Polymers for Novel Surfactants. The aim of the proposed research is to develop novel surface-active polymers with complex architectures and more efficient strategies for the synthesis of surface-active polymers in general. We will exploit the polymerization characteristics of the novel catalytic chain transfer and radical addition-fragmentation transfer polymerization techniques to achieve polymerization control that has been virtually impossible hitherto. The proposed research will thus make ....Polymers for Novel Surfactants. The aim of the proposed research is to develop novel surface-active polymers with complex architectures and more efficient strategies for the synthesis of surface-active polymers in general. We will exploit the polymerization characteristics of the novel catalytic chain transfer and radical addition-fragmentation transfer polymerization techniques to achieve polymerization control that has been virtually impossible hitherto. The proposed research will thus make accessible a wide range of novel surface-active polymers that have been impossible to synthesise to date, and which we expect to be more efficient and hence leads to greener technologies.
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Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0453637
Funder
Australian Research Council
Funding Amount
$256,804.00
Summary
Multi-dimensional polymer characterization facility. The microstructure of polymers dominates their physical properties. This integrated facility will create a world-leading means of characterizing in multiple dimensions the microstructure of complex polymers, eg copolymers and branched polymers. The facility will yield information on the distributions of chain end-groups, monomer microstructure, and branches, as functions of molecular weight. The facility will provide otherwise unobtainable dat ....Multi-dimensional polymer characterization facility. The microstructure of polymers dominates their physical properties. This integrated facility will create a world-leading means of characterizing in multiple dimensions the microstructure of complex polymers, eg copolymers and branched polymers. The facility will yield information on the distributions of chain end-groups, monomer microstructure, and branches, as functions of molecular weight. The facility will provide otherwise unobtainable data for a set of projects exploring questions ranging from how new synthetic materials with tailor-made properties can be created, through to how our understanding of natural polymers can be advanced to improve crop utilization.Read moreRead less
Novel Complex Architecture Polymers via a Combination of RAFT Chemistry and Pericyclic Reactions: Synthesis and Characterization. The project aims at advancing the synthetic limits and broadening the synthetic scope of living free radical polymerization and thus enhancing the library of polymer structures available for applications ranging from drug delivery to opto-electronics. Current material design for these applications is yet to reach its full potential through innovative synthetic approac ....Novel Complex Architecture Polymers via a Combination of RAFT Chemistry and Pericyclic Reactions: Synthesis and Characterization. The project aims at advancing the synthetic limits and broadening the synthetic scope of living free radical polymerization and thus enhancing the library of polymer structures available for applications ranging from drug delivery to opto-electronics. Current material design for these applications is yet to reach its full potential through innovative synthetic approaches. The proposal critically underpins and further advances Australia's leading position in both breakthrough science as well as advanced materials. Due to its significant scientific breadth and large coverage of both synthetic and physical aspects of polymer science, the project also provides a significant platform for research training at both honours and PhD level.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0347258
Funder
Australian Research Council
Funding Amount
$170,000.00
Summary
Polymer Analysis Facility. The aim of this application is to establish a facility for polymer analysis. The infra-red spectrometer will be used primarily for analysis of polymerisation reactions whilst the thermal analysis equipment is essential for the characterisation of polymers and thin polymer coatings. The facility will contribute an essential analysis capability for three strong research groups who work in different aspects of polymer science. The main outcomes will improved productivity ....Polymer Analysis Facility. The aim of this application is to establish a facility for polymer analysis. The infra-red spectrometer will be used primarily for analysis of polymerisation reactions whilst the thermal analysis equipment is essential for the characterisation of polymers and thin polymer coatings. The facility will contribute an essential analysis capability for three strong research groups who work in different aspects of polymer science. The main outcomes will improved productivity within the current projects together with new collaborations, particularly between the Steel Institute (ISPP) at Wollongong and the Centre of Advanced Molecular Design (CAMD) at UNSW.Read moreRead less
Establishing In-Depth Understanding of Molecular Degradation Processes in Acrylic Based Polymer Coil-Coatings for Domestic Roofing Applications. The national benefit is multipronged: (i) BlueScope Steel will maintain its technology leadership through continued innovation by taking advantage of the scientific insights that the project delivers for the introduction of next generation long lasting coil coatings for steel, based on an environmentally friendly production processes. (ii) The applicati ....Establishing In-Depth Understanding of Molecular Degradation Processes in Acrylic Based Polymer Coil-Coatings for Domestic Roofing Applications. The national benefit is multipronged: (i) BlueScope Steel will maintain its technology leadership through continued innovation by taking advantage of the scientific insights that the project delivers for the introduction of next generation long lasting coil coatings for steel, based on an environmentally friendly production processes. (ii) The application of mass spectrometry for the analysis of polymer degradation has been pioneered by the CI and BlueScope Steel. The project will demonstrate the power of this technique and secure Australia's place at the forefront of molecular polymer degradation research. (iii) The project has a strong educational component, training a PhD student at the interface of application and fundamental research.Read moreRead less
Fundamentals of the Performance Chemistry of Water-borne Acrylic Polymer based Surface Coatings for Pre-painted Steel Employed in Domestic Roofing Applications. The proposed project will systematically investigate the structure-performance relationships of acrylic emulsion based surface coatings and provide a detailed understanding of their degradation mechanisms. The improved understanding of these coatings will lead to the development of an optimum coating for steel roofs with extremely high d ....Fundamentals of the Performance Chemistry of Water-borne Acrylic Polymer based Surface Coatings for Pre-painted Steel Employed in Domestic Roofing Applications. The proposed project will systematically investigate the structure-performance relationships of acrylic emulsion based surface coatings and provide a detailed understanding of their degradation mechanisms. The improved understanding of these coatings will lead to the development of an optimum coating for steel roofs with extremely high durability and resistance against degradation and gloss loss in typical tropical and sub-tropical Australian climates.Read moreRead less
Defining Polymer Structures in Radical Polymerization Systems: Chain Birth, Chain Growth and Complex Macromolecular Architectures. The project underpins and extends Australia's leading position in the development and application of novel methods to generate advanced polymeric materials. By carefully studying the reaction pathways underpinning the polymerization processes, an in-depth picture of the polymerization is obtained. The research outcomes will strongly benefit the preparation of the com ....Defining Polymer Structures in Radical Polymerization Systems: Chain Birth, Chain Growth and Complex Macromolecular Architectures. The project underpins and extends Australia's leading position in the development and application of novel methods to generate advanced polymeric materials. By carefully studying the reaction pathways underpinning the polymerization processes, an in-depth picture of the polymerization is obtained. The research outcomes will strongly benefit the preparation of the coming generations of intelligent polymer materials of a highly controlled structure, responsive to their environment, with an even broader range of applications than existing polymers. In addition, the project has a substantial educational component providing training embedded in cutting polymer science for several honours and 1 PhD student.Read moreRead less
Novel Coatings For Steel. The aim of this project is to design coatings for steel that have high flexibility and high resistance to scatching and hardness. This will be achieved by the introduction of liquid crystalline phases in the coatings. The outcome will be a new generation of steel coatings with novel properties