Discovery Early Career Researcher Award - Grant ID: DE200100421
Funder
Australian Research Council
Funding Amount
$427,116.00
Summary
A New Breed of Metallosupramolecular Assembly. Self-assembly is the ready formation of complex structures from simple components. Nature uses this to generate its most impressive molecular machinery to carry out complex tasks. Metallosupramolecular chemists combine simple components (metal ions and organic ligands) to create synthetic variants to fulfil similar roles. Current methods have limitations, and this project aims to create a new structural type: large and controllably variable metallo- ....A New Breed of Metallosupramolecular Assembly. Self-assembly is the ready formation of complex structures from simple components. Nature uses this to generate its most impressive molecular machinery to carry out complex tasks. Metallosupramolecular chemists combine simple components (metal ions and organic ligands) to create synthetic variants to fulfil similar roles. Current methods have limitations, and this project aims to create a new structural type: large and controllably variable metallo-foldamers (structures consisting of metal ions and ligands that coil like DNA). As well as benefiting fundamental knowledge, these molecules will be functional. They are expected to improve performance with enhanced outcomes in photophysical, photochemical, catalytic, and sensing applications.Read moreRead less
Faster interfacial electron transfer: the effect of molecule shape and size. This project aims to explore the effect of shape and size of pi-conjugated molecules on interfacial electron transfer reactions, which are fundamentally important in all applications of photo-electrochemical conversion and storage of energy. By making two series of pi-conjugated molecules and determining electron transfer rates using a combination of transient spectroscopies and computational chemistry, the project expe ....Faster interfacial electron transfer: the effect of molecule shape and size. This project aims to explore the effect of shape and size of pi-conjugated molecules on interfacial electron transfer reactions, which are fundamentally important in all applications of photo-electrochemical conversion and storage of energy. By making two series of pi-conjugated molecules and determining electron transfer rates using a combination of transient spectroscopies and computational chemistry, the project expects to generate new design principles for molecules with the potential to significantly improve the efficiencies of solar energy conversion and photo-catalytic processes. The new materials and findings will be exploited in a novel redox-mediated water splitting device as a practical outcome with potential end user benefits.Read moreRead less
Luminophores and photochromes: towards molecular componentry. This project aims to enhance current knowledge of luminogenic and photochromic molecules, including self-assembled structures, and materials composed thereof, by constructing a computationally guided compound library. Translation of primary outcomes towards utility in emerging technologies including passive light harvesting from transparent surfaces, bio-sensors and photo-responsive devices will be pursued in collaboration with both a ....Luminophores and photochromes: towards molecular componentry. This project aims to enhance current knowledge of luminogenic and photochromic molecules, including self-assembled structures, and materials composed thereof, by constructing a computationally guided compound library. Translation of primary outcomes towards utility in emerging technologies including passive light harvesting from transparent surfaces, bio-sensors and photo-responsive devices will be pursued in collaboration with both academia and industry. The expected outcomes from this project include the creation of opportunities to explore the manufacture and commercialisation of high-value products with Australian industry. This will provide significant benefits, such as reduction in the carbon footprint of homes, businesses and other applicable structures due to passive power generation, while creating jobs and up-skilling the workforce.Read moreRead less
Nano-fibrous structure for high-performance organic photovoltaic thin films. This project aims to create nano-fibrous active thin films with high charge mobility for organic photovoltaic (OPV) devices, using a method inspired by molecular gelation. The significance of this project is that it addresses a major bottleneck, i.e. poor charge generation and transport, that limits the efficiency of OPV devices. The outcomes will provide insights into the crucial factors that affect the self-assembly o ....Nano-fibrous structure for high-performance organic photovoltaic thin films. This project aims to create nano-fibrous active thin films with high charge mobility for organic photovoltaic (OPV) devices, using a method inspired by molecular gelation. The significance of this project is that it addresses a major bottleneck, i.e. poor charge generation and transport, that limits the efficiency of OPV devices. The outcomes will provide insights into the crucial factors that affect the self-assembly of organic semiconducting materials, and the influences of nano-fibrous structure on the charge mobility and efficiency of an OPV device. The outcomes will greatly facilitate the development of highly efficient, lightweight and low-cost solar energy harvesting devices to reduce our carbon footprint.Read moreRead less
Elucidating the morphology of organic semiconductors at an atomic level. Controlling morphology and self-organization at a molecular level is key to advancing the performance of optoelectronic devices such as organic light-emitting diodes and organic photovoltaic cells. Current device development relies on a costly and inefficient empirical design cycle (material synthesis followed by device fabrication and testing). In addition, the active layers often involve multiple components and their nano ....Elucidating the morphology of organic semiconductors at an atomic level. Controlling morphology and self-organization at a molecular level is key to advancing the performance of optoelectronic devices such as organic light-emitting diodes and organic photovoltaic cells. Current device development relies on a costly and inefficient empirical design cycle (material synthesis followed by device fabrication and testing). In addition, the active layers often involve multiple components and their nano-scale morphology is difficult to probe experimentally. Recently developed molecular simulation techniques can provide unique insight into atomic-level structural details that determine device efficiency. The project will determine if such simulations are sufficiently accurate to be industrially useful.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE240100004
Funder
Australian Research Council
Funding Amount
$762,800.00
Summary
Ultrafast Infrared Spectroscopy Facility. The Ultrafast Infrared Spectroscopy Facility will provide a suite of techniques spanning the visible to mid-infrared spectral regions, on time scales corresponding to the emission of light, and energy conversion in low energy advanced functional materials. Research performed with this equipment will include photonic and thermal energy conversion; nanophotonics; quantum technologies and new infrared functional materials. This facility will enhance capacit ....Ultrafast Infrared Spectroscopy Facility. The Ultrafast Infrared Spectroscopy Facility will provide a suite of techniques spanning the visible to mid-infrared spectral regions, on time scales corresponding to the emission of light, and energy conversion in low energy advanced functional materials. Research performed with this equipment will include photonic and thermal energy conversion; nanophotonics; quantum technologies and new infrared functional materials. This facility will enhance capacity in probing new materials and devices in the near and mid-infrared regions, and will increase institutional and cross-disciplinary research collaboration.Read moreRead less
Mid-Career Industry Fellowships - Grant ID: IM230100090
Funder
Australian Research Council
Funding Amount
$1,053,046.00
Summary
Multi material 3D Printing. This project aims to further develop a new 3D printing technique commercialised by an Australian start-up company. Current electronics manufacturing is extremely capital intensive, slow and restrictive in 3D design. The 3D printing method proposed in this application will disrupt the current advanced manufacturing eco system; creating unique methods to unlock advances in diverse markets for example, photovoltaics, printed circuit boards and sensors. The expected outco ....Multi material 3D Printing. This project aims to further develop a new 3D printing technique commercialised by an Australian start-up company. Current electronics manufacturing is extremely capital intensive, slow and restrictive in 3D design. The 3D printing method proposed in this application will disrupt the current advanced manufacturing eco system; creating unique methods to unlock advances in diverse markets for example, photovoltaics, printed circuit boards and sensors. The expected outcomes of this project are to create new commercial opportunities for the next generation of 3D printed electronics. This will provide significant benefits, creating unique capability to manufacture devices in 3D - faster, cheaper and with reduced reliance on global supply chains.Read moreRead less
Data-driven development of photocatalytic and optoelectronic perovskites. This project aims to use materials informatics to discover new, high efficiency perovskites for synthesis and testing in optoelectronic applications. This project expects to identify perovskite composition-property relationships to overcome current drawbacks of high performance perovskites (contain rare or toxic elements and low stability in oxidative and humid environments) by considered selection of elements and their pr ....Data-driven development of photocatalytic and optoelectronic perovskites. This project aims to use materials informatics to discover new, high efficiency perovskites for synthesis and testing in optoelectronic applications. This project expects to identify perovskite composition-property relationships to overcome current drawbacks of high performance perovskites (contain rare or toxic elements and low stability in oxidative and humid environments) by considered selection of elements and their properties. Expected outcomes from this project include new perovskites with commercial potential in critical areas such as energy conversion, photocatalysis and luminescence. This should provide significant benefits including approaches to materials discovery, novel materials and in renewable energy and environmental areas.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE230100382
Funder
Australian Research Council
Funding Amount
$449,154.00
Summary
Charge and Energy Transfer Processes at Inorganic-Organic Interfaces . The integration of functional molecular materials with inorganic systems remains an outstanding hurdle to achieve durable, highly efficient optoelectronic devices. This project aims to develop and understand this new class of devices, with a focus on directional energy transfer processes across hybrid interfaces. This project expects to generate new knowledge in photovoltaics (PV) and for organic light emitting diodes (OLEDs) ....Charge and Energy Transfer Processes at Inorganic-Organic Interfaces . The integration of functional molecular materials with inorganic systems remains an outstanding hurdle to achieve durable, highly efficient optoelectronic devices. This project aims to develop and understand this new class of devices, with a focus on directional energy transfer processes across hybrid interfaces. This project expects to generate new knowledge in photovoltaics (PV) and for organic light emitting diodes (OLEDs) by studying triplet transfer in two model systems. The first will be a step towards the development of advanced PV devices using down-conversion to push solar cells beyond the efficiency barrier. The second will demonstrate inorganic-organic solid state up-conversion for next generation OLEDs with improved stability.Read moreRead less
Charge and energy transport in disordered functional materials. This project aims to understand how energy and electric charge move through disordered materials. Many next-generation materials—including organic semiconductors, hybrid perovskites, and conductive metal-organic frameworks—promise better solar cells, sensors, and electrocatalysts; however, they remain incompletely understood because they are disordered and noisy systems that are difficult to describe mathematically. This project exp ....Charge and energy transport in disordered functional materials. This project aims to understand how energy and electric charge move through disordered materials. Many next-generation materials—including organic semiconductors, hybrid perovskites, and conductive metal-organic frameworks—promise better solar cells, sensors, and electrocatalysts; however, they remain incompletely understood because they are disordered and noisy systems that are difficult to describe mathematically. This project expects to develop the first theoretical techniques that capture all essential features of transport in disordered materials. The resulting understanding of structure-function relationships should accelerate the rational design of cutting-edge devices for energy conversion and storage.Read moreRead less