An Integrated Synthetic and NMR Spectroscopic Study of Photochemical Organometallic Bond Activation. Modifications of alkanes and related processes under study will occupy the heart of next generation catalysed chemical processes that may ultimately be used globally on a vast scale. A detailed knowledge of mechanism is the precursor to rational design and improvement of catalysed processes, making them more efficient and greener. This will allow better usage of Australia's natural gas and preci ....An Integrated Synthetic and NMR Spectroscopic Study of Photochemical Organometallic Bond Activation. Modifications of alkanes and related processes under study will occupy the heart of next generation catalysed chemical processes that may ultimately be used globally on a vast scale. A detailed knowledge of mechanism is the precursor to rational design and improvement of catalysed processes, making them more efficient and greener. This will allow better usage of Australia's natural gas and precious metal resources and benefit local chemical companies. Specialized new NMR technology that will greatly aid a wide range of local researchers will be developed to facilitate these studies. The researchers of the future will also be trained.Read moreRead less
Advanced Molecular Frameworks for Sodium Battery Electrode Applications. This project aims to develop new molecular materials capable of high capacity sodium-ion insertion. Through an innovative interdisciplinary approach that targets the synthesis and detailed characterisation of an extensive family of materials this project expects to generate major advances in the understanding of how the chemical, physical and structural attributes of the materials relate to their electrical charge/discharge ....Advanced Molecular Frameworks for Sodium Battery Electrode Applications. This project aims to develop new molecular materials capable of high capacity sodium-ion insertion. Through an innovative interdisciplinary approach that targets the synthesis and detailed characterisation of an extensive family of materials this project expects to generate major advances in the understanding of how the chemical, physical and structural attributes of the materials relate to their electrical charge/discharge behaviours. Significant anticipated outcomes and benefits include the development of new material design approaches that optimise battery electrode performance across a diverse parameter space, and the generation of advanced new materials worthy of commercial development in low-cost, large-scale battery applications.Read moreRead less
Emergent properties in spin crossover materials. This project aims to develop ‘intelligent’ materials in which emergent properties arise due to the strategic combination of spin switching with other functionalities. Spin crossover is a versatile form of molecular switch which can reversibly change structure, colour and magnetism using convenient external stimuli. In probing new and interesting forms of interplay between technologically relevant properties, this work addresses the science of host ....Emergent properties in spin crossover materials. This project aims to develop ‘intelligent’ materials in which emergent properties arise due to the strategic combination of spin switching with other functionalities. Spin crossover is a versatile form of molecular switch which can reversibly change structure, colour and magnetism using convenient external stimuli. In probing new and interesting forms of interplay between technologically relevant properties, this work addresses the science of host-guest and electronic/magnetic systems and could lead to materials worthy of commercial development to underpin a range of future high-level technologies spanning low energy separations, molecular sensing, data storage, and electronic/magnetic/optical device componentry.Read moreRead less
Molecular switching nanomaterials for modern technology. This project aims to develop a new class of functional materials with integrated molecular switching capacity. Molecule-based switching materials are actively pursued in cutting-edge sensory, information storage and nanophotonic devices. This project expects to drive the advancement of modern memory-switching device and sensor technologies. An expected outcome of this project is to define a new sophisticated class of nanomaterials with in ....Molecular switching nanomaterials for modern technology. This project aims to develop a new class of functional materials with integrated molecular switching capacity. Molecule-based switching materials are actively pursued in cutting-edge sensory, information storage and nanophotonic devices. This project expects to drive the advancement of modern memory-switching device and sensor technologies. An expected outcome of this project is to define a new sophisticated class of nanomaterials with inbuilt molecular switching features in active pursuit of modern nanotechnologies and evolving key fundamental concepts which underpin nano-scale switching.Read moreRead less
Advanced Dynamic Function in Metal-Organic Framework Materials. This project targets the strategic incorporation of three important high-order functionalities into metal-organic framework materials. These are nanoporosity, that is the reversible inclusion of molecules and ions; anomalous mechanical response to changes in temperature, pressure and included guests; and electronic/magnetic function, specifically electron transfer and magnetic alignment. Examination of the unique interplay between ....Advanced Dynamic Function in Metal-Organic Framework Materials. This project targets the strategic incorporation of three important high-order functionalities into metal-organic framework materials. These are nanoporosity, that is the reversible inclusion of molecules and ions; anomalous mechanical response to changes in temperature, pressure and included guests; and electronic/magnetic function, specifically electron transfer and magnetic alignment. Examination of the unique interplay between these properties will address key questions in the science of nanoscale systems and may lead to the discovery of exciting new emergent phenomena. This will underpin the development of advanced new technologies, spanning gas separations, rechargeable batteries, high precision componentry and molecular electronic devices.Read moreRead less
Emergent function in coordination framework materials. This project aims to generate new classes of advanced materials that possess multiple high-order properties. The project targets the strategic incorporation of three high-order functionalities into molecular materials. These are anomalous mechanical response to changes in temperature, pressure and included guests, electronic and magnetic function, involving the transport and alignment of electrons, and nanoporosity, involving the reversible ....Emergent function in coordination framework materials. This project aims to generate new classes of advanced materials that possess multiple high-order properties. The project targets the strategic incorporation of three high-order functionalities into molecular materials. These are anomalous mechanical response to changes in temperature, pressure and included guests, electronic and magnetic function, involving the transport and alignment of electrons, and nanoporosity, involving the reversible inclusion of molecules and ions. Examination of the dynamic interplay between these properties will address key questions in the science of nanoscale systems. This will underpin the development of advanced new technologies spanning high precision device componentry, molecular electronic devices and gas separations.Read moreRead less
A Radical Approach to Multifunctional Coordination Solids. The development of multifunctional coordination solids represents one of the foremost challenges in the field of advanced materials as their properties underpin the next generation of technologically useful devices. Using a highly targeted theoretical and experimental approach for crystal engineering, this project aims to generate coordination solids that integrate radicals as molecular components for charge transfer. At a fundamental le ....A Radical Approach to Multifunctional Coordination Solids. The development of multifunctional coordination solids represents one of the foremost challenges in the field of advanced materials as their properties underpin the next generation of technologically useful devices. Using a highly targeted theoretical and experimental approach for crystal engineering, this project aims to generate coordination solids that integrate radicals as molecular components for charge transfer. At a fundamental level these materials will offer unprecedented insights into charge delocalisation and radical-induced switching phenomena in three-dimensional coordination space. It is expected that the outcomes of the project will spur the development of devices for applications ranging from solid state sensing to energy conversion and storage.Read moreRead less
Emergent Behaviours in Spin Crossover Materials. This project aims to develop new molecular materials in which the incorporation of electronic switching leads to the emergence of fundamentally new chemical and physical phenomena. Through an innovative interdisciplinary approach that targets interesting new forms of interplay at the nanoscale this project expects to generate step-change advances in the understanding of spin-switching materials. Significant anticipated outcomes and benefits includ ....Emergent Behaviours in Spin Crossover Materials. This project aims to develop new molecular materials in which the incorporation of electronic switching leads to the emergence of fundamentally new chemical and physical phenomena. Through an innovative interdisciplinary approach that targets interesting new forms of interplay at the nanoscale this project expects to generate step-change advances in the understanding of spin-switching materials. Significant anticipated outcomes and benefits include identification and development of several new classes of materials function, each of major fundamental interest, and to the generation of advanced new materials worthy of commercial development in electronic device, actuator, sensor and gas separations technologies.Read moreRead less
Conducting nanoporous materials: toward molecular devices. This project addresses one of the foremost challenges in the field of advanced functional materials, namely the design and synthesis of nanoporous materials that conduct electrons. The outcomes on both a fundamental and applied level will pave the way toward molecular electronics devices for solid-state sensing to solar energy harvesting.