaking experimental studies mimicking natural conditions, this project expects to generate knowledge of the fundamental relationships between fluid-mineral reactions, pore creation and decay, pore geometry and connectivity, and the mechanism ....Fluid-induced creation and decay of porosity and permeability in minerals. This project aims to investigate the role of hydrothermal fluids in the creation and decay of porosity and permeability in minerals. By developing new experimental techniques and undertaking experimental studies mimicking natural conditions, this project expects to generate knowledge of the fundamental relationships between fluid-mineral reactions, pore creation and decay, pore geometry and connectivity, and the mechanism for the formation of fluid inclusions. This should provide significant benefits such as a deeper understanding of the hydrothermal fluids flowing through tight rocks in the Earth’s crust to form orebodies, and provide a scientific basis to underpin the development of greener technologies for recovering natural resources.Read moreRead less