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Packed bed reactor for continuous biodiesel production process. One of the few oppoutunities for significant substitution of liquid fossil fuels by renewable energy resources is through biodiesel. This project seeks to develop a continuous process for biodiesel production from beef tallow, including feed preparation, reaction and the separation processes of the product exiting the reator. A key reqirement is to develop a heterogeneous catalyst for the chemical conversion, enabling the use of a p ....Packed bed reactor for continuous biodiesel production process. One of the few oppoutunities for significant substitution of liquid fossil fuels by renewable energy resources is through biodiesel. This project seeks to develop a continuous process for biodiesel production from beef tallow, including feed preparation, reaction and the separation processes of the product exiting the reator. A key reqirement is to develop a heterogeneous catalyst for the chemical conversion, enabling the use of a packed bed reactor for the conversion step. The process offers the potential to use poor quality and wet feed materials with much higher efficency and product quality than existing processesRead moreRead less
Surface Processing of Photo-Sensitive Semiconducting Oxides for Solar-Hydrogen. Aim: To enhance the performance of titania-based semiconducting photo-electrodes for the generation of hydrogen from water using sunlight. Means: Engineering of the surface and near-surface layers so as to increase photo-sensitivity and reactivity with water. Significance: Success will provide the key functional component of photo-electrochemical cells for the mass production of renewable and clean hydrogen. In ....Surface Processing of Photo-Sensitive Semiconducting Oxides for Solar-Hydrogen. Aim: To enhance the performance of titania-based semiconducting photo-electrodes for the generation of hydrogen from water using sunlight. Means: Engineering of the surface and near-surface layers so as to increase photo-sensitivity and reactivity with water. Significance: Success will provide the key functional component of photo-electrochemical cells for the mass production of renewable and clean hydrogen. Innovation: For the first time, the properties controlling photo-sensitivity (defect disorder; charge transport; and chemically-induced, local, surface electric fields) will be modified. Outcomes: Technologies for the production of fuel (hydrogen) using renewable energy (solar energy) and a renewable resource (water).
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Biotransformation and biodegradation of organic nitrogen compounds from wastewater in bio-electrochemical systems. The rapid emergence of water recycling in Australia requires more vigilant control of pollutants that are discharged to sewers. This project will develop a novel, cost-effective process to remove organic nitrogen compounds (and likely other organics) present in many industrial wastewaters. It could provide an excellent solution for the pre-treatment of such industrial wastewaters at ....Biotransformation and biodegradation of organic nitrogen compounds from wastewater in bio-electrochemical systems. The rapid emergence of water recycling in Australia requires more vigilant control of pollutants that are discharged to sewers. This project will develop a novel, cost-effective process to remove organic nitrogen compounds (and likely other organics) present in many industrial wastewaters. It could provide an excellent solution for the pre-treatment of such industrial wastewaters at the source without any chemical addition, hence reducing the challenge and risks facing the water recycling plants. This innovative technology will further expand the growing research capacity and know-how in water recycling in Australia.Read moreRead less
P-Type Titanium Dioxide for Hydrogen Generation from Water using Solar Energy. This project aims to develop a completely new processing technology for photo-sensitive oxide materials based on titanium dioxide for the conversion of renewable energy (solar energy) into chemical energy (hydrogen) or electrical energy (photovoltaic). When commercialised, the resultant technology will allow Australia to achieve the following: a) reduction in air pollution, b) reduction in greenhouse gas emissions, c) ....P-Type Titanium Dioxide for Hydrogen Generation from Water using Solar Energy. This project aims to develop a completely new processing technology for photo-sensitive oxide materials based on titanium dioxide for the conversion of renewable energy (solar energy) into chemical energy (hydrogen) or electrical energy (photovoltaic). When commercialised, the resultant technology will allow Australia to achieve the following: a) reduction in air pollution, b) reduction in greenhouse gas emissions, c) reduction in reliance on foreign energy sources, d) development of a range of ancillary technologies and infrastructure, and e) export of solar energy in the form of solar-hydrogen. This project addresses National Priorities #1 and #3.Read moreRead less
PROCESSING OF REDUCED-BAND-GAP TITANIA FOR SOLAR-HYDROGEN. The present project involves the development of materials and devices for solar-hydrogen using photo-assisted water decomposition. The research focusses on the processing of titanium dioxide (titania) with substantially enhanced photo-sensitivity and, consequently, increased efficiency of the conversion of solar energy into chemical energy (hydrogen) through imposition of the optimal Ti/O ratio. Significance: processing technology of tit ....PROCESSING OF REDUCED-BAND-GAP TITANIA FOR SOLAR-HYDROGEN. The present project involves the development of materials and devices for solar-hydrogen using photo-assisted water decomposition. The research focusses on the processing of titanium dioxide (titania) with substantially enhanced photo-sensitivity and, consequently, increased efficiency of the conversion of solar energy into chemical energy (hydrogen) through imposition of the optimal Ti/O ratio. Significance: processing technology of titania for photo-electrochemical devices for hydrogen generation and water decontamination. Innovation: processing of titania with reduced band-gap to be achieved through optimised oxygen nonstoichiometry. Outcome: processing technology of titania with outstanding photo-sensitivity.Read moreRead less
TITANIA-BASED MATERIALS WITH ENHANCED PHOTO-SENSITIVITY FOR SOLAR-HYDROGEN. Aims: Enhancement of the photo-sensitivity of titania photo-electrodes will be achieved through the effect of aliovalent ions in the titania lattice, leading to, at a high density of states, the imposition of mid-gap bands. This will result in the reduction of the effective band gap required for ionisation. Significance: The practical application of titania for the photolysis of water using solar energy at efficiencies s ....TITANIA-BASED MATERIALS WITH ENHANCED PHOTO-SENSITIVITY FOR SOLAR-HYDROGEN. Aims: Enhancement of the photo-sensitivity of titania photo-electrodes will be achieved through the effect of aliovalent ions in the titania lattice, leading to, at a high density of states, the imposition of mid-gap bands. This will result in the reduction of the effective band gap required for ionisation. Significance: The practical application of titania for the photolysis of water using solar energy at efficiencies sufficiently high for commercialisation (greater than 10%). Innovation: Examination for the first time of the impact of the electronic structure on the photo-sensitivity of oxide materials, including titania single crystals and polycrystals.Read moreRead less
Computational approaches to selection and design of ionic materials. Advanced batteries, fuel cells and solar cell technologies are beginning to use ionic liquids/plastic crystals as electrolytes due to their superb stability and valuable properties. As a broad class these ionic materials have only been known for the last 10 years or so and there is much to learn about their structure and properties. The project will develop and advance quantum chemical techniques for selection and design of ion ....Computational approaches to selection and design of ionic materials. Advanced batteries, fuel cells and solar cell technologies are beginning to use ionic liquids/plastic crystals as electrolytes due to their superb stability and valuable properties. As a broad class these ionic materials have only been known for the last 10 years or so and there is much to learn about their structure and properties. The project will develop and advance quantum chemical techniques for selection and design of ionic materials with the goal of developing electrolytes for a range of applications from advanced metal batteries, solar cells to fuel cells. These applications will have impact on energy efficiency and energy conservation by enabling CO2 replacing technologies. Read moreRead less
Fully ab initio, large-scale calculations of thermodynamic and transport properties of ionic materials. Advanced batteries, fuel cells, and photonic device technologies are beginning to use ionic materials as electrolytes due to their superb stability and technologically valuable properties. As a broad class these materials have only been known for just over a decade and there is still more unknown than known about their structure and properties. The project will develop new advanced computation ....Fully ab initio, large-scale calculations of thermodynamic and transport properties of ionic materials. Advanced batteries, fuel cells, and photonic device technologies are beginning to use ionic materials as electrolytes due to their superb stability and technologically valuable properties. As a broad class these materials have only been known for just over a decade and there is still more unknown than known about their structure and properties. The project will develop new advanced computational methods as a basis for understanding their properties and thereby allowing us to design-in desired features. Ultimately these advances will have support the development of energy efficient CO2 replacement technologies.Read moreRead less
Next generation, very high efficiency thin silicon cells. A new type of thin silicon solar cell, with an efficiency potential of 21% or greater, is to be developed and characterized.
These cells should be cheaper, and have better efficiency, power to weight ratio and radiation tolerance than existing commercial silicon solar cells opening interesting possible applications. Novel solar cell designs and associated interconnection and encapsulation schemes for the cells suitable for space and hi ....Next generation, very high efficiency thin silicon cells. A new type of thin silicon solar cell, with an efficiency potential of 21% or greater, is to be developed and characterized.
These cells should be cheaper, and have better efficiency, power to weight ratio and radiation tolerance than existing commercial silicon solar cells opening interesting possible applications. Novel solar cell designs and associated interconnection and encapsulation schemes for the cells suitable for space and high altitude aircraft applications superior to existing technologies are expected to be developed. This should lead to a new, internationally competitive Australian industry.
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The LASE process - a new approach to cost effective thin solar cells. This project aims to develop a process to produce a new type of single
crystalline silicon solar cell. The cell is made on very thin slices of silicon that are detached from a conventional high quality silicon wafer. The wafer is gradually consumed as successive slices are harvested from it. Substantially less silicon is used in each solar cell, which allows significant cost reductions.