Perovskite-Based Ferroelectrics for Solar Fuel Production. This project aims to develop perovskite-based ferroelectrics for photocatalytic carbon dioxide reduction to produce solar fuels. It is expected to reveal the relationship of ferroelectric polarisation and photocatalytic behaviour, thereby promoting solar energy utilisation and greenhouse gas reduction. Expected outcomes include delivery of a novel family of chemically and structurally controlled ferroelectrics and catalytic reaction prot ....Perovskite-Based Ferroelectrics for Solar Fuel Production. This project aims to develop perovskite-based ferroelectrics for photocatalytic carbon dioxide reduction to produce solar fuels. It is expected to reveal the relationship of ferroelectric polarisation and photocatalytic behaviour, thereby promoting solar energy utilisation and greenhouse gas reduction. Expected outcomes include delivery of a novel family of chemically and structurally controlled ferroelectrics and catalytic reaction prototypes for efficient carbon dioxide photoreduction, and in-depth understanding of structure-performance correlation to guide future polar catalysts design. This project should provide significant benefits in minimising fossil fuel consumption, increasing energy security, and expanding clean energy industry.Read moreRead less
Monolithic Solar Thermal Photocatalytic Membrane for Hydrogen Production. This ambitious project aims to develop a new concept of monolithic membranes composed of photocatalysts embedded in highly efficient solar thermal graphene. Such a membrane will be first of its kind and is able to utilise full solar spectrum for scalable seawater desalination and direct splitting to produce hydrogen without the need to concentrate sunlight. Expected outcomes include chemically and structurally tailored mem ....Monolithic Solar Thermal Photocatalytic Membrane for Hydrogen Production. This ambitious project aims to develop a new concept of monolithic membranes composed of photocatalysts embedded in highly efficient solar thermal graphene. Such a membrane will be first of its kind and is able to utilise full solar spectrum for scalable seawater desalination and direct splitting to produce hydrogen without the need to concentrate sunlight. Expected outcomes include chemically and structurally tailored membranes and 2D floating prototypes for real life hydrogen production, and in-depth understanding of working mechanism to facilitate up-scaled renewable hydrogen generation. Significant benefits in minimising fossil fuel consumption, increasing energy security, and expanding competitive clean energy industry are promised.Read moreRead less
Solar-driven thermochemical dissociation of carbon dioxide and water to produce carbon-neutral fuels. The biggest challenge to humanity of the century is to develop enabling clean energy resources to encounter rapidly diminished fossil fuel and accelerated global warming conditions. This project will offer a solution by developing a unique solar-driven thermochemical system capable of cleaving carbon dioxide and water to produce artificial syngas.
Rechargeable lithium carbon dioxide battery - catalyst design to prototype . This project aims to develop a new concept of rechargeable lithium carbon dioxide batteries and scaled-up prototypes. Such a battery will be first of its kind to show high power comparable to gasoline and superior rechargeability over existing gas-involved batteries, ensuring realistic use for industrial purposes. Expected outcomes include 2-dimensional catalysts made from earth-abundant elements lowering large-scale pr ....Rechargeable lithium carbon dioxide battery - catalyst design to prototype . This project aims to develop a new concept of rechargeable lithium carbon dioxide batteries and scaled-up prototypes. Such a battery will be first of its kind to show high power comparable to gasoline and superior rechargeability over existing gas-involved batteries, ensuring realistic use for industrial purposes. Expected outcomes include 2-dimensional catalysts made from earth-abundant elements lowering large-scale production cost, a novel but reliable working principle based on reversible carbon dioxide/oxalate conversion, and prototypes featuring high specific capacity, large energy density and excellent durability. Via industrial pilot trials, commercial benefits will be fast tracked for energy security and carbon dioxide utilisation.Read moreRead less
Single-atom catalysts for electrochemical carbon dioxide conversion. This project aims to develop a new synthetic technique for the fabrication of template-free and metal single-atoms embedded in doped carbon nano tubes. It will generate fundamental knowledge about multiple proton and electron transfer steps in carbon dioxide (CO2RR) using in-situ synchrotron characterisation techniques. Expected outcomes of the research include the development of new single-atom catalysts for production of the ....Single-atom catalysts for electrochemical carbon dioxide conversion. This project aims to develop a new synthetic technique for the fabrication of template-free and metal single-atoms embedded in doped carbon nano tubes. It will generate fundamental knowledge about multiple proton and electron transfer steps in carbon dioxide (CO2RR) using in-situ synchrotron characterisation techniques. Expected outcomes of the research include the development of new single-atom catalysts for production of the key feed-stock of CO for sustainable use in hydrocarbon fuels, providing significant benefits in the reduction of greenhouse emissions.Read moreRead less
Scale-up of catalytic furandicarboxylic acid production at room temperature. This project will use new knowledge acquired from our laboratory-scale discoveries to develop a new process feasible for industrial-scale production of 2,5-furandicarboxylic acid (FDCA). The method makes FDCA, a platform chemical for future chemical industry, from a completely renewable source derived from plant sugars, 5-hydroxymethyl-furfural. This is an essential process for production of biodegradable plastic from s ....Scale-up of catalytic furandicarboxylic acid production at room temperature. This project will use new knowledge acquired from our laboratory-scale discoveries to develop a new process feasible for industrial-scale production of 2,5-furandicarboxylic acid (FDCA). The method makes FDCA, a platform chemical for future chemical industry, from a completely renewable source derived from plant sugars, 5-hydroxymethyl-furfural. This is an essential process for production of biodegradable plastic from sugar that has not been commercialised. This technology will realise sizeable industrial-scale production of FDCA at low costs and without heating. The production development of this valuable commodity from renewable plant sugars will provide high-quality postgraduate training in future green chemical production methods.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE210101259
Funder
Australian Research Council
Funding Amount
$360,000.00
Summary
A predictive, ab initio design of enhanced plasmonic photocatalysts. Plasmonic catalysis is a promising platform for sunlight-driven chemical reactions that employs optically absorptive plasmonic-metal/semiconductor nanostructures. However, it suffers from poor external quantum efficiencies. The aim of this project is to rationally design an efficient plasmonic photocatalyst utilizing state-of-the-art ab initio computations. The project is expected to provide insights on various atomic-level rea ....A predictive, ab initio design of enhanced plasmonic photocatalysts. Plasmonic catalysis is a promising platform for sunlight-driven chemical reactions that employs optically absorptive plasmonic-metal/semiconductor nanostructures. However, it suffers from poor external quantum efficiencies. The aim of this project is to rationally design an efficient plasmonic photocatalyst utilizing state-of-the-art ab initio computations. The project is expected to provide insights on various atomic-level reaction steps involved and consequently develop a set of catalyst design principles to guide experiments. The project will largely benefit Australia’s and international renewable energy sector and chemical industries by generating knowledge in catalysis relevant for hydrogen production and greenhouse gas reduction. Read moreRead less