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Ionic Dispersion Forces in Physical Chemistry: Implications for pH, Electrochemistry, Nanoparticle Formation and Organic Synthesis. Our current understanding of charged systems in solution is deeply flawed . Existing theories are not predictive, mainly because they concentrate entirely on electrostatics. This proposal aims to partially rectify this by including the effects of previously neglected dispersion forces in a number of problems. These forces are responsible for much of the behaviou ....Ionic Dispersion Forces in Physical Chemistry: Implications for pH, Electrochemistry, Nanoparticle Formation and Organic Synthesis. Our current understanding of charged systems in solution is deeply flawed . Existing theories are not predictive, mainly because they concentrate entirely on electrostatics. This proposal aims to partially rectify this by including the effects of previously neglected dispersion forces in a number of problems. These forces are responsible for much of the behaviour seen in the following systems: the theory of electrolytes; electrochemistry pH and buffers; self energy effects in organic chemistry; and zeolite and nano-particle synthesis. The main outcome will be accurate and predictive theories for these systems.Read moreRead less
Nanotribology and Nanorheometry: A Fundamental Study of the Dynamic Interactions of Particles and Surfaces at the Molecular Level. Friction and deformation occur from the mutual motion and interaction of microscopic particles and surfaces. This research aims to develop new theories and measurement techniques for these non-equilibrium phenomena by combining mathematical analysis and numerical computations with dynamic force measurement, surface modification, and surface characterisation on nanom ....Nanotribology and Nanorheometry: A Fundamental Study of the Dynamic Interactions of Particles and Surfaces at the Molecular Level. Friction and deformation occur from the mutual motion and interaction of microscopic particles and surfaces. This research aims to develop new theories and measurement techniques for these non-equilibrium phenomena by combining mathematical analysis and numerical computations with dynamic force measurement, surface modification, and surface characterisation on nanometre and molecular length scales. These insights and data will be critically important in designing low-friction surfaces that save energy and wear, in developing nanoscopic probes for the mechanical and structural properties of soft polymeric and bio-materials, and in making high performance coatings that control adhesion and particle aggregation in technologically advanced applications.Read moreRead less
Novel Nanomaterials for Photocatalytic Water Purification - Science and Application. Water is rapidly becoming Australia's most critical natural resource, and there is an urgent need to re-use and recycle water from domestic use (graywater) and industry, as well as utilisation of larger scale harvesting of rainwater. The outcome of this project will be a technology which can remove organic material (biological and non-biological) from water, enabling a greater range of uses of wastewater. This ....Novel Nanomaterials for Photocatalytic Water Purification - Science and Application. Water is rapidly becoming Australia's most critical natural resource, and there is an urgent need to re-use and recycle water from domestic use (graywater) and industry, as well as utilisation of larger scale harvesting of rainwater. The outcome of this project will be a technology which can remove organic material (biological and non-biological) from water, enabling a greater range of uses of wastewater. This technology will play a significant role in delivering future water security, and developing new industries involved in manufacture and export of water treatment technologies. This project directly addresses the National Priority Research area of water, and international priorities involving greater re-use and recycling of water.Read moreRead less
Anomalous interfacial air-bubble dynamics: the importance of electrokinetic effects in thin film drainage. Air bubbles play important roles in numerous systems including plastics and paper recycling, water treatment and mineral separation processes, foodstuffs, beverages, cosmetics, cleaning products, fire retardants, and natural systems such as rivers, oceans and biological fluids. The properties and behaviour of these systems and processes depend on how air bubbles in water interact with each ....Anomalous interfacial air-bubble dynamics: the importance of electrokinetic effects in thin film drainage. Air bubbles play important roles in numerous systems including plastics and paper recycling, water treatment and mineral separation processes, foodstuffs, beverages, cosmetics, cleaning products, fire retardants, and natural systems such as rivers, oceans and biological fluids. The properties and behaviour of these systems and processes depend on how air bubbles in water interact with each other, and/or with other materials. Currently our understanding of the bubble interactions is incomplete. The improved understanding gained from this research project will lead to better ability to control the properties of systems and processes such as those listed above.Read moreRead less
Computational studies of melting and the solvation properties of ionic liquids. Ionic liquids are used in industry as green solvents and electrolytes, although there is not yet sufficient knowledge on the science of ionic liquids to enable optimal solvents to be readily designed. This project uses state of the art techniques in computational chemistry to solve practical problems related to the characteristics of ionic liquids.
Reduced water usage in the Australian pulp and paper industry through novel process chemistry. Norske Skog Paper Mill operates two paper mills on major rivers in Australia. For these mills to reduce water consumption greater recycling of the process water is needed which results in a build-up of detrimental substances that will affect paper machine performance and efficiency. The knowledge gained from this project will help the paper mills to find strategies to control the build-up of the detr ....Reduced water usage in the Australian pulp and paper industry through novel process chemistry. Norske Skog Paper Mill operates two paper mills on major rivers in Australia. For these mills to reduce water consumption greater recycling of the process water is needed which results in a build-up of detrimental substances that will affect paper machine performance and efficiency. The knowledge gained from this project will help the paper mills to find strategies to control the build-up of the detrimental material and deal with it in such a way that the process water can be recycled and the paper mills can reduce water consumption.Read moreRead less
Development of a novel biodegradable ophthalmic biomaterial based on porous silicon. Within this interdisciplinary project, we will combine our diverse expertise towards the development of frontier technologies for control of stem cell behaviour on biodegradable scaffold materials. We will develop a novel ophthalmic bioimplant from porous silicon using topographical and chemical aspects of surface modification as well as immobilisation and/or incorporation of bioactive species such as growth fac ....Development of a novel biodegradable ophthalmic biomaterial based on porous silicon. Within this interdisciplinary project, we will combine our diverse expertise towards the development of frontier technologies for control of stem cell behaviour on biodegradable scaffold materials. We will develop a novel ophthalmic bioimplant from porous silicon using topographical and chemical aspects of surface modification as well as immobilisation and/or incorporation of bioactive species such as growth factors, to permit the growth and differentiation of mammalian stem cells. This project will result in biomaterials for the treatment of blinding diseases of the eye. Implanted into the limbus, bioimplants may ameliorate some common corneal diseases.Read moreRead less
The role of fat crystal wettability in altering dairy emulsion properties. The role of fat crystal wettability in altering dairy emulsion properties. This project aims to control fat crystal wettability, to create tailored dairy products with desirable stability, shelf-life and texture. Fat crystals are an essential component of dairy emulsions (fat droplets dispersed in dairy/milk serum) and control product processing, shelf life and texture. Their structuring role involves partial coalescence: ....The role of fat crystal wettability in altering dairy emulsion properties. The role of fat crystal wettability in altering dairy emulsion properties. This project aims to control fat crystal wettability, to create tailored dairy products with desirable stability, shelf-life and texture. Fat crystals are an essential component of dairy emulsions (fat droplets dispersed in dairy/milk serum) and control product processing, shelf life and texture. Their structuring role involves partial coalescence: the formation of complicated network structures of fat droplets. Unless fat crystals are partially wetted by water, they will not be present at the fat droplet interface, and partial coalescence will not occur. Expected outcomes are new dairy products with optimum stability and texture.Read moreRead less
Study of molecular interactions between wood pitch fixatives and components of wood pitch. Wood resins, released in pulping, agglomerate in the papermaking process to cause pitch deposits. These deposits adversely affect paper machine efficiency and product quality and limit further recycling of process water. This project aims to investigate the interactions between the components of the wood resins and different fixatives using capillary electrophoresis and other techniques. This knowledge w ....Study of molecular interactions between wood pitch fixatives and components of wood pitch. Wood resins, released in pulping, agglomerate in the papermaking process to cause pitch deposits. These deposits adversely affect paper machine efficiency and product quality and limit further recycling of process water. This project aims to investigate the interactions between the components of the wood resins and different fixatives using capillary electrophoresis and other techniques. This knowledge will provide a better understanding of the role of the physical and chemical properties of the fixatives in fixing the different compounds in wood resins. Molecular modelling will be used to design new fixatives that will be selective to a mixture of wood resins.
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De-risking new surfactant and polymer classes in personal care formulations. Personal care products are almost completely reliant on palm oil feedstocks for the surfactants or soaps that provide cleansing and conditioning. Yet, there is considerable risk in moving to alternative feedstocks for new surfactant formulations, where the design rules based in fundamental colloid science do not yet exist. In collaboration with world leading formulation expertise, this project aims to use a combination ....De-risking new surfactant and polymer classes in personal care formulations. Personal care products are almost completely reliant on palm oil feedstocks for the surfactants or soaps that provide cleansing and conditioning. Yet, there is considerable risk in moving to alternative feedstocks for new surfactant formulations, where the design rules based in fundamental colloid science do not yet exist. In collaboration with world leading formulation expertise, this project aims to use a combination of high-throughput microfluidic platforms to direct more detailed colloidal, surface and scattering techniques to drive mechanistic studies to link microstructure to formulation properties. This will lead to the design rules needed to control the synergistic interactions between surfactants and polymers in these formulations.Read moreRead less