Catalytic conversion of Australia's natural gas to value added products. While natural gas (of which methane is the primary component) is an abundant source of energy, it is normally found in remote areas and for its successful exploitation it needs to be processed. The processing usually requires significant energy and resources input. In this project we will develop a fundamental understanding to a single step catalytic process that can utilise natural gas and nitrous oxide (both potent greenh ....Catalytic conversion of Australia's natural gas to value added products. While natural gas (of which methane is the primary component) is an abundant source of energy, it is normally found in remote areas and for its successful exploitation it needs to be processed. The processing usually requires significant energy and resources input. In this project we will develop a fundamental understanding to a single step catalytic process that can utilise natural gas and nitrous oxide (both potent greenhouse gases) and oxygen to produce selectively methanol and hydrocarbons from a natural gas feedstream in a controlled manner. A single step process for natural gas conversion utilising waste green-house gases is expected to be of great benefit to the Australian economy, environment and energy securityRead moreRead less
High purity formaldehyde production from carbon oxides. This project aims to investigate the detailed reaction mechanism of a green chemistry route of producing formaldehyde by reducing carbon monoxide and carbon dioxide in liquid phase. Formaldehyde is a widely used feedstock for chemical industries, but is not considered a green chemical because it is produced using natural gas as the feed, which loses over 61 per cent of energy. This project will maximise the yield and purity of the product, ....High purity formaldehyde production from carbon oxides. This project aims to investigate the detailed reaction mechanism of a green chemistry route of producing formaldehyde by reducing carbon monoxide and carbon dioxide in liquid phase. Formaldehyde is a widely used feedstock for chemical industries, but is not considered a green chemical because it is produced using natural gas as the feed, which loses over 61 per cent of energy. This project will maximise the yield and purity of the product, making it commercially viable. This project’s method for producing formaldehyde is expected to reduce the capital cost and energy losses.Read moreRead less
Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-si ....Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-site metal-organic framework catalyst with high reaction-activity and chemo-selectivity in converting CO2 into valuable chemicals. This advancement will provide significant benefits for Australia’s emerging chemical manufacturing industry, and ultimately leading to a carbon-neutral energy economy and environment.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE190101618
Funder
Australian Research Council
Funding Amount
$389,000.00
Summary
Tailoring multifunctional single site catalysts for carbon dioxide conversion. This project aims to develop multifunctional single site catalysts and collaborative surface sites to complete multi-step reactions using carbon dioxide (CO2) hydrogenation to higher alcohols with enhanced selectivity for large-chain alcohols. CO2 is an abundant and renewable carbon source for use as a feedstock, and closing the carbon cycle in an energy efficient manner has the potential for significant environmental ....Tailoring multifunctional single site catalysts for carbon dioxide conversion. This project aims to develop multifunctional single site catalysts and collaborative surface sites to complete multi-step reactions using carbon dioxide (CO2) hydrogenation to higher alcohols with enhanced selectivity for large-chain alcohols. CO2 is an abundant and renewable carbon source for use as a feedstock, and closing the carbon cycle in an energy efficient manner has the potential for significant environmental benefits. The project is expected to advance the knowledge in rational design of new catalysts for CO2 conversion and understanding the catalyst structure-property induced reaction mechanism. This will result in an improved understanding of the reaction kinetics of utilising CO2 as a feedstock.Read moreRead less
Heterogeneous hydrophilic catalysts for green oxidation in bio-refining. The project aims to address one significant global challenge of developing green processes for producing high value chemicals from biomass, to enhance the environmental performance and cost-efficiency of bio-refining. This project aims to develop a new class of heterogeneous nanocatalysts with hydrophilic Co (salen) complexes for biomass oxidation in water rather than toxic solvent. This project will use this to devise prac ....Heterogeneous hydrophilic catalysts for green oxidation in bio-refining. The project aims to address one significant global challenge of developing green processes for producing high value chemicals from biomass, to enhance the environmental performance and cost-efficiency of bio-refining. This project aims to develop a new class of heterogeneous nanocatalysts with hydrophilic Co (salen) complexes for biomass oxidation in water rather than toxic solvent. This project will use this to devise practical routes for the production of targeted industrial components for flavours, fragrances, fine chemicals, and petrochemicals. The development of heterogeneous hydrophilic catalysts by which they will oxidise hydrophilic biomasses in a continuous flow system will dramatically improve the sustainability of the chemical industry.Read moreRead less
A novel route to produce olefin feedstock for Australia. This project aims to develop a new process to produce longer chain hydrocarbons usable in Australia's olefin and polymer industries. Besides their use as a fuel, hydrocarbons are major industrial chemicals used for the production of polymeric materials and as refrigerants. Olefins are precursors to polymers and conventionally are produced from saturated hydrocarbons through the process of steam cracking. The major precursors for monomers a ....A novel route to produce olefin feedstock for Australia. This project aims to develop a new process to produce longer chain hydrocarbons usable in Australia's olefin and polymer industries. Besides their use as a fuel, hydrocarbons are major industrial chemicals used for the production of polymeric materials and as refrigerants. Olefins are precursors to polymers and conventionally are produced from saturated hydrocarbons through the process of steam cracking. The major precursors for monomers are present in significant quantities in only a few natural gas sources and these sources also undergo significant seasonal variation and are costly. The project aims to develop new catalysts and process conditions to convert low-value feedstock hydrocarbons into feedstock for conventional steam crackers.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE220100583
Funder
Australian Research Council
Funding Amount
$445,000.00
Summary
Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous ....Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous polymeric MOF coating. This approach is expected to deliver robust biocatalysts with high reaction-activity and chemo-selectivity in converting CO2 into methanol under the industrial operating condition, involving thermal, pH, and chemical stressors. This advancement will contribute to a carbon-neutral industry and society.Read moreRead less
Advanced chemical recycling of mixed plastics for monomer recovery. This project aims to develop innovative catalytic routes to the chemical recycling of mixed plastics for recovery of their molecular building blocks. Plastic pollution poses a significant threat to the Australian ecosystem. Efficient recycling technologies are urgently needed as Australia only recycles ~4% of its 3.4 million tons of mixed waste plastics. This project expects to design highly efficient catalysts for the stepwise ....Advanced chemical recycling of mixed plastics for monomer recovery. This project aims to develop innovative catalytic routes to the chemical recycling of mixed plastics for recovery of their molecular building blocks. Plastic pollution poses a significant threat to the Australian ecosystem. Efficient recycling technologies are urgently needed as Australia only recycles ~4% of its 3.4 million tons of mixed waste plastics. This project expects to design highly efficient catalysts for the stepwise breakdown of mixed polyolefin plastics into monomers for the subsequent manufacturing of virgin plastics in a circular economy, and to elucidate fundamental underpinning reaction mechanisms. Outcomes will stimulate the Australian waste plastic recycling industry, and minimise plastic accumulation in the environment.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE120100329
Funder
Australian Research Council
Funding Amount
$375,000.00
Summary
Photocatalytic reduction of carbon dioxide with water into hydrocarbon fuels and chemicals. This project aims to develop a highly efficient photocatalytic process for converting CO2 into hydrocarbon fuels and high value-added chemicals. This new technology can reduce CO2 concentrations in the environment and provide a feasible mean to produce non-fossil fuels and industrial chemicals that society has to depend upon.
Scale-up of catalytic furandicarboxylic acid production at room temperature. This project will use new knowledge acquired from our laboratory-scale discoveries to develop a new process feasible for industrial-scale production of 2,5-furandicarboxylic acid (FDCA). The method makes FDCA, a platform chemical for future chemical industry, from a completely renewable source derived from plant sugars, 5-hydroxymethyl-furfural. This is an essential process for production of biodegradable plastic from s ....Scale-up of catalytic furandicarboxylic acid production at room temperature. This project will use new knowledge acquired from our laboratory-scale discoveries to develop a new process feasible for industrial-scale production of 2,5-furandicarboxylic acid (FDCA). The method makes FDCA, a platform chemical for future chemical industry, from a completely renewable source derived from plant sugars, 5-hydroxymethyl-furfural. This is an essential process for production of biodegradable plastic from sugar that has not been commercialised. This technology will realise sizeable industrial-scale production of FDCA at low costs and without heating. The production development of this valuable commodity from renewable plant sugars will provide high-quality postgraduate training in future green chemical production methods.Read moreRead less