THE FIRST DEVELOPMENT OF MULTI-DIMENSIONAL SPECTRO-ELECTROCHEMISTRY AND ITS APPLICATION TO CRUCIAL TRANSFORMATIONS IN INORGANIC SYSTEMS. Electrolysis is a very widespread and efficient method of chemical synthesis both in industry and research. However, the link between the control voltage and the resultant current is often complicated and easily misinterpreted. To overcome this fundamental problem, we propose an optical spectro-electrochemistry instrument based on a two-dimensional CCD detectio ....THE FIRST DEVELOPMENT OF MULTI-DIMENSIONAL SPECTRO-ELECTROCHEMISTRY AND ITS APPLICATION TO CRUCIAL TRANSFORMATIONS IN INORGANIC SYSTEMS. Electrolysis is a very widespread and efficient method of chemical synthesis both in industry and research. However, the link between the control voltage and the resultant current is often complicated and easily misinterpreted. To overcome this fundamental problem, we propose an optical spectro-electrochemistry instrument based on a two-dimensional CCD detection array. This radically new approach enables simultaneous spectroscopic and spatial data mapping in the realm adjacent to an electrode surface. Important applications range from unequivocal identification of elusive molecules to monitoring metal corrosion. Our first objective is to elucidate certain crucial transformations of mono- and binuclear heavy metal complexes.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0560818
Funder
Australian Research Council
Funding Amount
$154,000.00
Summary
A Pico-Newton Scale Force Measurement Apparatus for Polymer Physics and Non-equilibrium Statistical Mechanics. We propose to build a state-of-the-art Optical Tweezers apparatus that measures small forces and torques on micron-sized objects located in 'optical traps'. Using a single laser beam and computer-generated holograms, we will create arrays of optical traps that move or 'dance', and alter the force/torque-imposing properties of each trap. This proposed research equipment will be used (1 ....A Pico-Newton Scale Force Measurement Apparatus for Polymer Physics and Non-equilibrium Statistical Mechanics. We propose to build a state-of-the-art Optical Tweezers apparatus that measures small forces and torques on micron-sized objects located in 'optical traps'. Using a single laser beam and computer-generated holograms, we will create arrays of optical traps that move or 'dance', and alter the force/torque-imposing properties of each trap. This proposed research equipment will be used (1) to study the physics of single synthetic polymer and naturally occuring biopolymer chains, (2) to quantify experimentally, and for the first time, newly predicted molecular-scale forces, and (3) to demonstrate new theories in non-equilibrium statistical mechanics that quantitatively describe the operation of nanomachines. Read moreRead less
New methods assisting the detection and attribution of changes in atmospheric carbon dioxide (CO2) levels. New scientific tools to manage the global environment are an international priority. An Australian breakthrough in technology has the potential to revolutionise the measurement and management of atmospheric carbon dioxide, the single largest anthropogenic contributor to greenhouse warming. The fellowship levers sufficient resources to assess this potential in a number of critical applicatio ....New methods assisting the detection and attribution of changes in atmospheric carbon dioxide (CO2) levels. New scientific tools to manage the global environment are an international priority. An Australian breakthrough in technology has the potential to revolutionise the measurement and management of atmospheric carbon dioxide, the single largest anthropogenic contributor to greenhouse warming. The fellowship levers sufficient resources to assess this potential in a number of critical applications, including: early detection of predicted increases in Southern Ocean carbon dioxide emission; indefinite low cost monitoring of regional carbon flux changes over continental Australia; improved international standards for CO2 measurement; and improved manufacturing components for use world-wide in trace-gas measurement.Read moreRead less
Dynamic Force Microscopy of small molecular assemblies. The possibility of manipulating a single molecule seems at first unreal, indeed 5 years ago it was pure science fiction. Through the gaining popularity of the Atomic Force Microscope (AFM) many perspectives about the molecular world are changing. Macroscopic effects such as adhesion and lubrication are now discussed in light of measurements made with this instrument. Newer work includes the observation of single protein unfolding experim ....Dynamic Force Microscopy of small molecular assemblies. The possibility of manipulating a single molecule seems at first unreal, indeed 5 years ago it was pure science fiction. Through the gaining popularity of the Atomic Force Microscope (AFM) many perspectives about the molecular world are changing. Macroscopic effects such as adhesion and lubrication are now discussed in light of measurements made with this instrument. Newer work includes the observation of single protein unfolding experiments. The biophysics oriented project detailed in this application will extend the AFM: into multi-molecular systems formed by self-assembly, such as cell membranes; into polyelectrolyte-surface interactions; and, finally into the sequencing of DNA.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0560868
Funder
Australian Research Council
Funding Amount
$552,475.00
Summary
SHRIMP SI - Microscale stable-isotope analysis in the Earth Sciences. Stable-isotope variations of elements such as oxygen, carbon, and sulphur, preserve the most profound records of environmental conditions during the geological, biological, and climatic evolution of Earth and planets. We will build a stable isotope ion microprobe (SHRIMP SI) to examine extraterrestrial and terrestrial systems in unprecedented detail. In terrestrial applications, the main issue is accuracy at the 0.01 percent ....SHRIMP SI - Microscale stable-isotope analysis in the Earth Sciences. Stable-isotope variations of elements such as oxygen, carbon, and sulphur, preserve the most profound records of environmental conditions during the geological, biological, and climatic evolution of Earth and planets. We will build a stable isotope ion microprobe (SHRIMP SI) to examine extraterrestrial and terrestrial systems in unprecedented detail. In terrestrial applications, the main issue is accuracy at the 0.01 percent level for 20-micron spots, which we can apply to studies of development of life on Earth, climatic records, weathering, and formation of ore bodies. Sample return missions of solar wind and comets will provide unique samples related to the formation of our solar system.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0453320
Funder
Australian Research Council
Funding Amount
$347,886.00
Summary
Advanced Spectroscopy for Nano-characterisation of Materials Chemistry and Properties. This application proposes to establish a cutting-edge spectroscopic facility which includes; electron energy-loss spectroscopy (EELS), energy-dispersive X-ray spectroscopy (EDS), cathodoluminescence (CL), photoluminescence (PL) and micro-Raman spectroscopy. Each of the spectrometers to be installed has significantly higher sensitivity and resolution than any other facility available in Australia and is capable ....Advanced Spectroscopy for Nano-characterisation of Materials Chemistry and Properties. This application proposes to establish a cutting-edge spectroscopic facility which includes; electron energy-loss spectroscopy (EELS), energy-dispersive X-ray spectroscopy (EDS), cathodoluminescence (CL), photoluminescence (PL) and micro-Raman spectroscopy. Each of the spectrometers to be installed has significantly higher sensitivity and resolution than any other facility available in Australia and is capable of full spectrum imaging. This new spectroscopic infrastructure will enable the knowledge-based development of new materials by allowing complete characterisation of structure-composition-property relationships at the nanometre level.Read moreRead less
Pre-blast screening of improvised explosive devices - a National counter-terrorism initiative. The proposed research is focused on the specific needs of Australian counter-terrorism interests, including those of border protection, the customs service, transport authorities, forensic laboratories, etc. The support of this proposal will ensure that Australia, and its States and Territories are protected against terrorist threats. The support provided by the collaborating organisations from the var ....Pre-blast screening of improvised explosive devices - a National counter-terrorism initiative. The proposed research is focused on the specific needs of Australian counter-terrorism interests, including those of border protection, the customs service, transport authorities, forensic laboratories, etc. The support of this proposal will ensure that Australia, and its States and Territories are protected against terrorist threats. The support provided by the collaborating organisations from the various Federal and State police and forensic agencies, and the customs service, etc, highlights the importance of this project to the nation. Finally, a PhD student and a research assistant will be involved with the project and will gain specialised skills positioning them to make strong contributions to Australia's counter-terrorism measures.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0237527
Funder
Australian Research Council
Funding Amount
$170,000.00
Summary
Bioscope IV : Advanced Scanned Probe Microscopy. The Atomic Force Microscope presents a unique view of the microscopic and molecular world, for it is sensitive to force alone. This instrument can accurately map force over a surface at the molecular scale; picoNewtons at nanometre resolution. The host of intermolecular forces which cause phenomena such as self-assembly, colloid stability, cell interactions and friction are only directly measurable with this technique. In this field of force meas ....Bioscope IV : Advanced Scanned Probe Microscopy. The Atomic Force Microscope presents a unique view of the microscopic and molecular world, for it is sensitive to force alone. This instrument can accurately map force over a surface at the molecular scale; picoNewtons at nanometre resolution. The host of intermolecular forces which cause phenomena such as self-assembly, colloid stability, cell interactions and friction are only directly measurable with this technique. In this field of force measurement Australian researchers are leaders. The proposed instrument expands the capabilities of this effort, and develops exciting new directions including the direct manipulation of molecules through a novel feedback and control (haptic) interface.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0454207
Funder
Australian Research Council
Funding Amount
$311,381.00
Summary
New Technology to Fight Crime and Terrorism: Laser Ablation Inductively Coupled Plasma Mass Spectrometer Facilities (LA-ICP-MS). Australia urgently needs new technologies to prevent and fight crime and terrorism. This equipment will address current outstanding problems in forensic science and related disciplines, namely the requirement to (1) analyse minute quantities of samples, (2) differentiate samples with similar matrices but trace differences, (3) analyse solid samples that are difficult t ....New Technology to Fight Crime and Terrorism: Laser Ablation Inductively Coupled Plasma Mass Spectrometer Facilities (LA-ICP-MS). Australia urgently needs new technologies to prevent and fight crime and terrorism. This equipment will address current outstanding problems in forensic science and related disciplines, namely the requirement to (1) analyse minute quantities of samples, (2) differentiate samples with similar matrices but trace differences, (3) analyse solid samples that are difficult to analyse by current techniques. This equipment is also vital for research which will improve the justice system, the quality of food and health products and increase industry competitiveness through novel industrial and environmental testing. Acquiring this infrastructure will safeguard and ensure Australia's continuing prosperity.Read moreRead less
Molecular Fingerprinting: Forensic Spectroscopy of Trace Gases. Safeguarding Australia from terrorism, crime and invasive diseases is essential to securing our national infrastructure. This project will develop national capabilities in anticipating and responding to critical threats to society. The scientific instrumentation developed from this effort will enhance Australia's potential aid for early detection of explosive and chemical weaponry and also in the analysis of crime scenes. This rese ....Molecular Fingerprinting: Forensic Spectroscopy of Trace Gases. Safeguarding Australia from terrorism, crime and invasive diseases is essential to securing our national infrastructure. This project will develop national capabilities in anticipating and responding to critical threats to society. The scientific instrumentation developed from this effort will enhance Australia's potential aid for early detection of explosive and chemical weaponry and also in the analysis of crime scenes. This research will significantly improve our abilities to maintain the operational advantage of Australia's security agencies through superior capabilities in threat detection.Read moreRead less