Discovery Early Career Researcher Award - Grant ID: DE160101293
Funder
Australian Research Council
Funding Amount
$350,000.00
Summary
Nanoporous Iron-Based Oxygen Evolution Electrocatalysts for Water Splitting. This project aims to develop high-performance water splitting devices based on nanoporous iron-based oxygen evolution electrocatalysts. The devices, which will produce hydrogen to relieve the energy shortage in Australia, can be powered by photovoltaic and wind-generated electricity or directly use solar energy. The development of new energy materials that can be used to make renewable and clean fuels from abundant and ....Nanoporous Iron-Based Oxygen Evolution Electrocatalysts for Water Splitting. This project aims to develop high-performance water splitting devices based on nanoporous iron-based oxygen evolution electrocatalysts. The devices, which will produce hydrogen to relieve the energy shortage in Australia, can be powered by photovoltaic and wind-generated electricity or directly use solar energy. The development of new energy materials that can be used to make renewable and clean fuels from abundant and easily accessible resources is among the most challenging and demanding tasks today. The combination of iron doping and nanoporous structure are intended to improve both the intrinsic and extrinsic catalytic activities of the electrocatalysts to be developed in the project.Read moreRead less
Faster interfacial electron transfer: the effect of molecule shape and size. This project aims to explore the effect of shape and size of pi-conjugated molecules on interfacial electron transfer reactions, which are fundamentally important in all applications of photo-electrochemical conversion and storage of energy. By making two series of pi-conjugated molecules and determining electron transfer rates using a combination of transient spectroscopies and computational chemistry, the project expe ....Faster interfacial electron transfer: the effect of molecule shape and size. This project aims to explore the effect of shape and size of pi-conjugated molecules on interfacial electron transfer reactions, which are fundamentally important in all applications of photo-electrochemical conversion and storage of energy. By making two series of pi-conjugated molecules and determining electron transfer rates using a combination of transient spectroscopies and computational chemistry, the project expects to generate new design principles for molecules with the potential to significantly improve the efficiencies of solar energy conversion and photo-catalytic processes. The new materials and findings will be exploited in a novel redox-mediated water splitting device as a practical outcome with potential end user benefits.Read moreRead less
Nitride materials: In the “bond ionicity Goldilocks zone” for solar energy. Progress towards commercial devices for solar-driven hydrogen generation as well as in-situ electricity generation for vehicles is currently hampered by a lack of earth-abundant, stable, non-toxic semiconductor materials that can be fabricated by scalable methods. This project aims to develop the first scalable solution synthesis methods for a new class of earth-abundant Zn-based nitride semiconductor nanocrystals that h ....Nitride materials: In the “bond ionicity Goldilocks zone” for solar energy. Progress towards commercial devices for solar-driven hydrogen generation as well as in-situ electricity generation for vehicles is currently hampered by a lack of earth-abundant, stable, non-toxic semiconductor materials that can be fabricated by scalable methods. This project aims to develop the first scalable solution synthesis methods for a new class of earth-abundant Zn-based nitride semiconductor nanocrystals that have favourable bond ionicity and establish their optoelectronic properties for renewable energy devices for the first time. Flexible solution processing methods will be exploited to tune surface composition, remove defects and create devices to achieve optimised performance in these challenging new nitride material systems.Read moreRead less
Anodisation methods and materials for solar water splitting. This project aims to convert and chemically store solar energy as hydrogen. Photoactive materials could harness solar energy. With fabrication methods, these thin films often suffer from poor charge transport and stability, hindering their wider application. Fabrication by anodization could potentially overcome these problems. This project will develop thin film fabrication methods based on anodization that synthesise robust, nanostruc ....Anodisation methods and materials for solar water splitting. This project aims to convert and chemically store solar energy as hydrogen. Photoactive materials could harness solar energy. With fabrication methods, these thin films often suffer from poor charge transport and stability, hindering their wider application. Fabrication by anodization could potentially overcome these problems. This project will develop thin film fabrication methods based on anodization that synthesise robust, nanostructured films with efficient compositions and structures. This will lead to photoelectrodes for efficient solar hydrogen generation, crucial for a sustainable energy future. It will also develop general design principles for photoelectrodes for devices.Read moreRead less
Overcoming the inherent instability of photocatalyst to produce solar fuels. This project aims to develop innovative materials engineering methods to suppress the intrinsic instability of novel photoactive semiconductor materials that are promising candidates for harnessing solar energy from water or industrial waste water. A number of potentially impactful photoactive materials are currently suffering from chemical- and photo-dissolution, thus hindering their practical applications. Attaining f ....Overcoming the inherent instability of photocatalyst to produce solar fuels. This project aims to develop innovative materials engineering methods to suppress the intrinsic instability of novel photoactive semiconductor materials that are promising candidates for harnessing solar energy from water or industrial waste water. A number of potentially impactful photoactive materials are currently suffering from chemical- and photo-dissolution, thus hindering their practical applications. Attaining fundamental knowledge on charge interaction at electrolyte-semiconductor interfaces will be crucial in developing the next generation of highly efficient photochemical systems in solar fuels applications.Read moreRead less
Computer-Aided Design of High-Performance Photocatalysts for Solar Hydrogen Production Based on Red Titanium Dioxide. Large-scale generation of energy by solar conversion is critical for future sustainability. This project aims to develop high performance materials to efficiently convert solar energy to hydrogen - a clean fuel. Starting from the newly developed material red titanium dioxide, novel strategies for improved photocatalytic materials will be proposed and evaluated by advanced computa ....Computer-Aided Design of High-Performance Photocatalysts for Solar Hydrogen Production Based on Red Titanium Dioxide. Large-scale generation of energy by solar conversion is critical for future sustainability. This project aims to develop high performance materials to efficiently convert solar energy to hydrogen - a clean fuel. Starting from the newly developed material red titanium dioxide, novel strategies for improved photocatalytic materials will be proposed and evaluated by advanced computational approaches. Key issues for solar-to-hydrogen conversion will be clarified. The materials, knowledge and strategies achieved by this project will dramatically enhance current solar technology and in particular will advance the development of low-cost hydrogen production from water. Read moreRead less
Tuning the electrolytes for high efficiency solar splitting of water. This project will develop a new technology that uses ionic liquids and sunlight to split water into hydrogen and oxygen to be used as a clean fuel. Australia has abundant sunlight, is very close to the growing energy markets of the Asia-Pacific region, and is ideally placed to benefit from this new technology.
Discovery Early Career Researcher Award - Grant ID: DE210101565
Funder
Australian Research Council
Funding Amount
$423,193.00
Summary
An Emerging Ionic Chalcogenide Perovskites for Solar Energy Conversion. This project aims to develop a library of earth-abundant chalcogenide perovskite nanocrystals (CPNCs) for efficient solar energy conversion applications. The key concept is to design non-toxic and stable CPNCs using a facile solution process for solar-to-electricity and fuel generation. The intended outcomes include a fundamental understanding of the relationships between the synthesis, structure, photophysics, and electroch ....An Emerging Ionic Chalcogenide Perovskites for Solar Energy Conversion. This project aims to develop a library of earth-abundant chalcogenide perovskite nanocrystals (CPNCs) for efficient solar energy conversion applications. The key concept is to design non-toxic and stable CPNCs using a facile solution process for solar-to-electricity and fuel generation. The intended outcomes include a fundamental understanding of the relationships between the synthesis, structure, photophysics, and electrochemistry by advanced modeling and multiscale characterizations and ultimately the solar-to-electricity and fuel generation performances of new material systems. This project will build a national research capacity in an emerging field and put Australia at the forefront of practical solar energy conversion technologies.Read moreRead less
Defect control for high-performance green kesterites energy materials. This project will tackle the fundamental challenge of defect control of the quaternary compound kesterite, revolutionizing the way we can understand the hidden defect-evolution process and design accordingly effective defect-control approaches. This will be realized by a systematic approach integrating multiscale materials characterization, process and materials modeling, and linking microscopic local chemical potential and m ....Defect control for high-performance green kesterites energy materials. This project will tackle the fundamental challenge of defect control of the quaternary compound kesterite, revolutionizing the way we can understand the hidden defect-evolution process and design accordingly effective defect-control approaches. This will be realized by a systematic approach integrating multiscale materials characterization, process and materials modeling, and linking microscopic local chemical potential and macroscopic processing conditions, and associated compound properties and device performance to control defects evolution. Successfully achieved, this project will realize full potential of kesterite in photovoltaic and photoelectrochemical applications, and leading to new discoveries in other compound energy materials.Read moreRead less
Understanding and controlling of photoferroelectricity for photoenergy uses. The project seeks to develop high performance photoferroelectric materials for a wide range of photoenergy conversion technologies like photovoltaics and photocatalytics. For the past 50 years, ferroelectric photovoltaics have only been an academic curiosity due to their low energy conversion efficiency relative to the popular semiconductor photovoltaics. This project aims to unlock the potential of ferroelectric photov ....Understanding and controlling of photoferroelectricity for photoenergy uses. The project seeks to develop high performance photoferroelectric materials for a wide range of photoenergy conversion technologies like photovoltaics and photocatalytics. For the past 50 years, ferroelectric photovoltaics have only been an academic curiosity due to their low energy conversion efficiency relative to the popular semiconductor photovoltaics. This project aims to unlock the potential of ferroelectric photovoltaics by introducing an ion co-substitution, which is coupled with electron-pinning, into promising ferroelectric materials and investigating the resultant photo-excited electronic and electrical properties. It is anticipated that the outcomes from this proposed project will provide a solution for optimal ferroelectric visible light absorption to achieve high power conversion efficiency in ferroelectric materials for practical photoenergy applications.Read moreRead less