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Understanding and controlling the stereochemistry of free-radical polymerisation. The stereochemistry of a molecule, which relates to the relative spatial arrangement of its atoms, can have a profound effect on its physical and chemical properties. This project will use a computer-guided experimental approach to design new methods for controlling the stereochemistry of the polymers formed in free-radical polymerisation.
Vesicles stabilised by compressed carbon dioxide as nanoreactors and templates for radical polymerisation. A new environmentally friendly method for synthesis of surfactant vesicles involving stabilisation using low pressure carbon dioxide will be applied to the synthesis of hollow polymeric nanoparticles and polymer of well-defined structure. The resulting polymeric structures will have applications in drug delivery and nano-engineered materials.
Faster, greener, stronger: a new approach to synthesis of polymer materials. The project will investigate new approaches towards polymer material synthesis in the complete absence of hazardous solvents, with the aim of creating materials that have superior physical or chemical properties compared to those prepared using existing methods. This project is significant for driving advances in material design and characterization using simple starting materials and environmentally sustainable conditi ....Faster, greener, stronger: a new approach to synthesis of polymer materials. The project will investigate new approaches towards polymer material synthesis in the complete absence of hazardous solvents, with the aim of creating materials that have superior physical or chemical properties compared to those prepared using existing methods. This project is significant for driving advances in material design and characterization using simple starting materials and environmentally sustainable conditions. Expected outcomes include the production of unique nanomaterials, hydrogels and polymer monoliths with targeted applications, in addition to advances in 3D printing. This project will significantly benefit the sustainable material manufacturing industry into the future.Read moreRead less
Development of Fire Retardant Thermal Insulation Materials for Buildings. This Fellowship proposal aims to develop next-generation fire-retardant rigid polymer foams (RPF)-based thermal insulation materials for buildings. Through investigating fire-retardancy, mechanical and ageing properties, we will fundamentally understand the structure/composition - performance relationships of as-designed nanostructured fire-retardant polymer coatings and will achieve robust, durable and fire-retardant coat ....Development of Fire Retardant Thermal Insulation Materials for Buildings. This Fellowship proposal aims to develop next-generation fire-retardant rigid polymer foams (RPF)-based thermal insulation materials for buildings. Through investigating fire-retardancy, mechanical and ageing properties, we will fundamentally understand the structure/composition - performance relationships of as-designed nanostructured fire-retardant polymer coatings and will achieve robust, durable and fire-retardant coatings. This project will then apply the fire-retardant coatings to the RPF to create the target fire-retardant thermal insulation materials. New knowledge and patentable technologies to be generated will bring significant benefits to Australia by reducing energy costs and economic losses associated with building fires.Read moreRead less
Conducting polymer materials. This project aims to understand the optical, electrical and optoelectronic properties of conductive polymers by studying how ions influence the charge transport through the polymeric structure. The discovery of conductive polymers in the 1970s led to smartphone and laptop touch displays and solar cells. These materials promise even more still – but how they operate at the atomic level is not understood. This project could lead to an ability to harness and control th ....Conducting polymer materials. This project aims to understand the optical, electrical and optoelectronic properties of conductive polymers by studying how ions influence the charge transport through the polymeric structure. The discovery of conductive polymers in the 1970s led to smartphone and laptop touch displays and solar cells. These materials promise even more still – but how they operate at the atomic level is not understood. This project could lead to an ability to harness and control these properties for energy storage and wearable displays. These materials’ biological neutrality could lead to drug delivery and sensing applications in the agriculture and healthcare spaces.Read moreRead less
Developing next generation click chemistry. This project aims to develop next generation click chemistry as an enabling synthetic technology for creating functional molecules. Click-philosophy, that 'all searches must be restricted to molecules that are easy to make', is a key requirement for rapid discovery of useful functional materials, medicines and molecular tools. Click linkers make this possible, and the project will develop a new range of asymmetric 3D-Connectors based upon readily avail ....Developing next generation click chemistry. This project aims to develop next generation click chemistry as an enabling synthetic technology for creating functional molecules. Click-philosophy, that 'all searches must be restricted to molecules that are easy to make', is a key requirement for rapid discovery of useful functional materials, medicines and molecular tools. Click linkers make this possible, and the project will develop a new range of asymmetric 3D-Connectors based upon readily available, yet unexplored main group gasses, and will demonstrate their usefulness in several applications including the synthesis of new polymers. The project will also develop the first general asymmetric Click reaction, which will have significant impact in biological applications and materials science. This project will result in the development of new synthetic chemistry technology that will have a global impact, which will add value to the knowledge economy of Australia and contribute skills and training to the next generation of Australian scientists.Read moreRead less
New materials for manipulating intracellular communication. This project aims to identify new techniques for incorporating cell-signalling triggers into macromolecules, therefore enabling the development of next-generation stimuli-responsive nanoparticles that can emit signalling molecules on demand. Harnessing nanomaterials to stimulate specific sub-cellular processes is a neglected area in nanotechnology research. These nanoparticles could potentially be used to deliver signalling molecules fo ....New materials for manipulating intracellular communication. This project aims to identify new techniques for incorporating cell-signalling triggers into macromolecules, therefore enabling the development of next-generation stimuli-responsive nanoparticles that can emit signalling molecules on demand. Harnessing nanomaterials to stimulate specific sub-cellular processes is a neglected area in nanotechnology research. These nanoparticles could potentially be used to deliver signalling molecules for agricultural, pharmaceutical and veterinary applications. The project is expected to develop a new suite of materials that could ultimately be used to improve the yield of important commercial crops, or revitalise the use of medicines limited by their poor side effect profile.Read moreRead less
Expanding the toolbox of synthetic stealth polymers. This project aims to develop a new generation of synthetic and biomimetic pseudo peptide polymers with advanced biomedical properties. The polymers will be used for the fabrication of a range of nanoparticles, which will allow to study the effect of architecture, composition and surface functionalisation on their behaviour in a biological environment. Carefully conducted structure-physicochemical property relationship and bio-nano interaction ....Expanding the toolbox of synthetic stealth polymers. This project aims to develop a new generation of synthetic and biomimetic pseudo peptide polymers with advanced biomedical properties. The polymers will be used for the fabrication of a range of nanoparticles, which will allow to study the effect of architecture, composition and surface functionalisation on their behaviour in a biological environment. Carefully conducted structure-physicochemical property relationship and bio-nano interaction studies will generate new knowledge in the area of stealth and protein repellent nanomaterials. The intended outcome of the project is the generation of a platform of bioinert materials that could potentially find applications as building blocks in next generation nanomedicines and medical devices.Read moreRead less
Stereolithographic Additive Manufacturing of Semicrystalline Thermoplastics. This project aims to advance the development of high-throughput stereolithographic additive manufacturing of thermoplastic polymers and composites by employing a multi-colour irradiation schemes in conjunction with photopolymerisable, ring-opening monomer resin formulations. The fundamental scientific understanding, engineering expertise, and concomitant technology advances generated by this project are anticipated to e ....Stereolithographic Additive Manufacturing of Semicrystalline Thermoplastics. This project aims to advance the development of high-throughput stereolithographic additive manufacturing of thermoplastic polymers and composites by employing a multi-colour irradiation schemes in conjunction with photopolymerisable, ring-opening monomer resin formulations. The fundamental scientific understanding, engineering expertise, and concomitant technology advances generated by this project are anticipated to enable additive manufacturing to transition from the rapid prototyping of individual, unique items to the high volume production of robust, reprocessable plastic parts. By obviating the large capital expense of conventional fabrication, this developed technology should provide a path to reinvigorate Australian manufacturing.Read moreRead less
Unravelling early self-regulation: A longitudinal study. National data show persistent issues in Australian children's social-emotional vulnerability. Research shows we have had limited success shifting these trajectories through current education and intervention efforts. In short, we understand enough about self-regulation to establish it as a priority target in early childhood, yet not enough to meaningfully alter current trajectories. This project will develop a ‘big picture’ theory of child ....Unravelling early self-regulation: A longitudinal study. National data show persistent issues in Australian children's social-emotional vulnerability. Research shows we have had limited success shifting these trajectories through current education and intervention efforts. In short, we understand enough about self-regulation to establish it as a priority target in early childhood, yet not enough to meaningfully alter current trajectories. This project will develop a ‘big picture’ theory of children’s self-regulation abilities and change, supported by Australia’s first longitudinal study of early self-regulation, from preschool into early primary school (ages 4 to 6). This robust theory of change is expected to better position ongoing education and intervention efforts to succeed.Read moreRead less