Pioneering stable copper carbanions for new C-C bond forming paradigms. The stabilisation of highly reactive carbanions underpins advances in chemical synthesis of new compounds including polymers, agrichemicals and pharmaceuticals. This project aims to deliver an innovative chemical reactivity platform, underpinned by copper carbanion complexes accessed via synthetic electrochemistry. Carbanions are essential components of carbon-carbon bond forming reactions but their high reactivity can be pr ....Pioneering stable copper carbanions for new C-C bond forming paradigms. The stabilisation of highly reactive carbanions underpins advances in chemical synthesis of new compounds including polymers, agrichemicals and pharmaceuticals. This project aims to deliver an innovative chemical reactivity platform, underpinned by copper carbanion complexes accessed via synthetic electrochemistry. Carbanions are essential components of carbon-carbon bond forming reactions but their high reactivity can be problematic. Expected outcomes of this project are an understanding of why these novel copper compounds are stable and how they can be utilised as synthetic reagents. This should provide significant benefits in unlocking the synthetic potential of a new class of chemical compound that has until now remained unexplored.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE220101577
Funder
Australian Research Council
Funding Amount
$446,639.00
Summary
Two-Dimensional Covalent Organic Framework for Next-Generation Batteries. This project aims to develop advanced two-dimensional (2D) covalent organic framework (COF) materials for sodium and potassium-ion batteries. It expects to generate a new family of few-layered 2D COF materials and their 2D-2D heterostructured composites with improved electrochemical properties, and develop processing technologies and fundamental understanding of COF-based electrodes for flexible sodium and potassium-ion ba ....Two-Dimensional Covalent Organic Framework for Next-Generation Batteries. This project aims to develop advanced two-dimensional (2D) covalent organic framework (COF) materials for sodium and potassium-ion batteries. It expects to generate a new family of few-layered 2D COF materials and their 2D-2D heterostructured composites with improved electrochemical properties, and develop processing technologies and fundamental understanding of COF-based electrodes for flexible sodium and potassium-ion batteries. Expected outcomes include novel materials, technologies, and energy-storage options for Australia. Significant economic and environmental benefits are expected from developing advanced sodium and potassium-ion batteries with low cost, high energy density, and improved safety for renewable energy storage.Read moreRead less
New biosensing strategies based on bipolar electrochemiluminescence. Chemical analysis is a vital activity in our society, which is to a large extent confined to scientific laboratories and carried out with complex instrumentation. The breakthrough technology envisioned in this proposal will pave the way for simple, low-cost tests which can be used by non-scientists. The development of small, portable sensors for applications ranging from pollution monitoring to health testing, will enable ordi ....New biosensing strategies based on bipolar electrochemiluminescence. Chemical analysis is a vital activity in our society, which is to a large extent confined to scientific laboratories and carried out with complex instrumentation. The breakthrough technology envisioned in this proposal will pave the way for simple, low-cost tests which can be used by non-scientists. The development of small, portable sensors for applications ranging from pollution monitoring to health testing, will enable ordinary people to gain knowledge about the concentrations of molecular compounds in their environments and in themselves. This will stimulate economic and social benefits related to environmental testing and early disease diagnosis and generate new commercial opportunities for the Australian biotechnology industry.Read moreRead less
Australian Laureate Fellowships - Grant ID: FL170100101
Funder
Australian Research Council
Funding Amount
$2,843,970.00
Summary
Towards sustainable electrochemical energy storage technology. This project aims to address fundamental issues on electrochemical energy storage technology using sodium-ion capacitors, by designing novel electrode materials and utilising advanced, in-situ and ex-situ instrumental techniques in combination with modern computational simulation methods. The project will lead to a complete understanding of the charge storage mechanism and transport kinetics in sodium-ion capacitors, providing guide ....Towards sustainable electrochemical energy storage technology. This project aims to address fundamental issues on electrochemical energy storage technology using sodium-ion capacitors, by designing novel electrode materials and utilising advanced, in-situ and ex-situ instrumental techniques in combination with modern computational simulation methods. The project will lead to a complete understanding of the charge storage mechanism and transport kinetics in sodium-ion capacitors, providing guidelines for developing sustainable electrochemical energy storage technology. The project expects to generate new knowledge in energy storage including capacity building, training of young scientists, and intellectual property with potential commercialised products.Read moreRead less
Chlorine Evolution Catalysts for Efferent Seawater Electrolysis. Seawater is the most abundant aqueous resource on earth that is readily accessible at very low costs, but yet to be directly utilised for production of hydrogen fuel and commodity chemicals. This project aims to develop cheap and plentiful carbon-based high performance chlorine evolution electrocatalysts for seawater electrolysis powered by renewable electricity to realise the production of hydrogen, chlorine and sodium hydroxide d ....Chlorine Evolution Catalysts for Efferent Seawater Electrolysis. Seawater is the most abundant aqueous resource on earth that is readily accessible at very low costs, but yet to be directly utilised for production of hydrogen fuel and commodity chemicals. This project aims to develop cheap and plentiful carbon-based high performance chlorine evolution electrocatalysts for seawater electrolysis powered by renewable electricity to realise the production of hydrogen, chlorine and sodium hydroxide directly from seawater. The electrolyser can also be used to treat desalination brine while produce hydrogen and chemicals. The success of the project will set a firm technological foundation for seawater utilisation, which will add to Australian capability to meet future energy and environment challenges.Read moreRead less