High Performance Monolithic Perovskite Photocapacitors. Monolithic perovskite photocapacitor (MPPC) consisted of integrated energy harvesting perovskite solar cell and energy storage supercapacitor through an internally shared electrode can deliver stable electricity by harnessing solar energy. The performance of MPPC is dependent of properties of the shared electrode materials. This project aims to synthesis carbon materials with tailored surface, electrical and structure properties that are re ....High Performance Monolithic Perovskite Photocapacitors. Monolithic perovskite photocapacitor (MPPC) consisted of integrated energy harvesting perovskite solar cell and energy storage supercapacitor through an internally shared electrode can deliver stable electricity by harnessing solar energy. The performance of MPPC is dependent of properties of the shared electrode materials. This project aims to synthesis carbon materials with tailored surface, electrical and structure properties that are required to make a highly functioning shared electrode in MPPC. The goal is to fabricate stable, high performance MPPC. Successful achievement of the outcomes will enable cost-effective, reliable, solar electricity, placing Australia at the forefront of exploiting photovoltaics technologies.Read moreRead less
Corrosion of heat resisting alloys in steam/hydrogen-rich environment . Hydrogen is a clean fuel for energy future. Its production and utilisation unavoidably involve water vapour and hydrogen at high temperature which is however corrosive to materials used in the system. This project aims to investigate corrosion behaviour of heat resistant alloys in the presence of both hydrogen and water vapour, mechanisms of water transport in oxide scale, and the effect of hydrogen on water vapour corrosion ....Corrosion of heat resisting alloys in steam/hydrogen-rich environment . Hydrogen is a clean fuel for energy future. Its production and utilisation unavoidably involve water vapour and hydrogen at high temperature which is however corrosive to materials used in the system. This project aims to investigate corrosion behaviour of heat resistant alloys in the presence of both hydrogen and water vapour, mechanisms of water transport in oxide scale, and the effect of hydrogen on water vapour corrosion. Alloying effects on corrosion rates will be defined and methods of slowing or preventing water vapour corrosion in the presence of hydrogen will be devised. The results will provide a basis for improved design/selection of heat resisting alloys for hydrogen production and hydrogen utilisation industries.Read moreRead less
Solid Oxide Electrolysis Cells with Novel Perovskite-based Cathode. The electrochemical reduction of CO2 and steam to value-added fuels in a high-temperature solid oxide electrolysis cell (SOEC) is practically promising, but technologically challenging. This project aims to develop next generation SOECs using a perovskite-based cathode and scale-up engineering for rapid, bulk production of H2, CO and syngas fuels. Expected outcomes include material engineering, new knowledge on energy conversion ....Solid Oxide Electrolysis Cells with Novel Perovskite-based Cathode. The electrochemical reduction of CO2 and steam to value-added fuels in a high-temperature solid oxide electrolysis cell (SOEC) is practically promising, but technologically challenging. This project aims to develop next generation SOECs using a perovskite-based cathode and scale-up engineering for rapid, bulk production of H2, CO and syngas fuels. Expected outcomes include material engineering, new knowledge on energy conversion technology, and advanced manufacturing technologies. The success of the project will provide a practical solution to reduce fossil CO2 emissions and potential technology for hydrogen production. These will significantly aid Australia in important climate goals and ambitions.Read moreRead less
Efficient photovoltaic-electrochemical water splitting for clean hydrogen. This project aims to develop a novel, low cost and high performance monolithic photovoltaic-electrochemical (PV-EC) device for clean hydrogen production. This device tailors and integrates low cost and high performance thin film and tandem photovoltaics for water splitting with the aim of achieving high solar to hydrogen conversion efficiency towards 20%. Earth abundant and stable catalysts will be developed in this proje ....Efficient photovoltaic-electrochemical water splitting for clean hydrogen. This project aims to develop a novel, low cost and high performance monolithic photovoltaic-electrochemical (PV-EC) device for clean hydrogen production. This device tailors and integrates low cost and high performance thin film and tandem photovoltaics for water splitting with the aim of achieving high solar to hydrogen conversion efficiency towards 20%. Earth abundant and stable catalysts will be developed in this project to replace noble based catalysts, as well as novel architectures for electrical contacting, feed-through and catalyst integration in PV-EC devices. These innovations offer high performance and the potential for device costs 2 to 3 orders of magnitude lower than recent world record photoelectrochemical devices. Read moreRead less
Defect control for high-performance green kesterites energy materials. This project will tackle the fundamental challenge of defect control of the quaternary compound kesterite, revolutionizing the way we can understand the hidden defect-evolution process and design accordingly effective defect-control approaches. This will be realized by a systematic approach integrating multiscale materials characterization, process and materials modeling, and linking microscopic local chemical potential and m ....Defect control for high-performance green kesterites energy materials. This project will tackle the fundamental challenge of defect control of the quaternary compound kesterite, revolutionizing the way we can understand the hidden defect-evolution process and design accordingly effective defect-control approaches. This will be realized by a systematic approach integrating multiscale materials characterization, process and materials modeling, and linking microscopic local chemical potential and macroscopic processing conditions, and associated compound properties and device performance to control defects evolution. Successfully achieved, this project will realize full potential of kesterite in photovoltaic and photoelectrochemical applications, and leading to new discoveries in other compound energy materials.Read moreRead less
Ultrathin III-V Solar Cells via Crack-Assisted Layer Exfoliation. III-V semiconductors are excellent photovoltaic materials with highest demonstrated solar-to-electricity conversion efficiencies, but find limited usage in terrestrial applications due to high material and fabrication costs. This project aims to improve the cost-effectiveness of III-V solar cells by developing ultrathin III-V semiconductors via crack-assisted layer transfer approach and epitaxy-free fabrication via heterojunction ....Ultrathin III-V Solar Cells via Crack-Assisted Layer Exfoliation. III-V semiconductors are excellent photovoltaic materials with highest demonstrated solar-to-electricity conversion efficiencies, but find limited usage in terrestrial applications due to high material and fabrication costs. This project aims to improve the cost-effectiveness of III-V solar cells by developing ultrathin III-V semiconductors via crack-assisted layer transfer approach and epitaxy-free fabrication via heterojunction architectures, paving the way for cost-effective, high-efficiency, flexible solar cells. The expected outcomes include a disruptive technology for integrated photovoltaics, novel contact and passivation materials, as well as new knowledge generated in materials science and optoelectronics disciplines.Read moreRead less
Efficient, durable and green chalcopyrite solar powered building steel. This project aims to develop a long-life, stable, high-performance, and green chalcopyrite solar powered building steel, which is expected to offer a shapable truly green building integrated photovoltaic (BIPV) product for building deployment. This will be realized by synergising multidiscipline expertise, integrating established technologies of steel surface treatment, steel and solar cell integration and shaping, high-effi ....Efficient, durable and green chalcopyrite solar powered building steel. This project aims to develop a long-life, stable, high-performance, and green chalcopyrite solar powered building steel, which is expected to offer a shapable truly green building integrated photovoltaic (BIPV) product for building deployment. This will be realized by synergising multidiscipline expertise, integrating established technologies of steel surface treatment, steel and solar cell integration and shaping, high-efficiency chalcopyrite, identified strategies for tackling its durability and toxicity, and advanced macro-to-micro characterizations. The project completion will accelerate the transition to the zero-emission building, establish Australia's excellence in green steel for BIPV, and access a share in the soaring BIPV market.Read moreRead less
Tailoring smart film for energy efficient protected cropping. Cooling cost represents a major running cost for greenhouse, preventing the wide adoption of highly beneficial protected cropping technology. This project aims at solving this critical issue by developing a world-first tailored smart film that can simultaneously reject solar heat, cool down the greenhouse and maximise the yields of crops. This is made possible by advanced spectral engineering and light management with frontier nanostr ....Tailoring smart film for energy efficient protected cropping. Cooling cost represents a major running cost for greenhouse, preventing the wide adoption of highly beneficial protected cropping technology. This project aims at solving this critical issue by developing a world-first tailored smart film that can simultaneously reject solar heat, cool down the greenhouse and maximise the yields of crops. This is made possible by advanced spectral engineering and light management with frontier nanostructures combined with a scalable and low cost manufacturing process. Deliverables of the project include game-changing energy efficient solutions for protected cropping and marketable smart films readily integratable with existing greenhouse for dramatic energy saving and immediate economic and social benefits.Read moreRead less
A systems materials engineering strategy for hybrid ion capacitors. This project aims to develop a data science-driven approach to allow the use of materials systems engineering strategy to quantify the cell-level design of electrochemical energy storage devices such as hybrid ion capacitors. The intended outcomes of this project include new dynamic equivalent circuit models and a new quantitative approach to make the electrodes pairing predictable and realise their optimal design against the ne ....A systems materials engineering strategy for hybrid ion capacitors. This project aims to develop a data science-driven approach to allow the use of materials systems engineering strategy to quantify the cell-level design of electrochemical energy storage devices such as hybrid ion capacitors. The intended outcomes of this project include new dynamic equivalent circuit models and a new quantitative approach to make the electrodes pairing predictable and realise their optimal design against the needs of the specific applications. It will also demonstrate a combined strategy of data science and discipline-specific experiments and theories to advance the emerging field of materials systems engineering. Read moreRead less