An investigation of the mechanism of lacquer adhesion failure on electrolytic tinplate. "Tin" cans used for food packaging are actually made from tin-plated steel and, in most cases, the metal is coated with a lacquer. This lacquer is required to protect the can from corrosion and the contents from taint. The incidence of adhesion failure between the metal and the lacquer has increased recently for unknown reasons, causing considerable economic loss. This project will investigate the mechanisms ....An investigation of the mechanism of lacquer adhesion failure on electrolytic tinplate. "Tin" cans used for food packaging are actually made from tin-plated steel and, in most cases, the metal is coated with a lacquer. This lacquer is required to protect the can from corrosion and the contents from taint. The incidence of adhesion failure between the metal and the lacquer has increased recently for unknown reasons, causing considerable economic loss. This project will investigate the mechanisms of adhesion failure and improve our fundamental understanding of the problem. The results will be used to enable the selection of process conditions and lacquers that are more robust and reduce the incidence of adhesion failure.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0347258
Funder
Australian Research Council
Funding Amount
$170,000.00
Summary
Polymer Analysis Facility. The aim of this application is to establish a facility for polymer analysis. The infra-red spectrometer will be used primarily for analysis of polymerisation reactions whilst the thermal analysis equipment is essential for the characterisation of polymers and thin polymer coatings. The facility will contribute an essential analysis capability for three strong research groups who work in different aspects of polymer science. The main outcomes will improved productivity ....Polymer Analysis Facility. The aim of this application is to establish a facility for polymer analysis. The infra-red spectrometer will be used primarily for analysis of polymerisation reactions whilst the thermal analysis equipment is essential for the characterisation of polymers and thin polymer coatings. The facility will contribute an essential analysis capability for three strong research groups who work in different aspects of polymer science. The main outcomes will improved productivity within the current projects together with new collaborations, particularly between the Steel Institute (ISPP) at Wollongong and the Centre of Advanced Molecular Design (CAMD) at UNSW.Read moreRead less
Mechanisms in Catalytic Chain Transfer Polymerization. The aim of the proposed research is to gain more insight into the mechanisms underlying catalytic chain transfer polymerization, a relatively recent controlled radical polymerization technique which is finding an increasing number of industrial applications, especially in the paint and coatings industry. An improved understanding of the catalytic chain transfer process, of which some very important features are still poorly understood, will ....Mechanisms in Catalytic Chain Transfer Polymerization. The aim of the proposed research is to gain more insight into the mechanisms underlying catalytic chain transfer polymerization, a relatively recent controlled radical polymerization technique which is finding an increasing number of industrial applications, especially in the paint and coatings industry. An improved understanding of the catalytic chain transfer process, of which some very important features are still poorly understood, will ultimately lead to better catalyst design and improved process and product control. This in turn will lead to novel polymeric materials.Read moreRead less
Nano-scale Modification of Paint Surfaces for Contamination Resistance. The main aim of this work is to develop a process to produce a dirt resistant paint surface. Dirt resistance is an important characteristic of prepainted steel sheets often used in architectural situations where dirt build-up is unsightly. To develop the process it will be necessary to understand the mechanism of dirt adhesion to paints and the modes of operation of current dirt resistant processes. In addition work will be ....Nano-scale Modification of Paint Surfaces for Contamination Resistance. The main aim of this work is to develop a process to produce a dirt resistant paint surface. Dirt resistance is an important characteristic of prepainted steel sheets often used in architectural situations where dirt build-up is unsightly. To develop the process it will be necessary to understand the mechanism of dirt adhesion to paints and the modes of operation of current dirt resistant processes. In addition work will be required on the rate of surface segregation of additives to the paint solution. We propose to combine experimental and theoretical modelling approaches to obtain a fundamentally sound practical solution.Read moreRead less
Reversible Addition Fragmentation Chain Transfer (RAFT) Free Radical Copolymerizations of Various Monomers. The proposed project will investigate the structure and properties of statistical copolymers prepared via living free radical polymerization. We will study the characteristics of a wide variety of Reversible Addition Fragmentation Chain Transfer (RAFT) copolymerizations using a range of monomers, including those interesting for biomedical and material science applications. We expect to gai ....Reversible Addition Fragmentation Chain Transfer (RAFT) Free Radical Copolymerizations of Various Monomers. The proposed project will investigate the structure and properties of statistical copolymers prepared via living free radical polymerization. We will study the characteristics of a wide variety of Reversible Addition Fragmentation Chain Transfer (RAFT) copolymerizations using a range of monomers, including those interesting for biomedical and material science applications. We expect to gain a deeper understanding of the influence of the RAFT process on the kinetics and mechanism of copolymerization and the properties of the resulting polymers in order to tailor specific polymer materials for biomedial applications.Read moreRead less
Accessing Chain Length Dependent Rate Coefficients in Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerisations. The proposed project combines two exciting research areas, namely the chain length dependencies of kinetic coefficients and reversible addition fragmentation chain transfer (RAFT) polymerisations. The starting point of the project will be a novel technique recently invented by our team for termination rate measurement utilizing the RAFT process. Detailed knowledge of cha ....Accessing Chain Length Dependent Rate Coefficients in Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerisations. The proposed project combines two exciting research areas, namely the chain length dependencies of kinetic coefficients and reversible addition fragmentation chain transfer (RAFT) polymerisations. The starting point of the project will be a novel technique recently invented by our team for termination rate measurement utilizing the RAFT process. Detailed knowledge of chain length dependent rate coefficients in both homo- and copolymerisations is essential from both an academic and industrial perspective, because polymerisation kinetics not only govern the reaction rates but influence directly the polymeric material properties.Read moreRead less