Catalytic conversion of Australia's natural gas to value added products. While natural gas (of which methane is the primary component) is an abundant source of energy, it is normally found in remote areas and for its successful exploitation it needs to be processed. The processing usually requires significant energy and resources input. In this project we will develop a fundamental understanding to a single step catalytic process that can utilise natural gas and nitrous oxide (both potent greenh ....Catalytic conversion of Australia's natural gas to value added products. While natural gas (of which methane is the primary component) is an abundant source of energy, it is normally found in remote areas and for its successful exploitation it needs to be processed. The processing usually requires significant energy and resources input. In this project we will develop a fundamental understanding to a single step catalytic process that can utilise natural gas and nitrous oxide (both potent greenhouse gases) and oxygen to produce selectively methanol and hydrocarbons from a natural gas feedstream in a controlled manner. A single step process for natural gas conversion utilising waste green-house gases is expected to be of great benefit to the Australian economy, environment and energy securityRead moreRead less
Novel inkjet-printed organic solvent nanofiltration membranes. The pharmaceutical industry is one of fastest growing industries in Australia. Manufacturing pharmaceutical products requires the use of hazardous and expensive organic solvents, which are toxic for the environment and expensive to recover due to the energy intensive thermal process required. This project aims to discover and manufacture a novel, low-cost, chemically robust nanomaterial-based membrane using an industry scalable inkje ....Novel inkjet-printed organic solvent nanofiltration membranes. The pharmaceutical industry is one of fastest growing industries in Australia. Manufacturing pharmaceutical products requires the use of hazardous and expensive organic solvents, which are toxic for the environment and expensive to recover due to the energy intensive thermal process required. This project aims to discover and manufacture a novel, low-cost, chemically robust nanomaterial-based membrane using an industry scalable inkjet printing process. The membrane will be resistant to organic solvents while efficiently recovering valuable and hazardous organic solvents with minimum environmental footprint. It will effectively provide for the future growth of the Australian pharmaceutical industry while also having global applications.Read moreRead less
Synthesis of oligomers in dense carbon dioxide. The aim of the project is to develop a novel technique for the synthesis of low molecular weight polymers (oligomers) using dense carbon dioxide as a polymerisation solvent. The use of elevated pressure is the major impediment to the commercialisation of such technology. The technique proposed in this project will enable oligomers to be produced at greatly reduced operating pressures and may lead to a more general procedure for conducting other t ....Synthesis of oligomers in dense carbon dioxide. The aim of the project is to develop a novel technique for the synthesis of low molecular weight polymers (oligomers) using dense carbon dioxide as a polymerisation solvent. The use of elevated pressure is the major impediment to the commercialisation of such technology. The technique proposed in this project will enable oligomers to be produced at greatly reduced operating pressures and may lead to a more general procedure for conducting other types of polymer synthesis in dense carbon dioxide.Read moreRead less
An Integrated Framework for Optimisation and Control of Key Product Properties in Emulsion Polymerisation. Emulsion polymerization is of major industrial importance. In addition to process efficiency, the use of water as the reactor medium provides environmental benefits. This proposal is aimed at building an integrated framework to analyse, model, control and optimise emulsion polymerisation systems in order to understand, design and operate such complex systems to obtain desired polymer produc ....An Integrated Framework for Optimisation and Control of Key Product Properties in Emulsion Polymerisation. Emulsion polymerization is of major industrial importance. In addition to process efficiency, the use of water as the reactor medium provides environmental benefits. This proposal is aimed at building an integrated framework to analyse, model, control and optimise emulsion polymerisation systems in order to understand, design and operate such complex systems to obtain desired polymer product characteristics. Complex kinetic, transport and evolution equations will be analysed and solved for predicting and controlling key product properties. This project will provide not only a significant advance in fundamental knowledge of polymerisation systems but will also enable production of cost-effective ?designer polymers? for a wide-range of applications.Read moreRead less
Clean technologies for the synthesis and purification of a biohybrid and biodegradable polymer. The project aims to transform an Australian industry in the forefront of the global market for manufacturing biodegradable polymers and boost export earnings derived from CO2 based biohybrid polymers. The project will develop cost-effective and clean methods for processing CO2 based polymers and demonstrate its potential for packaging and biomedical applications.
Discovery Early Career Researcher Award - Grant ID: DE190101618
Funder
Australian Research Council
Funding Amount
$389,000.00
Summary
Tailoring multifunctional single site catalysts for carbon dioxide conversion. This project aims to develop multifunctional single site catalysts and collaborative surface sites to complete multi-step reactions using carbon dioxide (CO2) hydrogenation to higher alcohols with enhanced selectivity for large-chain alcohols. CO2 is an abundant and renewable carbon source for use as a feedstock, and closing the carbon cycle in an energy efficient manner has the potential for significant environmental ....Tailoring multifunctional single site catalysts for carbon dioxide conversion. This project aims to develop multifunctional single site catalysts and collaborative surface sites to complete multi-step reactions using carbon dioxide (CO2) hydrogenation to higher alcohols with enhanced selectivity for large-chain alcohols. CO2 is an abundant and renewable carbon source for use as a feedstock, and closing the carbon cycle in an energy efficient manner has the potential for significant environmental benefits. The project is expected to advance the knowledge in rational design of new catalysts for CO2 conversion and understanding the catalyst structure-property induced reaction mechanism. This will result in an improved understanding of the reaction kinetics of utilising CO2 as a feedstock.Read moreRead less
A novel route to produce olefin feedstock for Australia. This project aims to develop a new process to produce longer chain hydrocarbons usable in Australia's olefin and polymer industries. Besides their use as a fuel, hydrocarbons are major industrial chemicals used for the production of polymeric materials and as refrigerants. Olefins are precursors to polymers and conventionally are produced from saturated hydrocarbons through the process of steam cracking. The major precursors for monomers a ....A novel route to produce olefin feedstock for Australia. This project aims to develop a new process to produce longer chain hydrocarbons usable in Australia's olefin and polymer industries. Besides their use as a fuel, hydrocarbons are major industrial chemicals used for the production of polymeric materials and as refrigerants. Olefins are precursors to polymers and conventionally are produced from saturated hydrocarbons through the process of steam cracking. The major precursors for monomers are present in significant quantities in only a few natural gas sources and these sources also undergo significant seasonal variation and are costly. The project aims to develop new catalysts and process conditions to convert low-value feedstock hydrocarbons into feedstock for conventional steam crackers.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE220100583
Funder
Australian Research Council
Funding Amount
$445,000.00
Summary
Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous ....Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous polymeric MOF coating. This approach is expected to deliver robust biocatalysts with high reaction-activity and chemo-selectivity in converting CO2 into methanol under the industrial operating condition, involving thermal, pH, and chemical stressors. This advancement will contribute to a carbon-neutral industry and society.Read moreRead less
Advanced chemical recycling of mixed plastics for monomer recovery. This project aims to develop innovative catalytic routes to the chemical recycling of mixed plastics for recovery of their molecular building blocks. Plastic pollution poses a significant threat to the Australian ecosystem. Efficient recycling technologies are urgently needed as Australia only recycles ~4% of its 3.4 million tons of mixed waste plastics. This project expects to design highly efficient catalysts for the stepwise ....Advanced chemical recycling of mixed plastics for monomer recovery. This project aims to develop innovative catalytic routes to the chemical recycling of mixed plastics for recovery of their molecular building blocks. Plastic pollution poses a significant threat to the Australian ecosystem. Efficient recycling technologies are urgently needed as Australia only recycles ~4% of its 3.4 million tons of mixed waste plastics. This project expects to design highly efficient catalysts for the stepwise breakdown of mixed polyolefin plastics into monomers for the subsequent manufacturing of virgin plastics in a circular economy, and to elucidate fundamental underpinning reaction mechanisms. Outcomes will stimulate the Australian waste plastic recycling industry, and minimise plastic accumulation in the environment.Read moreRead less
Manufacturing high value carbon products and chemicals from spent tyres. Manufacturing high value carbon products and chemicals from spent tyres. This project aims to develop an innovative and integrated thermochemical process for use of spent tyres. Australia disposes of more than 400,000 tonnes of spent tyres per annum in landfills, stockpiles and random dumping, incurring significant environmental hazards, serious health risks and wastage of resources. This research is expected to result in n ....Manufacturing high value carbon products and chemicals from spent tyres. Manufacturing high value carbon products and chemicals from spent tyres. This project aims to develop an innovative and integrated thermochemical process for use of spent tyres. Australia disposes of more than 400,000 tonnes of spent tyres per annum in landfills, stockpiles and random dumping, incurring significant environmental hazards, serious health risks and wastage of resources. This research is expected to result in new knowledge of the thermal behaviour of rubber and new techniques to identify, extract and use high value carbon materials and chemicals from thermochemical processing of spent tyres. The research outcomes are expected to provide a technological foundation for an emerging industry for environmentally responsible and economically self-sustaining use of spent tyres.Read moreRead less