Development of next-generation nanoengineered advanced materials for targeted applications. This proposal seeks to develop and use a novel next-generation nanoscale fabrication technique to assemble technologically advanced materials not accessible via current fabrication strategies. The resulting materials are expected to find application in water purification, pharmaceutical development and drug delivery.
Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-si ....Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-site metal-organic framework catalyst with high reaction-activity and chemo-selectivity in converting CO2 into valuable chemicals. This advancement will provide significant benefits for Australia’s emerging chemical manufacturing industry, and ultimately leading to a carbon-neutral energy economy and environment.Read moreRead less
Novel Hybrid Nanotechnologies by Infiltration of Functional Polymers. Hybrid inorganic-organic materials have important applications in energy, environmental and health technologies. Sequential infiltration synthesis (SIS) of polymers is a recently introduced approach to preparing such hybrid structures. Advancement in the field is however hampered by lack of fundamental understanding of the mechanisms of interactions of SIS molecules with polymers, and the narrow range of polymers studied so fa ....Novel Hybrid Nanotechnologies by Infiltration of Functional Polymers. Hybrid inorganic-organic materials have important applications in energy, environmental and health technologies. Sequential infiltration synthesis (SIS) of polymers is a recently introduced approach to preparing such hybrid structures. Advancement in the field is however hampered by lack of fundamental understanding of the mechanisms of interactions of SIS molecules with polymers, and the narrow range of polymers studied so far. This project aims to build a fundamental framework for the development of SIS through systematic studies of interactions of polymers and SIS molecules. Expected outcomes include new methods for constructing nanostructures using functional polymers and novel fabrication processes exploiting polymer self-assembly.Read moreRead less
New stimuli-responsive polymer membranes using graphene as a multifunctional scaffold. Membranes are used in a range of applications to filter liquids and gases and increasingly must be able to be activated by stimuli such as temperature, pH and voltage. We will develop a new type of membrane which is easy to make, is strong and allows the incorporation of a variety of stimuli-responsive polymers within a functional graphene scaffold.
Heterogeneous hydrophilic catalysts for green oxidation in bio-refining. The project aims to address one significant global challenge of developing green processes for producing high value chemicals from biomass, to enhance the environmental performance and cost-efficiency of bio-refining. This project aims to develop a new class of heterogeneous nanocatalysts with hydrophilic Co (salen) complexes for biomass oxidation in water rather than toxic solvent. This project will use this to devise prac ....Heterogeneous hydrophilic catalysts for green oxidation in bio-refining. The project aims to address one significant global challenge of developing green processes for producing high value chemicals from biomass, to enhance the environmental performance and cost-efficiency of bio-refining. This project aims to develop a new class of heterogeneous nanocatalysts with hydrophilic Co (salen) complexes for biomass oxidation in water rather than toxic solvent. This project will use this to devise practical routes for the production of targeted industrial components for flavours, fragrances, fine chemicals, and petrochemicals. The development of heterogeneous hydrophilic catalysts by which they will oxidise hydrophilic biomasses in a continuous flow system will dramatically improve the sustainability of the chemical industry.Read moreRead less
Carbon fibre thermoplastics as next-generation carbon fibre composites. By combining sizing, chemical grafting, and nano-reinforcement strategies, this project develops chemically and thermally robust thermoplastic interfacial sizing for carbon fiber/thermoplastic composites for rapid manufacturing. Thermostamped carbon fiber/thermoplastic composite prototypes will be used to verify the sizing. In order to demonstrate industrial viability, recyclability and reprocessability analyses will be cond ....Carbon fibre thermoplastics as next-generation carbon fibre composites. By combining sizing, chemical grafting, and nano-reinforcement strategies, this project develops chemically and thermally robust thermoplastic interfacial sizing for carbon fiber/thermoplastic composites for rapid manufacturing. Thermostamped carbon fiber/thermoplastic composite prototypes will be used to verify the sizing. In order to demonstrate industrial viability, recyclability and reprocessability analyses will be conducted. This sizing method can enable high-performance thermoplastic composites in nonaerospace applications with its atomistic level modelling and comprehensive characterisation routine. A key objective of this study is to produce sustainably manufactured composite materials that are also commercially relevant.Read moreRead less
Next-generation lithography: photo-directing assembly of block copolymers. This project aims to introduce a novel approach to organising block polymers through the photochemical modification of the surface of a photo-sensitive polymer. Chemo-epitaxy is the science of organising materials on a surface decorated with chemical patterns. The process has the potential to revolutionise the manufacture of integrated circuits, enabling faster processors. This project expects to introduce innovative conc ....Next-generation lithography: photo-directing assembly of block copolymers. This project aims to introduce a novel approach to organising block polymers through the photochemical modification of the surface of a photo-sensitive polymer. Chemo-epitaxy is the science of organising materials on a surface decorated with chemical patterns. The process has the potential to revolutionise the manufacture of integrated circuits, enabling faster processors. This project expects to introduce innovative concepts in polymer chemistry and nanoscale assembly with the potential to advance a multi-billion-dollar industry.Read moreRead less
Fast stimuli-responsive polymer hydrogels as a new class of draw agent for forward osmosis desalination. The ability to extract fresh water from saline water can be important in areas such as desalination and other industrial applications. In this project new materials will be developed to perform this operation at a much lower energy cost than similar processes, whilst also improving the purity of the separated water.
Targeting nano-catalysts for sustainable biorefining and chemical processes. This joint computational-experimental project aims to address one significant global challenge of developing sustainable technologies for important chemical processes. The project expects to discover new advanced nano-catalysts via a rapid single-step process which will replace toxic and corrosive liquid acids, and low efficient solid acids, used in emerging biorefining and petrochemistry. Advanced spectroscopic studies ....Targeting nano-catalysts for sustainable biorefining and chemical processes. This joint computational-experimental project aims to address one significant global challenge of developing sustainable technologies for important chemical processes. The project expects to discover new advanced nano-catalysts via a rapid single-step process which will replace toxic and corrosive liquid acids, and low efficient solid acids, used in emerging biorefining and petrochemistry. Advanced spectroscopic studies, in synergy with state-of-the-art ab initio calculations will be used to explore nanostructure-performance relationship in depth. Such cutting-edge knowledge will have profound implications on designing innovative catalysts with tailored activity for sustainable production of biofuels and chemicals.Read moreRead less
Fluid Transport in Materials of Nanoscale Dimensions. This project aims to transform the modelling of fluid transport in materials of nanoscale dimension by determining the coupled interfacial heat and mass-transfer barriers, which critically influence the transport. The outcome will not only be new knowledge on the effects of inherent structural distortion and of the barriers on the fluid flow, but also cutting-edge techniques to estimate system size-dependent transport coefficients in nanoscal ....Fluid Transport in Materials of Nanoscale Dimensions. This project aims to transform the modelling of fluid transport in materials of nanoscale dimension by determining the coupled interfacial heat and mass-transfer barriers, which critically influence the transport. The outcome will not only be new knowledge on the effects of inherent structural distortion and of the barriers on the fluid flow, but also cutting-edge techniques to estimate system size-dependent transport coefficients in nanoscale systems. These will be achieved through a combination of targeted molecular dynamics simulations and experiment, and will have far-reaching implications for nanotechnology and emerging processes in catalysis, gas separation, human health and nanofluidics, and enable design of more efficient systems.Read moreRead less