Linkage Infrastructure, Equipment And Facilities - Grant ID: LE100100127
Funder
Australian Research Council
Funding Amount
$300,000.00
Summary
High resolution liquid chromatography mass spectrometry (Orbitrap) for analyses of polar compounds in biomass, petroleum, potable and reclaimed water. Climate change and human impact can harm sensitive ecosystems, significantly threatening Australian biodiversity and water resources. Chemical and biological characterisation of aquatic and terrestrial environments is paramount to assessing and responding to these threats, as well as assisting natural resource utilisation. The high structural pola ....High resolution liquid chromatography mass spectrometry (Orbitrap) for analyses of polar compounds in biomass, petroleum, potable and reclaimed water. Climate change and human impact can harm sensitive ecosystems, significantly threatening Australian biodiversity and water resources. Chemical and biological characterisation of aquatic and terrestrial environments is paramount to assessing and responding to these threats, as well as assisting natural resource utilisation. The high structural polarity of many environmentally occurring organics from biological, petroleum and anthropogenic sources, unamenable to gas chromatographic resolution, can now be accommodated by the advanced organic analytical technology sought in this proposal. This project will enable scholars and young professionals to be skilled in state-of-the-art technology, and prepare quality scientists, ready for employment.Read moreRead less
Sulfur Cycling in Toxic Oozes, Microbialites and Petroleum. This project will apply compound specific sulfur isotope analyses to sulfur-rich deposits from extreme environments including sulfidic black oozes (Peel-Harvey estuary); modern microbialites (for example, Shark Bay) and oils/source rocks (established and frontier oil fields). Sulfur isotopic data, integrated with other stable isotopic and molecular data, will greatly assist the study of sulfur biogeochemical cycles and mechanisms of org ....Sulfur Cycling in Toxic Oozes, Microbialites and Petroleum. This project will apply compound specific sulfur isotope analyses to sulfur-rich deposits from extreme environments including sulfidic black oozes (Peel-Harvey estuary); modern microbialites (for example, Shark Bay) and oils/source rocks (established and frontier oil fields). Sulfur isotopic data, integrated with other stable isotopic and molecular data, will greatly assist the study of sulfur biogeochemical cycles and mechanisms of organic sulfurisation at different diagenetic stages or geological ages. The project aims to address national concerns through measuring the respective impact of anthropogenic and natural changes on environments, helping to understand the evolution of life on Earth and contributing to efficient discovery of our natural petroleum systems.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE150100770
Funder
Australian Research Council
Funding Amount
$358,536.00
Summary
Solving the mystery of natural carbon mineralisation in Australian lakes. Some lakes, such as the Coorong lakes in South Australia, naturally sequester carbon dioxide in magnesium carbonate minerals. These minerals, which form in association with microorganisms in lake water, represent the safest possible long-term traps for carbon dioxide pollution. This project aims to determine the essential geochemical constraints on formation of magnesium carbonate minerals in the Coorong lakes, which are u ....Solving the mystery of natural carbon mineralisation in Australian lakes. Some lakes, such as the Coorong lakes in South Australia, naturally sequester carbon dioxide in magnesium carbonate minerals. These minerals, which form in association with microorganisms in lake water, represent the safest possible long-term traps for carbon dioxide pollution. This project aims to determine the essential geochemical constraints on formation of magnesium carbonate minerals in the Coorong lakes, which are unique natural laboratories for studying carbon dioxide sequestration. By delivering fundamental understanding of how microbial populations alter water chemistry for carbonate production, this project aims to inform the design of efficient and sustainable technologies for carbon dioxide sequestration that emulate natural processes in lakes.Read moreRead less
Unlocking the secrets of the groundwater cycle using Si and Li isotopes. This project aims to determine how non-conventional lithium and silicon isotopes can be used to understand groundwater processes using an innovative source-to-target approach. The project aims to apply these isotope tracers to trace the water cycle within a well constrained system: an island aquifer with a dense borefield which has been analysed using traditional isotopic techniques. Supporting hydrochemical data will be us ....Unlocking the secrets of the groundwater cycle using Si and Li isotopes. This project aims to determine how non-conventional lithium and silicon isotopes can be used to understand groundwater processes using an innovative source-to-target approach. The project aims to apply these isotope tracers to trace the water cycle within a well constrained system: an island aquifer with a dense borefield which has been analysed using traditional isotopic techniques. Supporting hydrochemical data will be used to determine the relationship of the isotopes with environmental processes. The project impact will be the development of new methods to help understand our groundwater resource. The improved process understanding will be translated to groundwater management in general. The projects' focus on carbonate aquifer systems typical of coastal regions of southern, eastern and western Australia will have relevance to groundwater management in urban areas such as Perth and in rural areas for tourism and viticulture, and for management of natural resources in National Parks.Read moreRead less
New perspectives on arsenic speciation and fate in anoxic aqueous environments: Resolving unexplored interactions with the sulfur cycle. Using exciting new experiments and innovative analyses, this project will provide transformational insights into how sulfur cycling in the Earth’s critical zone affects arsenic speciation and fate. The project will resolve, for the first time, unexplored interactions between arsenic geochemistry and the low-temperature formation and transformation of metastable ....New perspectives on arsenic speciation and fate in anoxic aqueous environments: Resolving unexplored interactions with the sulfur cycle. Using exciting new experiments and innovative analyses, this project will provide transformational insights into how sulfur cycling in the Earth’s critical zone affects arsenic speciation and fate. The project will resolve, for the first time, unexplored interactions between arsenic geochemistry and the low-temperature formation and transformation of metastable iron sulfide minerals. The outcomes will provide crucially important new perspectives on arsenic geochemistry in anoxic soils, sediments and groundwater systems.Read moreRead less
Interactions between antimony and the sulphur cycle. This project aims to unravel unexplored interactions between the sulphur cycle and fundamentally important aspects of antimony geochemistry in the Earth’s critical zone. This project will resolve interactions between antimony geochemistry and the low-temperature formation and transformation of metastable iron sulphide minerals. The outcomes are expected to provide crucially important perspectives on antimony geochemistry in anoxic soils, sedim ....Interactions between antimony and the sulphur cycle. This project aims to unravel unexplored interactions between the sulphur cycle and fundamentally important aspects of antimony geochemistry in the Earth’s critical zone. This project will resolve interactions between antimony geochemistry and the low-temperature formation and transformation of metastable iron sulphide minerals. The outcomes are expected to provide crucially important perspectives on antimony geochemistry in anoxic soils, sediments and groundwater systems. This understanding should lead to more accurate geochemical risk assessments and better site treatment strategies for environmental antimony contamination.Read moreRead less
Reactive oxygen species production on oxygenation of subsurface sediments. This project aims to examine the nature, extent and effect of redox processes in subsurface environments. Reactive oxygen species, including hydrogen peroxide, superoxide and hydroxyl radicals, transform and affect redox-active substances in the environment such as arsenic, uranium and natural organic matter (which may be oxidised to carbon dioxide). Production of significant quantities of reactive oxygen species on oxyge ....Reactive oxygen species production on oxygenation of subsurface sediments. This project aims to examine the nature, extent and effect of redox processes in subsurface environments. Reactive oxygen species, including hydrogen peroxide, superoxide and hydroxyl radicals, transform and affect redox-active substances in the environment such as arsenic, uranium and natural organic matter (which may be oxidised to carbon dioxide). Production of significant quantities of reactive oxygen species on oxygenation of subsurface sediments through actions such as aquifer recharge and high flow events may alter the form and mobility of trace elements and influence the cycling of carbon and eventual efflux of carbon dioxide to the atmosphere. This project will examine the nature, extent and effect of these redox processes in selected subsurface environments. This research could have implications for contaminant transformation and fate and carbon cycling.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0882836
Funder
Australian Research Council
Funding Amount
$160,000.00
Summary
A novel isotope facility to characterise high-molecular-weight fractions of natural organic matter in soils, sediments, water, petroleum and coal. This facility will improve our ability to forecast environmental responses to future climate change, and help Australia manage current threats to its biodiversity. Furthermore, this research will increase the ability to identify crude oil sources, to the benefit of petroleum exploration in Australia. This facility will also contribute to an improved u ....A novel isotope facility to characterise high-molecular-weight fractions of natural organic matter in soils, sediments, water, petroleum and coal. This facility will improve our ability to forecast environmental responses to future climate change, and help Australia manage current threats to its biodiversity. Furthermore, this research will increase the ability to identify crude oil sources, to the benefit of petroleum exploration in Australia. This facility will also contribute to an improved understanding of controls on water quality and will help to protect our precious freshwater resources, already under intense pressure from climate change. Importantly, this project will enable students and young professionals to be trained in state-of-the-art technology, leading to quality scientists ready for employment in industry.
Read moreRead less
Unsaturated zone functioning in a semi-arid flash flood driven climate. Groundwater is the only perennial water source in arid and semiarid zones, which encompass 1/3 of the global landmass and 70 % of Australia. We still do not fully understand how the unsaturated zone contributes to groundwater recharge in semi-arid zone floodplains. We will study the dynamics of soil moisture, and its contribution to groundwater recharge respective to hydrological regimes and weather patterns. We will measure ....Unsaturated zone functioning in a semi-arid flash flood driven climate. Groundwater is the only perennial water source in arid and semiarid zones, which encompass 1/3 of the global landmass and 70 % of Australia. We still do not fully understand how the unsaturated zone contributes to groundwater recharge in semi-arid zone floodplains. We will study the dynamics of soil moisture, and its contribution to groundwater recharge respective to hydrological regimes and weather patterns. We will measure direct responses to flood events using loggers and compare them to indirect measurements inferred from hydrochemical and isotope tracer models to better understand recharge patterns, evaporative losses, and interactions between surface runoff, floodplains, and aquifers at different positions in the landscape.Read moreRead less
New perspectives on iron oxide transformations in oxic and anoxic aqueous environments: implications for iron bioavailability and contaminant mobility. Transformations in the form and reactivity of iron oxides in oxic and anoxic aqueous environments are considerably more dynamic than previously thought. This project will examine the nature and extent of these transformations and elucidate their impact on supply of iron to organisms and mobility of uranium and arsenic in groundwaters.