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Using natural products to inspire discoveries in synthesis and biosynthesis. This project aims to understand the organic chemistry that occurs in the biosynthesis of unusual antibiotic natural products by marine microorganisms. In an interdisciplinary approach, proposed biosynthetic intermediates will be synthesised and screened against newly isolated enzymes from the microorganisms of interest. This will allow the elucidation of biosynthetic pathways, and aid the discovery of new chemoenzymatic ....Using natural products to inspire discoveries in synthesis and biosynthesis. This project aims to understand the organic chemistry that occurs in the biosynthesis of unusual antibiotic natural products by marine microorganisms. In an interdisciplinary approach, proposed biosynthetic intermediates will be synthesised and screened against newly isolated enzymes from the microorganisms of interest. This will allow the elucidation of biosynthetic pathways, and aid the discovery of new chemoenzymatic reactivity that may be broadly useful in organic synthesis. Non-enzymatic, predisposed organic reactions will also be uncovered during the project. The benefit of this project will be an improvement in our ability to synthesise potential antibiotics using a combined synthetic organic and chemoenzymatic approach. This could lead to useful new antibiotics in the future.Read moreRead less
Internally decorated discrete Metallo-supramolecular Assemblies and infinite Metal-Organic Frameworks as molecular containers. In the macroscopic world, containers are used to hold, provide physical protection, or create a modified environment for their contents. This project will result in the synthesis of novel molecular container materials that provide decorated internal surfaces capable of selectively binding chemical species. In addition to the breakthrough scientific benefits of establish ....Internally decorated discrete Metallo-supramolecular Assemblies and infinite Metal-Organic Frameworks as molecular containers. In the macroscopic world, containers are used to hold, provide physical protection, or create a modified environment for their contents. This project will result in the synthesis of novel molecular container materials that provide decorated internal surfaces capable of selectively binding chemical species. In addition to the breakthrough scientific benefits of establishing the fundamentals of these systems, the binding of chemicals, which are environmental contaminants, will provide the grounding for applications that will contribute to the national priority of 'Frontier technologies'. Furthermore, this research will lead to the training of the next generation of Australian scientists by quality international researchers.Read moreRead less
Defining and controlling seawater intrusion in threatened coastal aquifers. This project aims to improve knowledge of coastal aquifer processes and management practices in order to increase the security of highly vulnerable freshwater. In particular, it aims to address critical barriers to the regional-scale investigation of coastal aquifers, including island lenses – the most vulnerable freshwater resources on earth. Threats to coastal aquifers are intensifying globally, and key knowledge gaps ....Defining and controlling seawater intrusion in threatened coastal aquifers. This project aims to improve knowledge of coastal aquifer processes and management practices in order to increase the security of highly vulnerable freshwater. In particular, it aims to address critical barriers to the regional-scale investigation of coastal aquifers, including island lenses – the most vulnerable freshwater resources on earth. Threats to coastal aquifers are intensifying globally, and key knowledge gaps prevail in our current understanding and representation of transient, regional-scale seawater intrusion. The project plans to use coastal aquifer case studies from Australia and overseas to evaluate seawater intrusion reversibility, intermittent pumping effects, offshore aquifer processes, and management approaches. The project may improve coastal aquifer practices globally by unravelling the driving forces of transient seawater intrusion and developing new seawater intrusion models.Read moreRead less
Novel CO2-stable oxygen transporting membranes for oxyfuel-based CO2 capture and utilization. Industrial carbon dioxide (CO2) emission is considered the main contribution to global warming. This project aims to develop a new class of oxygen transporting membrane (OTM) for CO2 capture and utilisation. To achieve this objective, the formation process and the unique characteristic of the membrane, as well as the oxygen transportation mechanism through the membrane will be investigated, experimental ....Novel CO2-stable oxygen transporting membranes for oxyfuel-based CO2 capture and utilization. Industrial carbon dioxide (CO2) emission is considered the main contribution to global warming. This project aims to develop a new class of oxygen transporting membrane (OTM) for CO2 capture and utilisation. To achieve this objective, the formation process and the unique characteristic of the membrane, as well as the oxygen transportation mechanism through the membrane will be investigated, experimentally and theoretically. This will advance the membrane technology in economically viable and efficient, clean energy applications.Read moreRead less
Deciphering Electron Transfer Pathways in Bacteria. Enzyme catalysed oxidation reactions are key players in the production of naturally occurring biologically active molecules. These processes are tightly regulated by their electron transfer partners. This project aims to characterise new electron transfer ferredoxin proteins from a metabolically diverse bacterium. These ferredoxins, important in many bacteria, contain different non-cysteine amino acids in their iron-sulfur cluster binding motif ....Deciphering Electron Transfer Pathways in Bacteria. Enzyme catalysed oxidation reactions are key players in the production of naturally occurring biologically active molecules. These processes are tightly regulated by their electron transfer partners. This project aims to characterise new electron transfer ferredoxin proteins from a metabolically diverse bacterium. These ferredoxins, important in many bacteria, contain different non-cysteine amino acids in their iron-sulfur cluster binding motifs and are poorly defined. The outcomes will advance understandings of electron transfer, a fundamental process. This will allow strategies to combat human and plant pathogens and unlock the potential of these systems as biocatalysts for the green chemical synthesis of complex and valuable chemicals.Read moreRead less
Blue energy harvesting and storage technology for wearable electronics. This project aims to develop new self-charging power devices that can harvest and store body energy generated during body motions, and power smart and implantable medical electronics. The project will develop new Piezo-supercapacitors by designing new electrode materials and cell designs. The charge storage and transport kinetics will be uncovered using advanced in-situ characterisation techniques and modern simulation metho ....Blue energy harvesting and storage technology for wearable electronics. This project aims to develop new self-charging power devices that can harvest and store body energy generated during body motions, and power smart and implantable medical electronics. The project will develop new Piezo-supercapacitors by designing new electrode materials and cell designs. The charge storage and transport kinetics will be uncovered using advanced in-situ characterisation techniques and modern simulation methods. The project expects to generate new knowledge in blue energy harvesting and storage systems, training for young scientists, and generate intellectual property with potential commercialised products to be used in implantable devices, placing Australia at the forefront of new technology.Read moreRead less
Carbon nanotube based chromatography. This project will reveal new insights into fundamental phenomena of molecular separation processes by carbon nanotubes and underpinning the development of a new generation of microchip separation devices that have the potential to revolutionise chromatographic techniques currently applied in genomics, proteomics, forensics and biotechnology.
Kelp forest ecosystems near and far: Putting a new theory explaining dynamic ecological systems to the test. Few, if any, ecological models account for the biological diversity and observed vulnerability of ecosystems, from the molecular to the oceanic scale. This project aims to investigate kelp forests in ways that integrate previously disparate approaches to the study of ecosystems in order to prove the value of a novel framework for understanding how broad-scale and local phenomena interrela ....Kelp forest ecosystems near and far: Putting a new theory explaining dynamic ecological systems to the test. Few, if any, ecological models account for the biological diversity and observed vulnerability of ecosystems, from the molecular to the oceanic scale. This project aims to investigate kelp forests in ways that integrate previously disparate approaches to the study of ecosystems in order to prove the value of a novel framework for understanding how broad-scale and local phenomena interrelate to maintain the diversity and function of ecosystems or to provoke their decline, transition or collapse. This new conceptualisation of ecosystem processes will assist in forecasting the consequences of their management and the effects of external stimuli on normally robust systems. Read moreRead less
Design of novel nanoporous semiconductor materials for clean environment and energy. This project will develop a low cost nanoporous semiconductor device for the capture and conversion of CO2 into fuels by using water and sunlight. This novel approach will deliver a low cost technology that offers clean energy and will help to mitigate global warming.
New molecular tools to study the mechanisms of bacterial metal homeostasis. This project aims to provide new insight into how metal ion uptake is regulated. It will precisely measure the cellular concentrations of metal ions, reveal the roles of metal ions in essential cellular processes, and identify the molecular targets of metal toxicity. Metal ions are essential to all forms of life and are used by up to half of all proteins to facilitate cellular chemical processes. The intended outcome of ....New molecular tools to study the mechanisms of bacterial metal homeostasis. This project aims to provide new insight into how metal ion uptake is regulated. It will precisely measure the cellular concentrations of metal ions, reveal the roles of metal ions in essential cellular processes, and identify the molecular targets of metal toxicity. Metal ions are essential to all forms of life and are used by up to half of all proteins to facilitate cellular chemical processes. The intended outcome of the research is to provide new fundamental knowledge of the roles of metal ions in bacterial cells; knowledge that will be key to defining the chemical biology of living systems and will provide information essential to understanding how microbes adapt to changing environments.Read moreRead less