Polymers for Novel Surfactants. The aim of the proposed research is to develop novel surface-active polymers with complex architectures and more efficient strategies for the synthesis of surface-active polymers in general. We will exploit the polymerization characteristics of the novel catalytic chain transfer and radical addition-fragmentation transfer polymerization techniques to achieve polymerization control that has been virtually impossible hitherto. The proposed research will thus make ....Polymers for Novel Surfactants. The aim of the proposed research is to develop novel surface-active polymers with complex architectures and more efficient strategies for the synthesis of surface-active polymers in general. We will exploit the polymerization characteristics of the novel catalytic chain transfer and radical addition-fragmentation transfer polymerization techniques to achieve polymerization control that has been virtually impossible hitherto. The proposed research will thus make accessible a wide range of novel surface-active polymers that have been impossible to synthesise to date, and which we expect to be more efficient and hence leads to greener technologies.
Read moreRead less
Novel Complex Architecture Polymers via a Combination of RAFT Chemistry and Pericyclic Reactions: Synthesis and Characterization. The project aims at advancing the synthetic limits and broadening the synthetic scope of living free radical polymerization and thus enhancing the library of polymer structures available for applications ranging from drug delivery to opto-electronics. Current material design for these applications is yet to reach its full potential through innovative synthetic approac ....Novel Complex Architecture Polymers via a Combination of RAFT Chemistry and Pericyclic Reactions: Synthesis and Characterization. The project aims at advancing the synthetic limits and broadening the synthetic scope of living free radical polymerization and thus enhancing the library of polymer structures available for applications ranging from drug delivery to opto-electronics. Current material design for these applications is yet to reach its full potential through innovative synthetic approaches. The proposal critically underpins and further advances Australia's leading position in both breakthrough science as well as advanced materials. Due to its significant scientific breadth and large coverage of both synthetic and physical aspects of polymer science, the project also provides a significant platform for research training at both honours and PhD level.Read moreRead less
Janus particles and nanorattles: new materials for paint technology. This project will pave the way for self cleaning paints that achieve opacity with greatly reduced titanium dioxide levels. Painted surfaces will maintain their clean and new look for longer and a clean town look will be much more readily maintained. More efficient use of titanium dioxide will reduce the need for sand mining and reduce the cost of quality paint.
Polymer micro-capsules for stain-resistant paint. This project aims to create an advanced micro-capsule system to be used in the manufacturing of high-performance waterborne paints on a large scale. Surface coatings seal, strengthen, and decorate the majority of surfaces in the building industry. Despite their importance, advances in paint science have only been incremental and a truly stain-resistant, robust and environmentally friendly coating has yet to be developed. This project will use pol ....Polymer micro-capsules for stain-resistant paint. This project aims to create an advanced micro-capsule system to be used in the manufacturing of high-performance waterborne paints on a large scale. Surface coatings seal, strengthen, and decorate the majority of surfaces in the building industry. Despite their importance, advances in paint science have only been incremental and a truly stain-resistant, robust and environmentally friendly coating has yet to be developed. This project will use polymer Janus nanoparticles to radically redesign architectural coatings, with the goal to reduce the use of non-renewable components, and increase stain-resistance and durability. This new technology will lead to less disruption for the environment, and important economic and technological benefits for Australia.Read moreRead less
Key Functional Additives in Paint Technology. The goal of this project is to create two novel advanced particle systems with complex architecture that can be manufactured on a large scale, which aim to lead to high-performance waterborne paints. It is intended that these paints will have three functional characteristics: provide more efficient use of titanium dioxide; display pronounced water-resistance; and contribute to removing the need for organic solvents from the gloss paint sector. This r ....Key Functional Additives in Paint Technology. The goal of this project is to create two novel advanced particle systems with complex architecture that can be manufactured on a large scale, which aim to lead to high-performance waterborne paints. It is intended that these paints will have three functional characteristics: provide more efficient use of titanium dioxide; display pronounced water-resistance; and contribute to removing the need for organic solvents from the gloss paint sector. This research aims to provide the means to create paint films with greatly improved properties at reduced cost, with reduced requirement for non-renewable resources and reduced environmental footprint.Read moreRead less
Polymer nanoparticles with gradient morphology for environmentally friendly aqueous coatings applications. The commercial and practical importance of coatings (paints) in today’s society can hardly be overstated. With the ongoing drive towards more environmentally friendly coating systems, there is a strong desire to replace traditionally employed solvent-based coatings with entirely waterborne systems. Waterborne coatings are a key measure by which the coating industry can meet requirements to ....Polymer nanoparticles with gradient morphology for environmentally friendly aqueous coatings applications. The commercial and practical importance of coatings (paints) in today’s society can hardly be overstated. With the ongoing drive towards more environmentally friendly coating systems, there is a strong desire to replace traditionally employed solvent-based coatings with entirely waterborne systems. Waterborne coatings are a key measure by which the coating industry can meet requirements to reduce emission of volatile organic compounds. However, maximum performance cannot be achieved currently using waterborne coatings, which in turn limits applications. The overall aim of this project is to develop environmentally friendly high-performance waterborne coatings that will enable replacement of currently employed solvent-based systems.Read moreRead less
Polymer nanofibres for advanced paint formulations. Surface coatings seal, strengthen, and decorate the majority of surfaces in the building industry—a $72 billion market. Despite their importance, advances in paint science have only been incremental and a truly robust and water resistant paint coating has yet to be developed. Dulux Group Australia and the University of Sydney will use polymer nanofibres as additives to radically redesign architectural coatings, with the goal to drastically incr ....Polymer nanofibres for advanced paint formulations. Surface coatings seal, strengthen, and decorate the majority of surfaces in the building industry—a $72 billion market. Despite their importance, advances in paint science have only been incremental and a truly robust and water resistant paint coating has yet to be developed. Dulux Group Australia and the University of Sydney will use polymer nanofibres as additives to radically redesign architectural coatings, with the goal to drastically increase their durability. The partnership will bring a technological breakthrough that will lead to less disruption for the environment, and important economic and technological benefits for Australia.Read moreRead less
Nanogels: Next Generation Polymeric Particles. The existing knowledge in the formation of polymeric networks limits the technological development of polymer materials. This project will introduce new polymeric particles, called nanogels to open a new area in new polymeric architecture research. A number of new structures based on the nanogels will be developed. These new macromolecules will not only bring the polymer science into a new field, it will provide a great opportunity to discover the ....Nanogels: Next Generation Polymeric Particles. The existing knowledge in the formation of polymeric networks limits the technological development of polymer materials. This project will introduce new polymeric particles, called nanogels to open a new area in new polymeric architecture research. A number of new structures based on the nanogels will be developed. These new macromolecules will not only bring the polymer science into a new field, it will provide a great opportunity to discover the next generation of the polymeric products, particularly for application in automotive paint, drug delivery and bio-molecular separations.Read moreRead less
Nanoparticles with designed morphology for surface-coating applications. Significantly improved water-based paints, with zero volatile organic content and organic opacifiers, are highly desirable for environmental and health reasons. The science needed to produce such paints has been persistently elusive. USyd and Dulux will collaborate to achieve these paints by using Australian-developed platform technologies that allow polymer architecture to be controlled at molecular and nanoscale levels. T ....Nanoparticles with designed morphology for surface-coating applications. Significantly improved water-based paints, with zero volatile organic content and organic opacifiers, are highly desirable for environmental and health reasons. The science needed to produce such paints has been persistently elusive. USyd and Dulux will collaborate to achieve these paints by using Australian-developed platform technologies that allow polymer architecture to be controlled at molecular and nanoscale levels. This will give us the means to make structured nanoparticles with morphologies that had been regarded as unachievable, and that are the key to dispensing with harmful ingredients in paints.Read moreRead less
Pro-Fluorescent Aryl Nitroxides: New Probes for Polymer Lifetime and Kinetics Research. Internal aryl rings present in novel probes developed for this project impart fluorescence which is efficiently and internally quenched by the presence of a paramagnetic nitroxide group. Scavenging of radicals by the nitroxide however "switches on" the fluorescence and this enables powerful new fluorescence-based detection levels for the technique of nitroxide free radical scavenging. Such sensitivity is a ....Pro-Fluorescent Aryl Nitroxides: New Probes for Polymer Lifetime and Kinetics Research. Internal aryl rings present in novel probes developed for this project impart fluorescence which is efficiently and internally quenched by the presence of a paramagnetic nitroxide group. Scavenging of radicals by the nitroxide however "switches on" the fluorescence and this enables powerful new fluorescence-based detection levels for the technique of nitroxide free radical scavenging. Such sensitivity is applicable to polymerization kinetics studies, as well as providing new means for the determination of materials lifetimes. The development of pro-fluorescent markers as indicators for polymer degradation would be a significant outcome for materials where component failure has a major negative impact.Read moreRead less