Modelling of Nitric Oxides and Carbon Monoxide Emissions from Bagasse-Fires Boilers. The project aims to develop computational models to predict emissions of nitric oxides and carbon monoxide from sugar-mill boilers burning bagasse. Bagasse combustion does not contribute to greenhouse gas emissions and clean and efficient combustion of this fuel has become very important for the sugar industry and for Australia. The project combines the opportunity of direct boiler measurements by SRI with the m ....Modelling of Nitric Oxides and Carbon Monoxide Emissions from Bagasse-Fires Boilers. The project aims to develop computational models to predict emissions of nitric oxides and carbon monoxide from sugar-mill boilers burning bagasse. Bagasse combustion does not contribute to greenhouse gas emissions and clean and efficient combustion of this fuel has become very important for the sugar industry and for Australia. The project combines the opportunity of direct boiler measurements by SRI with the modelling expertise at the University to develop combustion-kinetics models for these species. The models will be incorporated into the previously developed computational fluid dynamics - combustion code of the furnace to give the capability of emission prediction as a function of burner operating conditions and fuel parameters.Read moreRead less
A Fundamental Study on Redox Behaviour of Oxygen Carriers in Chemical Looping Combustion. Our goal here is to acquire fundamental knowledge about the redox behaviour of metal oxide oxygen carriers which, arguably, underpins the feasibility of the Chemical Looping Combustion (CLC) concept. Although the proposed work is fundamental and will contribute to the advancement of knowledge, the results will have immediate practical applications in power generation industry at both national and internatio ....A Fundamental Study on Redox Behaviour of Oxygen Carriers in Chemical Looping Combustion. Our goal here is to acquire fundamental knowledge about the redox behaviour of metal oxide oxygen carriers which, arguably, underpins the feasibility of the Chemical Looping Combustion (CLC) concept. Although the proposed work is fundamental and will contribute to the advancement of knowledge, the results will have immediate practical applications in power generation industry at both national and international levels. This should significantly contribute to the Australian Government's efforts in producing world class solutions for abatement of greenhouse emissions (Research Priority 1: An Environmentally Sustainable Australia, Priority Goal 1.4 - Reducing and capturing emissions in transport and energy generation).Read moreRead less
Degradation of atomically dispersed M-N-C carbon catalysts in acidic media. This project aims to provide a clear understanding of the degradation mechanisms of transition metal (M) and nitrogen (N) co-doped carbon (M-N-C) catalysts in acidic media by utilising new model catalysts, standardised degradation tests, comprehensive catalyst characterisation, and machine learning tools to interrogate mechanistic hypotheses and link degradation mechanisms to specific catalyst characteristics. This proje ....Degradation of atomically dispersed M-N-C carbon catalysts in acidic media. This project aims to provide a clear understanding of the degradation mechanisms of transition metal (M) and nitrogen (N) co-doped carbon (M-N-C) catalysts in acidic media by utilising new model catalysts, standardised degradation tests, comprehensive catalyst characterisation, and machine learning tools to interrogate mechanistic hypotheses and link degradation mechanisms to specific catalyst characteristics. This project expects to generate new knowledge on rationally designing robust hydrogen fuel cell catalysts. This will provide significant benefits, such as new knowledge on catalyst degradation, new catalysts for energy conversion applications, and collaborations with the industry to accelerate Australia’s shift to renewable energy.Read moreRead less
Self-heating of porous lignocellulosic and coal particles. This project develops models for spontaneous heating of materials, which have substantial value to Australian economy, and whose self-heating behaviour have led to loss of life and significant material losses in industries processing these materials. The results will be immediately applicable to evaluate risks of spontaneous ignition in process plants in a more rigorous manner than performed presently. Furthermore, findings of this inv ....Self-heating of porous lignocellulosic and coal particles. This project develops models for spontaneous heating of materials, which have substantial value to Australian economy, and whose self-heating behaviour have led to loss of life and significant material losses in industries processing these materials. The results will be immediately applicable to evaluate risks of spontaneous ignition in process plants in a more rigorous manner than performed presently. Furthermore, findings of this investigation will allow considerable improvement in estimating green house gas emissions as a consequence of spontaneous combustion.Read moreRead less
Fundamental Fire Properties From Extinction and Piloted Ignition Experiments of Solid Fuels. Current approval methods for determining fire properties of construction materials are often incorrect in yielding properties that can be used in situations removed from test conditions. The main aim of this project is to obtain fundamental fire properties by examining the ignition and extinction processes of diffusion flames near solid surfaces. The project undertakes detailed study of flame spread in ....Fundamental Fire Properties From Extinction and Piloted Ignition Experiments of Solid Fuels. Current approval methods for determining fire properties of construction materials are often incorrect in yielding properties that can be used in situations removed from test conditions. The main aim of this project is to obtain fundamental fire properties by examining the ignition and extinction processes of diffusion flames near solid surfaces. The project undertakes detailed study of flame spread in the direction opposite to the flow of air, which defines the initial fire growth and is important in fire propagation. Results from this project will provide scientific underpinning for the development of approval standards for new materials, which are needed to support Australia's transition from prescriptive to performance based building codes.Read moreRead less
All-Metal Nanoporous Materials as Highly Active Electrocatalysts. This project aims to create new avenues for well-controlled large-scale synthesis of hierarchical nanoporous platinum-based architectures, and develop applications for the resultant new electrocatalysts. Developing novel high-performance, low-cost, and long-life electrode catalysts can improve the efficiency, cost, and durability of energy conversion technology. The project plans to use the unique properties of well-defined nanoar ....All-Metal Nanoporous Materials as Highly Active Electrocatalysts. This project aims to create new avenues for well-controlled large-scale synthesis of hierarchical nanoporous platinum-based architectures, and develop applications for the resultant new electrocatalysts. Developing novel high-performance, low-cost, and long-life electrode catalysts can improve the efficiency, cost, and durability of energy conversion technology. The project plans to use the unique properties of well-defined nanoarchitectures to reduce platinum content and to improve electrocatalytic performance. Nanoporous systems in electrocatalysts can provide more active sites and effective surface permeability, which should enhance catalytic activity. Project outcomes may also contribute to our understanding of the relationships among morphologies, pore structures, surface atomic structures and catalytic activities to guide the development of other kinds of high performance nanoporous catalysts.Read moreRead less
Carbon surface oxides: the key to understanding the chemical rate of carbon combustion. This project employs a unique combination of experimental measurements and fundamental quantum chemical calculations to study the oxides which form on the surface of carbon as it burns. Our objective is to develop a quantitative model for the kinetics of carbon combustion which will be a profound improvement over existing approaches. Such a model would provide the basis for the improved prediction of carbon c ....Carbon surface oxides: the key to understanding the chemical rate of carbon combustion. This project employs a unique combination of experimental measurements and fundamental quantum chemical calculations to study the oxides which form on the surface of carbon as it burns. Our objective is to develop a quantitative model for the kinetics of carbon combustion which will be a profound improvement over existing approaches. Such a model would provide the basis for the improved prediction of carbon combustion and gasification in current (coal-burning) power generation appliances, as well as catering for new approaches to lowering greenhouse emissions which also depend on the combustion and gasification of carbon as coal, biomass or refuse-derived fuel.Read moreRead less
Development of a gas-diesel engine injection system using a hydraulically actuated, electronically controlled unit injector (HEUI) for flexible dual-fuel operation. Achieving targets for greenhouse gas reduction will require practical, easily implemented alternative fuels for vehicles. Converting existing truck/bus diesel engines to dual-fuel systems using natural gas is important. In particular, for long distance application, these systems need to allow flexible switching from sole diesel to du ....Development of a gas-diesel engine injection system using a hydraulically actuated, electronically controlled unit injector (HEUI) for flexible dual-fuel operation. Achieving targets for greenhouse gas reduction will require practical, easily implemented alternative fuels for vehicles. Converting existing truck/bus diesel engines to dual-fuel systems using natural gas is important. In particular, for long distance application, these systems need to allow flexible switching from sole diesel to dual-fuel operation and good gas substitution at low loads within cities. An earlier ARC funded project allowed UNSW to develop the world's most compact, flexible HEUI diesel injector. This project aims to develop, test and explore dual-fuel combustion using a compact single unit, combined NG/HEUI injector which will have considerable combustion and operational advantages.Read moreRead less
Hydrogen fuel cells with non-precious metal cathode catalysts. Low-cost and robust fuel cell technology is a cornerstone towards the success of the hydrogen economy. The project aims to address the cost and durability of hydrogen fuel cells by advancing low-cost electrocatalysts for oxygen reduction reactions. Novel non-precious catalysts will be developed, and their stability understood in fuel cells using a new approach with in situ current mapping and X-ray computed tomography. The expected ....Hydrogen fuel cells with non-precious metal cathode catalysts. Low-cost and robust fuel cell technology is a cornerstone towards the success of the hydrogen economy. The project aims to address the cost and durability of hydrogen fuel cells by advancing low-cost electrocatalysts for oxygen reduction reactions. Novel non-precious catalysts will be developed, and their stability understood in fuel cells using a new approach with in situ current mapping and X-ray computed tomography. The expected outcomes of this project include material development, improved characterisation techniques and new knowledge on electrocatalysis. The project will benefit Kohodo Hydrogen Energy by positioning them as an Australian leader in low-cost catalysts, and to Australian industries in developing the hydrogen economy. Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0238345
Funder
Australian Research Council
Funding Amount
$373,000.00
Summary
Advanced Laser Diagnostics in Dilute Heterogeneous Combustion. This proposal seeks to establish a state-of-the-art laser diagnostics facility with unique capabilities for non-intrusive measurements in dilute multi-phase flows. Such heterogeneous flows which involve stationary surfaces, disperse suspended droplets or suspended particles are found in many applications including engines, furnaces, industrial and chemical processing and micro-combustion devices. This facility will give Australian re ....Advanced Laser Diagnostics in Dilute Heterogeneous Combustion. This proposal seeks to establish a state-of-the-art laser diagnostics facility with unique capabilities for non-intrusive measurements in dilute multi-phase flows. Such heterogeneous flows which involve stationary surfaces, disperse suspended droplets or suspended particles are found in many applications including engines, furnaces, industrial and chemical processing and micro-combustion devices. This facility will give Australian researchers the unprecedented opportunity to perform measurements of flow, mixing, temperature and composition fields in the gas and liquid or solid phases simultaneously. The resulting data will advance current knowledge in these complex flows and lead to new and improved reactor designs.
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