Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-si ....Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-site metal-organic framework catalyst with high reaction-activity and chemo-selectivity in converting CO2 into valuable chemicals. This advancement will provide significant benefits for Australia’s emerging chemical manufacturing industry, and ultimately leading to a carbon-neutral energy economy and environment.Read moreRead less
High Efficiency Electrochemical Cells. This project will study a recently developed, energy efficient ‘capillary-fed’ electrochemical cell architecture in the facilitation of various electro-energy and electro-synthetic transformations. The new cell architecture will be examined as a hydrogen-oxygen fuel cell and as a cell for extracting pure hydrogen from a 5-10% mixture of hydrogen in methane (natural gas), amongst others. The work seeks to improve upon the electrochemical performance of the b ....High Efficiency Electrochemical Cells. This project will study a recently developed, energy efficient ‘capillary-fed’ electrochemical cell architecture in the facilitation of various electro-energy and electro-synthetic transformations. The new cell architecture will be examined as a hydrogen-oxygen fuel cell and as a cell for extracting pure hydrogen from a 5-10% mixture of hydrogen in methane (natural gas), amongst others. The work seeks to improve upon the electrochemical performance of the best commercial and academic cells of such types, if possible. In increasing the efficiency with which renewable electricity can be converted into renewable hydrogen and back, this project will support the national priority of net-zero carbon emissions by 2050.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE220100583
Funder
Australian Research Council
Funding Amount
$445,000.00
Summary
Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous ....Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous polymeric MOF coating. This approach is expected to deliver robust biocatalysts with high reaction-activity and chemo-selectivity in converting CO2 into methanol under the industrial operating condition, involving thermal, pH, and chemical stressors. This advancement will contribute to a carbon-neutral industry and society.Read moreRead less
Advanced Proton-Conducting Ceramic FCs for Power Generation from Ammonia . The project aims to design an innovative ammonia fuel cell using a new perovskite substrate decorated with metal nanoparticles, which demonstrates multi-functionalities and tackles most challenges of conventional fuel cells (FCs). The key concept of this project is the designing of the novel architected smart perovskite as both anode and electrolyte of the fuel cell by systematic modelling and experimental development. T ....Advanced Proton-Conducting Ceramic FCs for Power Generation from Ammonia . The project aims to design an innovative ammonia fuel cell using a new perovskite substrate decorated with metal nanoparticles, which demonstrates multi-functionalities and tackles most challenges of conventional fuel cells (FCs). The key concept of this project is the designing of the novel architected smart perovskite as both anode and electrolyte of the fuel cell by systematic modelling and experimental development. The versatile cell components developed in this project will improve the operational stability and efficiency of the fuel cell, thereby providing a promising pathway for ammonia fuel cells to replace hydrogen fuel cells. This study will reinforce the development of the future supply of reliable, low cost and clean energy. Read moreRead less
Hybrid Hydrocarbon-Carbon Fuel Cells for Long-Life Power Generation. This project aims to design an innovative high-energy portable power source based on a hybrid direct hydrocarbon-carbon fuel cell concept, in which the deposited carbon in the anode of a fuel cell during operation with liquid hydrocarbon fuels can be used as a fuel by subsequent operation in the direct carbon fuel cell mode. The key concept in this project is the controlled deposition and utilization of carbon over the anode of ....Hybrid Hydrocarbon-Carbon Fuel Cells for Long-Life Power Generation. This project aims to design an innovative high-energy portable power source based on a hybrid direct hydrocarbon-carbon fuel cell concept, in which the deposited carbon in the anode of a fuel cell during operation with liquid hydrocarbon fuels can be used as a fuel by subsequent operation in the direct carbon fuel cell mode. The key concept in this project is the controlled deposition and utilization of carbon over the anode of the fuel cell by systematic modelling and experimental development. A continuous power output will be realized via an intelligent cycling mode with an intermittent supply of pure liquid hydrocarbon fuels, thereby achieving an extremely high fuel utilization efficiency in a hybrid electrochemical system.Read moreRead less
Electrochemical conversion of carbon dioxide to formic acid. This project aims to develop economical and scalable carbon dioxide electrochemical technologies to convert carbon dioxide in blast furnace flue gas to formic acid as a value-added product in steel-making plants. The project expects to develop new electrochemical catalysts, to optimise the structure of electrodes and ultimately improve carbon dioxide conversion efficiency and reaction selectivity towards formic acid. The expected outco ....Electrochemical conversion of carbon dioxide to formic acid. This project aims to develop economical and scalable carbon dioxide electrochemical technologies to convert carbon dioxide in blast furnace flue gas to formic acid as a value-added product in steel-making plants. The project expects to develop new electrochemical catalysts, to optimise the structure of electrodes and ultimately improve carbon dioxide conversion efficiency and reaction selectivity towards formic acid. The expected outcomes of this project will provide an efficient and economically viable electrochemical technology to convert carbon dioxide to a valuable product such as formic acid or syngas, with the potential to significantly reduce the emission of carbon dioxide from steel-making processes and coal-fired power plants.Read moreRead less