Polymer Inclusion Membranes for Electrokinetic Sampling and Separation. This proposal aims to understand the chemical and physical properties governing the transport of ions into and within advanced extracting polymeric materials, known as polymer inclusion membranes, under the influence of an applied voltage. These membranes are dry-to-touch and represent a new and potentially powerful analytical platform for environmental, medical and industry sample preparation. By understanding the transport ....Polymer Inclusion Membranes for Electrokinetic Sampling and Separation. This proposal aims to understand the chemical and physical properties governing the transport of ions into and within advanced extracting polymeric materials, known as polymer inclusion membranes, under the influence of an applied voltage. These membranes are dry-to-touch and represent a new and potentially powerful analytical platform for environmental, medical and industry sample preparation. By understanding the transport mechanism, new membranes will be developed, capable of purifying and concentrating diverse targets chemicals from liquid and solid samples. These processes can take place during sample transportation to a centralised laboratory thus simplifying and streamlining analysis upon arrival to decrease drastically its costs.Read moreRead less
Carbon Molecular Sieve Membranes for Organic Solvent Separation. Directly addressing the pressing challenge of organic solvent separation faced by numerous industries, the project aims to develop molecular sieve membranes with outstanding selectivity and solvent tolerance by constructing zeolite-carbon mixed matrix membrane via incorporating zeolite nanosheets into carbon materials. The project expects to generate advanced knowledge of nanosheet synthesis, membrane fabrication and selective mole ....Carbon Molecular Sieve Membranes for Organic Solvent Separation. Directly addressing the pressing challenge of organic solvent separation faced by numerous industries, the project aims to develop molecular sieve membranes with outstanding selectivity and solvent tolerance by constructing zeolite-carbon mixed matrix membrane via incorporating zeolite nanosheets into carbon materials. The project expects to generate advanced knowledge of nanosheet synthesis, membrane fabrication and selective molecule transport. The membranes developed in the project have great potentials for improving the production capacity and sustainability of Australian industries, e.g., pharmaceutical manufacturing, bioethanol production and petroleum refining, providing significant economic and environmental benefits to Australia.Read moreRead less
Crystal engineering of membranes for chiral separation . This project addresses the urgent challenge of chiral separation in the manufacturing of pharmaceuticals and agrochemicals by creating a new class of membranes produced by engineering functionalised porous framework crystals. This project expects to generate new knowledge regarding how membrane chemistry and architecture can be used to achieve highly selective, fast chiral molecule transport. The expected outcomes of the project include ne ....Crystal engineering of membranes for chiral separation . This project addresses the urgent challenge of chiral separation in the manufacturing of pharmaceuticals and agrochemicals by creating a new class of membranes produced by engineering functionalised porous framework crystals. This project expects to generate new knowledge regarding how membrane chemistry and architecture can be used to achieve highly selective, fast chiral molecule transport. The expected outcomes of the project include new membrane compositions, design principles, fabrication techniques, and proof-of-concept production of scalable, high-performance composite membranes. This project should produce significant economic and environmental benefits in the development of advanced membranes, pharmaceuticals, and agrochemicals.Read moreRead less
Unlocking the ion selectivity of lithium superionic conductor membranes. This project aims to address a longstanding challenge in designing advanced membranes to enable sustainable lithium refining by unlocking the ion selectivity of lithium superionic conductors. This project expects to generate new knowledge in the areas of membrane science and emerging nanoionics by using interdisciplinary approaches. Expected outcomes of this project include a novel class of lithium separation membranes and ....Unlocking the ion selectivity of lithium superionic conductor membranes. This project aims to address a longstanding challenge in designing advanced membranes to enable sustainable lithium refining by unlocking the ion selectivity of lithium superionic conductors. This project expects to generate new knowledge in the areas of membrane science and emerging nanoionics by using interdisciplinary approaches. Expected outcomes of this project include a novel class of lithium separation membranes and their fabrication techniques. This should provide significant benefits in improving lithium extraction and recycling efficiency, reducing their environmental impact and building the research capacity in advanced membrane manufacturing and critical mineral refining in Australia. Read moreRead less
Regulating guest transport in microporous materials by electric field. This project aims to address the fundamentals and applications of regulating micropore accessibility. It has long been known that some highly adsorbing molecular sieves suddenly become inaccessible to gases below certain temperatures. Following a recent breakthrough in elucidating the mechanism of such temperature-regulated guest admission, this project will explore electrical regulation of micropore accessibility in conjunct ....Regulating guest transport in microporous materials by electric field. This project aims to address the fundamentals and applications of regulating micropore accessibility. It has long been known that some highly adsorbing molecular sieves suddenly become inaccessible to gases below certain temperatures. Following a recent breakthrough in elucidating the mechanism of such temperature-regulated guest admission, this project will explore electrical regulation of micropore accessibility in conjunction with developing new mechanisms, materials, and control tools for applications, including tunable molecular sieves, valves and gas encapsulation devices. The outcomes of this project will generate new knowledge in the active manipulation of the admission and release of guest molecules in/out of microporous materials, and establish new expertise and capabilities that can advance gas separation, storage and sensing technologies. It is expected that this project will contribute to the long term benefit in low emission energy supplies and Australia's natural gas industry, improve the separation efficiency of our chemical industry, and boost the development of the hydrogen economy.Read moreRead less
The evolution of specialised orchid pollination and its reversibility. This project aims to determine the changes in key floral volatile compounds underpinning pollination transitions, identify their molecular basis, and understand the ecological processes favouring reversals away from extreme specialisation. By focusing on pollination of sexually deceptive Australian orchids, this project would be the first to determine the molecular, chemical and behavioural basis of evolutionary reversals to ....The evolution of specialised orchid pollination and its reversibility. This project aims to determine the changes in key floral volatile compounds underpinning pollination transitions, identify their molecular basis, and understand the ecological processes favouring reversals away from extreme specialisation. By focusing on pollination of sexually deceptive Australian orchids, this project would be the first to determine the molecular, chemical and behavioural basis of evolutionary reversals to more generalised strategies in a group of plants facing high risk of pollinator extinction. The expected outcome, a mechanistic understanding of how pollination transitions occur, would be internationally ground-breaking, and provide crucial insights to protect this diverse but highly threatened group of plants.Read moreRead less
Advanced separators for lithium-sulphur batteries. This project aims to develop new membranes for use as separators in lithium-sulphur batteries. Currently diffusion of polysulphides within these batteries reduces battery power and lifetime. The new membranes are intended to block polysulphide diffusion over an extended lifetime, while transporting the other ions needed for the battery to function. The project is expected to generate new membrane materials and further knowledge about the design, ....Advanced separators for lithium-sulphur batteries. This project aims to develop new membranes for use as separators in lithium-sulphur batteries. Currently diffusion of polysulphides within these batteries reduces battery power and lifetime. The new membranes are intended to block polysulphide diffusion over an extended lifetime, while transporting the other ions needed for the battery to function. The project is expected to generate new membrane materials and further knowledge about the design, synthesis and larger-scale production of membranes for electrochemical applications. This project will provide significant benefits by producing potentially lighter, longer-lasting and cheaper batteries than existing lithium-ion technologies, with the potential to accelerate the adoption of electric cars.Read moreRead less
Mapping, modelling, and manipulating graphene oxide interfaces. This project aims to provide a platform for the controllable manipulation of graphene oxide in water and with additives. Graphene oxide-based materials promise transformative change in the areas of filtration, separation science, energy materials and specialty coatings. Expansion of these materials into this broad range of high-performance applications is limited by the lack of reliable control over the organisation of the graphene ....Mapping, modelling, and manipulating graphene oxide interfaces. This project aims to provide a platform for the controllable manipulation of graphene oxide in water and with additives. Graphene oxide-based materials promise transformative change in the areas of filtration, separation science, energy materials and specialty coatings. Expansion of these materials into this broad range of high-performance applications is limited by the lack of reliable control over the organisation of the graphene oxide sheets in solution and in the presence of additives. This project will identify the practical steps for controlling the inter-sheet spacing in graphene oxide stacks, which is critical to realising their potential in real-world applications such as in filtration membranes for water desalination. This project will provide significant benefits in making reliable energy materials and filtration and separation membranes.Read moreRead less
Smart foliage: imparting intelligence to synthetic leaves. This project aims to develop an innovative “lab-on-a-leaf” platform technology based on smart membranes with switchable pores to enable hitherto unachievable control of gas and vapour transfer. The innovated membrane based technology can be used as a versatile platform for many important applications, such as desalination and carbon capture. This project expects to advance the knowledge in biomimetic design of synthetic leaves, and bring ....Smart foliage: imparting intelligence to synthetic leaves. This project aims to develop an innovative “lab-on-a-leaf” platform technology based on smart membranes with switchable pores to enable hitherto unachievable control of gas and vapour transfer. The innovated membrane based technology can be used as a versatile platform for many important applications, such as desalination and carbon capture. This project expects to advance the knowledge in biomimetic design of synthetic leaves, and bring new membrane technologies to applications, such as desalination, solar energy harvesting, and evaporative cooling. This project should provide significant benefits for Australian manufacturing industry by addressing energy and environmental concerns and boosting national economic growth.Read moreRead less
Overcoming performance limiting chemistries in membrane distillation. This project aims to study performance limiting chemistries associated with fouling of solution-borne components on membrane surfaces that cause critical vapour pressure loss. Membrane distillation could be used for sustainable resource recovery, but no research has overcome the total loss of membrane water flux when removing water from saturated solutions where the critical resource recovery function occurs. This project will ....Overcoming performance limiting chemistries in membrane distillation. This project aims to study performance limiting chemistries associated with fouling of solution-borne components on membrane surfaces that cause critical vapour pressure loss. Membrane distillation could be used for sustainable resource recovery, but no research has overcome the total loss of membrane water flux when removing water from saturated solutions where the critical resource recovery function occurs. This project will characterise the physical and chemical properties of the flux limiting solid on the membrane surface, and the role of membrane chemistry and functional conditions in overcoming this limit. The outcomes of the work will provide innovative sustainable solutions to recover valuable products from current wastes.Read moreRead less