Unlocking the secrets of the groundwater cycle using Si and Li isotopes. This project aims to determine how non-conventional lithium and silicon isotopes can be used to understand groundwater processes using an innovative source-to-target approach. The project aims to apply these isotope tracers to trace the water cycle within a well constrained system: an island aquifer with a dense borefield which has been analysed using traditional isotopic techniques. Supporting hydrochemical data will be us ....Unlocking the secrets of the groundwater cycle using Si and Li isotopes. This project aims to determine how non-conventional lithium and silicon isotopes can be used to understand groundwater processes using an innovative source-to-target approach. The project aims to apply these isotope tracers to trace the water cycle within a well constrained system: an island aquifer with a dense borefield which has been analysed using traditional isotopic techniques. Supporting hydrochemical data will be used to determine the relationship of the isotopes with environmental processes. The project impact will be the development of new methods to help understand our groundwater resource. The improved process understanding will be translated to groundwater management in general. The projects' focus on carbonate aquifer systems typical of coastal regions of southern, eastern and western Australia will have relevance to groundwater management in urban areas such as Perth and in rural areas for tourism and viticulture, and for management of natural resources in National Parks.Read moreRead less
New perspectives on arsenic speciation and fate in anoxic aqueous environments: Resolving unexplored interactions with the sulfur cycle. Using exciting new experiments and innovative analyses, this project will provide transformational insights into how sulfur cycling in the Earth’s critical zone affects arsenic speciation and fate. The project will resolve, for the first time, unexplored interactions between arsenic geochemistry and the low-temperature formation and transformation of metastable ....New perspectives on arsenic speciation and fate in anoxic aqueous environments: Resolving unexplored interactions with the sulfur cycle. Using exciting new experiments and innovative analyses, this project will provide transformational insights into how sulfur cycling in the Earth’s critical zone affects arsenic speciation and fate. The project will resolve, for the first time, unexplored interactions between arsenic geochemistry and the low-temperature formation and transformation of metastable iron sulfide minerals. The outcomes will provide crucially important new perspectives on arsenic geochemistry in anoxic soils, sediments and groundwater systems.Read moreRead less
Interactions between antimony and the sulphur cycle. This project aims to unravel unexplored interactions between the sulphur cycle and fundamentally important aspects of antimony geochemistry in the Earth’s critical zone. This project will resolve interactions between antimony geochemistry and the low-temperature formation and transformation of metastable iron sulphide minerals. The outcomes are expected to provide crucially important perspectives on antimony geochemistry in anoxic soils, sedim ....Interactions between antimony and the sulphur cycle. This project aims to unravel unexplored interactions between the sulphur cycle and fundamentally important aspects of antimony geochemistry in the Earth’s critical zone. This project will resolve interactions between antimony geochemistry and the low-temperature formation and transformation of metastable iron sulphide minerals. The outcomes are expected to provide crucially important perspectives on antimony geochemistry in anoxic soils, sediments and groundwater systems. This understanding should lead to more accurate geochemical risk assessments and better site treatment strategies for environmental antimony contamination.Read moreRead less
Reactive oxygen species production on oxygenation of subsurface sediments. This project aims to examine the nature, extent and effect of redox processes in subsurface environments. Reactive oxygen species, including hydrogen peroxide, superoxide and hydroxyl radicals, transform and affect redox-active substances in the environment such as arsenic, uranium and natural organic matter (which may be oxidised to carbon dioxide). Production of significant quantities of reactive oxygen species on oxyge ....Reactive oxygen species production on oxygenation of subsurface sediments. This project aims to examine the nature, extent and effect of redox processes in subsurface environments. Reactive oxygen species, including hydrogen peroxide, superoxide and hydroxyl radicals, transform and affect redox-active substances in the environment such as arsenic, uranium and natural organic matter (which may be oxidised to carbon dioxide). Production of significant quantities of reactive oxygen species on oxygenation of subsurface sediments through actions such as aquifer recharge and high flow events may alter the form and mobility of trace elements and influence the cycling of carbon and eventual efflux of carbon dioxide to the atmosphere. This project will examine the nature, extent and effect of these redox processes in selected subsurface environments. This research could have implications for contaminant transformation and fate and carbon cycling.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0882836
Funder
Australian Research Council
Funding Amount
$160,000.00
Summary
A novel isotope facility to characterise high-molecular-weight fractions of natural organic matter in soils, sediments, water, petroleum and coal. This facility will improve our ability to forecast environmental responses to future climate change, and help Australia manage current threats to its biodiversity. Furthermore, this research will increase the ability to identify crude oil sources, to the benefit of petroleum exploration in Australia. This facility will also contribute to an improved u ....A novel isotope facility to characterise high-molecular-weight fractions of natural organic matter in soils, sediments, water, petroleum and coal. This facility will improve our ability to forecast environmental responses to future climate change, and help Australia manage current threats to its biodiversity. Furthermore, this research will increase the ability to identify crude oil sources, to the benefit of petroleum exploration in Australia. This facility will also contribute to an improved understanding of controls on water quality and will help to protect our precious freshwater resources, already under intense pressure from climate change. Importantly, this project will enable students and young professionals to be trained in state-of-the-art technology, leading to quality scientists ready for employment in industry.
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New perspectives on iron oxide transformations in oxic and anoxic aqueous environments: implications for iron bioavailability and contaminant mobility. Transformations in the form and reactivity of iron oxides in oxic and anoxic aqueous environments are considerably more dynamic than previously thought. This project will examine the nature and extent of these transformations and elucidate their impact on supply of iron to organisms and mobility of uranium and arsenic in groundwaters.
Environmental controls over Fe availability and transport in a forested coastal catchment. Iron is one of a number of elements that are mobilised in catchments, have recognised detrimental impacts to marine settings and are known to be nutrients for toxic cyanobacteria blooms. Knowledge of controls over distribution of Fe is important in catchment management and for sustainable forestry. The total catchment approach will result in an understanding of release and transport of Fe, and other heav ....Environmental controls over Fe availability and transport in a forested coastal catchment. Iron is one of a number of elements that are mobilised in catchments, have recognised detrimental impacts to marine settings and are known to be nutrients for toxic cyanobacteria blooms. Knowledge of controls over distribution of Fe is important in catchment management and for sustainable forestry. The total catchment approach will result in an understanding of release and transport of Fe, and other heavy metals. The outcomes of the study will enable useful comparison to coastal plantations elsewhere in Australia, and overseas. Determination of the relationship to rainfall and hydrological processes will enhance these comparisons plus consideration of climatic change.
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Chemical optimisation of geothermal heat extraction. Geothermal energy can contribute to our energy needs, but we must understand chemical interactions between geothermal fluids, the host aquifers and the engineered environment to use the energy safely and efficiently. This project will assess those interactions, provide guidelines for geothermal energy use and train future geothermal scientists.
Resolving the geochemistry of coastal floodplain blackwaters. Deoxygenated dead zones are a rapidly growing global crisis in coastal areas. A major cause of dead zones in our estuaries is the formation and release of blackwaters from coastal wetlands. This project will provide the knowledge necessary to manage blackwaters in these wetlands and to greatly improve the health and sustainability of our estuaries.
Redox transformations of natural organic matter. This project aims to determine the electron transfer (redox) properties of terrestrially and microbially-derived natural organic matter (NOM) and the implications of these redox characteristics to reactive oxygen species generation, metals transformation and carbon cycling. Experimental and computational studies using model compounds containing quinone and thiol-containing functional groups as well as well-characterised humic substances and algal ....Redox transformations of natural organic matter. This project aims to determine the electron transfer (redox) properties of terrestrially and microbially-derived natural organic matter (NOM) and the implications of these redox characteristics to reactive oxygen species generation, metals transformation and carbon cycling. Experimental and computational studies using model compounds containing quinone and thiol-containing functional groups as well as well-characterised humic substances and algal exudates will be undertaken under both dark and light conditions. Kinetic models of these processes will be developed enabling prediction of the impact of NOM-mediated electron transfer processes on oxidant generation, metals transformation and carbon cycling.Read moreRead less