Novel Biomimetic Nanosprings:Protein-based Elastomer for Engineering Applications. The ability to produce biomimetic elastomeric components with approximately infinite fatigue life offers significant impact on energy consumption and materials usage. In this project, we seek this goal by bio-macromolecular modification and understanding of the unique proteins from a number of different insects that provide the structural basis of novel bioelastomers with outstanding in-vitro fatigue properties. T ....Novel Biomimetic Nanosprings:Protein-based Elastomer for Engineering Applications. The ability to produce biomimetic elastomeric components with approximately infinite fatigue life offers significant impact on energy consumption and materials usage. In this project, we seek this goal by bio-macromolecular modification and understanding of the unique proteins from a number of different insects that provide the structural basis of novel bioelastomers with outstanding in-vitro fatigue properties. The project will translate the superior in-vivo properties of these proteins to real-world novel bioelastomers for engineering applications. Such functional materials will find potential use in areas such as microelectromechanical devices (MEMS), actuators, artificial muscles, drug delivery vehicles, etc.Read moreRead less
Highly Crosslinked Poly(urea-co-urethane) Copolymer Concrete Floor Coatings. Recently developed, poly(urea-co-urethane) concrete floor screeds are used, in the construction industry, to provide protection against corrosive chemicals and abrasive wear; properties unmatched by other commercial floor treatments. Significantly such material has reduced environmental emissions and toxicity hazards. Factors, which affect the cure and performance of poly(urea-co-urethane) flooring materials will now ....Highly Crosslinked Poly(urea-co-urethane) Copolymer Concrete Floor Coatings. Recently developed, poly(urea-co-urethane) concrete floor screeds are used, in the construction industry, to provide protection against corrosive chemicals and abrasive wear; properties unmatched by other commercial floor treatments. Significantly such material has reduced environmental emissions and toxicity hazards. Factors, which affect the cure and performance of poly(urea-co-urethane) flooring materials will now be studied, including the uncontrolled release of carbon dioxide, which results in sporadic blister formation, leading to the on-site product failures that have severely limited the product's commercial growth. Clear understanding of cure chemistry and adhesion will be established for the first, allowing for the products further development.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0211003
Funder
Australian Research Council
Funding Amount
$125,000.00
Summary
A Facility for Probing Nanostructure in Polymers. The properties of a polymer are only partly determined by its molecular structure. It is now clear that the organization of molecular structure and phase morphology on a nano-scale has an equally important role in determining material behaviour. Increasingly this can be manipulated by judicious choice of formulation and processing variables. The polymer Nano-Structure Facility will bring together Australia's principal polymer experts in this a ....A Facility for Probing Nanostructure in Polymers. The properties of a polymer are only partly determined by its molecular structure. It is now clear that the organization of molecular structure and phase morphology on a nano-scale has an equally important role in determining material behaviour. Increasingly this can be manipulated by judicious choice of formulation and processing variables. The polymer Nano-Structure Facility will bring together Australia's principal polymer experts in this area of structure-property relations and provide them with shared access to the appropriate, modern analytical tools required to probe the nano-structure of such new materials with enhanced properties.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0668517
Funder
Australian Research Council
Funding Amount
$220,000.00
Summary
Hyphenated techniques in polymer science and engineering. The collaborator's research capabilities will be greatly enhanced because the equipment will allow simultaneous measurements of various properties which can provide much more information than sequential experiments. Students will be able to undertake research with state-of-the-art equipment which will enhance their research careers and employment prospects. The resulting information will be invaluable to the development of polymer blends ....Hyphenated techniques in polymer science and engineering. The collaborator's research capabilities will be greatly enhanced because the equipment will allow simultaneous measurements of various properties which can provide much more information than sequential experiments. Students will be able to undertake research with state-of-the-art equipment which will enhance their research careers and employment prospects. The resulting information will be invaluable to the development of polymer blends with optimized morphology and mechanical properties; improved polymer processing techniques linked to how the structure and orientation develops; the development of new materials, including novel human tissue implants, from studies of the rheology and phase structure of a polymer during photopolymerization.Read moreRead less
The Synthesis and Evaluation of White Nano Particles that Reinforce the Mechanical Properties of Elastomers. This project will introduce admicellar polymerization technique to produce a bound polymer layer on the surface of fillers used for reinforcement of elastomers. The novel approach in this project will provide advanced material with excellent mechanical properties. Such composites can be used in various high performance elastomer applications such as rubber for tyres in automotive vehicles ....The Synthesis and Evaluation of White Nano Particles that Reinforce the Mechanical Properties of Elastomers. This project will introduce admicellar polymerization technique to produce a bound polymer layer on the surface of fillers used for reinforcement of elastomers. The novel approach in this project will provide advanced material with excellent mechanical properties. Such composites can be used in various high performance elastomer applications such as rubber for tyres in automotive vehicles. Products based on this new technology will produce significantly improved properties. The development of this new technology will not only advance polymer science, it will also provide great opportunities for new elastomer applications in a number of industries.Read moreRead less
Structure-Property Relationships of Polymers with Controlled Architecture. Mechanical properties of a polymer (e.g., how elastic it is and how it dissipates energy when compressed) govern how well it performs as an adhesive, or its behaviour when melted and shaped into a consumer item. This project aims to relate molecular architecture to mechanical properties, using new techniques which permit the creation of polymers wherein each architectural characteristic is separately controlled. This has ....Structure-Property Relationships of Polymers with Controlled Architecture. Mechanical properties of a polymer (e.g., how elastic it is and how it dissipates energy when compressed) govern how well it performs as an adhesive, or its behaviour when melted and shaped into a consumer item. This project aims to relate molecular architecture to mechanical properties, using new techniques which permit the creation of polymers wherein each architectural characteristic is separately controlled. This has the potential to develop fundamental understanding for structure-property relations for the type of branched polymers that are in common use in industry and for which adequate models do not currently exist.Read moreRead less
An Integrated Framework for Optimisation and Control of Key Product Properties in Emulsion Polymerisation. Emulsion polymerization is of major industrial importance. In addition to process efficiency, the use of water as the reactor medium provides environmental benefits. This proposal is aimed at building an integrated framework to analyse, model, control and optimise emulsion polymerisation systems in order to understand, design and operate such complex systems to obtain desired polymer produc ....An Integrated Framework for Optimisation and Control of Key Product Properties in Emulsion Polymerisation. Emulsion polymerization is of major industrial importance. In addition to process efficiency, the use of water as the reactor medium provides environmental benefits. This proposal is aimed at building an integrated framework to analyse, model, control and optimise emulsion polymerisation systems in order to understand, design and operate such complex systems to obtain desired polymer product characteristics. Complex kinetic, transport and evolution equations will be analysed and solved for predicting and controlling key product properties. This project will provide not only a significant advance in fundamental knowledge of polymerisation systems but will also enable production of cost-effective ?designer polymers? for a wide-range of applications.Read moreRead less
Nanostructured materials by controlled photopolymerization. Photo-polymerization is an important and flexible means of converting a crosslinkable monomer into a solid and has application ranging from lens production to photo-lithography. This project aims at developing the technology of producing multi-phase structures of controllable morphology by selective and independent dual photo-polymerization of blends of crosslinkable monomers at controlled rates. These morphologies may have applicatio ....Nanostructured materials by controlled photopolymerization. Photo-polymerization is an important and flexible means of converting a crosslinkable monomer into a solid and has application ranging from lens production to photo-lithography. This project aims at developing the technology of producing multi-phase structures of controllable morphology by selective and independent dual photo-polymerization of blends of crosslinkable monomers at controlled rates. These morphologies may have applications in toughening polymers with minimum loss in strength and optical transparency, abrasion resistant coatings, tissue engineering (where the phases have differing biodegradability), in microfluidics, and microelectro-mechanical systems (where sub-micron channels/domains are required) or in membrane separation.Read moreRead less
Novel network polymers with photoinduced plasticity. The production of crosslinked polymers (thermosets and rubbers) is a multi-billion dollar industry and these polymers are irreplaceable in their use in numerous applications in the household goods, medical, electronics, automotive and construction industries. However, they shrink during solidification causing internal stresses which weaken them and they can not be reshaped, repaired or recycled. This study will develop a novel range of cros ....Novel network polymers with photoinduced plasticity. The production of crosslinked polymers (thermosets and rubbers) is a multi-billion dollar industry and these polymers are irreplaceable in their use in numerous applications in the household goods, medical, electronics, automotive and construction industries. However, they shrink during solidification causing internal stresses which weaken them and they can not be reshaped, repaired or recycled. This study will develop a novel range of crosslinkable polymers which can change shape on irradiation by light (or by heating) for use in applications ranging from repairable composites, stress-free lens, non-shrinking dental filling materials and light-sensitive actuators which will have significant benefit to industry.Read moreRead less
High efficiency photoinitiators for novel photopolymerization processes. The radiation curing industry is worth several billion dollars world-wide with an Australian market of ca. $100 million and an even greater market in the Asian region. One of the main factors controlling the expansion of this industry is the development of new photoinitiator systems with improved performance. This project aims to combine the skills of three leading scientists in the photocuring field to develop more efficie ....High efficiency photoinitiators for novel photopolymerization processes. The radiation curing industry is worth several billion dollars world-wide with an Australian market of ca. $100 million and an even greater market in the Asian region. One of the main factors controlling the expansion of this industry is the development of new photoinitiator systems with improved performance. This project aims to combine the skills of three leading scientists in the photocuring field to develop more efficient, environmentally-friendly systems by controlling the initiation and polymerization mechanisms in (meth)acrylate, cyclic ether, cyanate and vinyl ethers. This should benefit local manufacturers exporting into the printing, adhesive, dental, lithography, composite industries and to the photopolymer industry generally.Read moreRead less