Highly functional green materials platform: Starch-ionic liquid-carbon nanotube polymer melt nanocomposites. This project will deliver state of the art scientific advances in green polymers, green plasticisers and tailored nanomaterials for melt processible renewable starch plastics for high-performance applications as electroactive polymers in areas such as biosensors and biodiagnostics.
Self-reinforced biopolymer composites. This project will pioneer high performance and biodegradable composites using self-reinforced biopolymer composites. Composites can have poor properties due to interfacial issues, and this reduces their performance. By producing a fully self-reinforced (where the fibre and the polymer are the same type of polymer) polymer composites, the project will develop a way to improve properties, increase the use of biobased materials, and improve recyclability and b ....Self-reinforced biopolymer composites. This project will pioneer high performance and biodegradable composites using self-reinforced biopolymer composites. Composites can have poor properties due to interfacial issues, and this reduces their performance. By producing a fully self-reinforced (where the fibre and the polymer are the same type of polymer) polymer composites, the project will develop a way to improve properties, increase the use of biobased materials, and improve recyclability and biodegradability. Outcomes include greater understanding of design of self-reinforced biopolymer composites structure, processing and properties. This will produce opportunities for high performance biobased composite manufacturing and a growing circular plastics economy for Australia.Read moreRead less
Nanoporous Epoxy Thermosets via Microphase Separation of Block Copolymers. This project has many expected outcomes and benefits to Australia: (1) Development of the first technology to produce nanoporous epoxy thermosets (i.e. epoxy nanofoams) that may have many applications in microelectronics, optical waveguides and biological separations; (2) Providing impetus for an advanced materials synthesis and manufacturing industry for Australia and contributing to the Frontier Technologies National Re ....Nanoporous Epoxy Thermosets via Microphase Separation of Block Copolymers. This project has many expected outcomes and benefits to Australia: (1) Development of the first technology to produce nanoporous epoxy thermosets (i.e. epoxy nanofoams) that may have many applications in microelectronics, optical waveguides and biological separations; (2) Providing impetus for an advanced materials synthesis and manufacturing industry for Australia and contributing to the Frontier Technologies National Research Priority-Advanced Materials Priority Goals; (3) The development of new niche markets with these new materials and the new technologies, which is an excellent vehicle for Australia to move to a high-value added industrial portfolio that maximises return and promotes job growth.Read moreRead less
Bioplastics in the environment: lifetimes and toxicology. Globally, governments are implementing policies to drive a move to a circular economy. In the process, new materials are being introduced whose potential impacts need to be understood before they are widely used. This project pioneers investigations into the rate and extent of biodegradation of biodegradable plastics in aquatic and soil environments and the associated ecotoxicology of this process. In particular, it aims to quantify the e ....Bioplastics in the environment: lifetimes and toxicology. Globally, governments are implementing policies to drive a move to a circular economy. In the process, new materials are being introduced whose potential impacts need to be understood before they are widely used. This project pioneers investigations into the rate and extent of biodegradation of biodegradable plastics in aquatic and soil environments and the associated ecotoxicology of this process. In particular, it aims to quantify the extent to which the surfaces of these materials accumulate environmental pollutants via adsorption and other mechanisms. The outcomes will include conceptual models of biodegradation across environments, including lifetimes and likely impacts, critical information for framing a sustainable plastics industry.Read moreRead less
Core-shell nanofibrous bio-based flame retardants with reinforcement function. This project aims to develop high-performance bio-based flame retardants (FRs) by designing a novel core-shell nanofibrous FR system, combining exceptional flame retardant qualities and mechanical reinforcement to enhance the safe use of thermoplastic products. Thermoplastic products are widespread in building, electric and electronic, automobile and packaging products, but their intrinsic flammability poses great fir ....Core-shell nanofibrous bio-based flame retardants with reinforcement function. This project aims to develop high-performance bio-based flame retardants (FRs) by designing a novel core-shell nanofibrous FR system, combining exceptional flame retardant qualities and mechanical reinforcement to enhance the safe use of thermoplastic products. Thermoplastic products are widespread in building, electric and electronic, automobile and packaging products, but their intrinsic flammability poses great fire threats to the society. Flame retardants are key to producing fire-resistant plastic products with a low fire hazard rating. The novel bio-based flame retardant material developed by this project seeks to combine enhanced flame retardant properties and mechanical reinforcement functions. The outcomes of the project will demonstrate eco-friendly flame retardants and high performance flame retardant thermoplastic products.Read moreRead less
Novel Tough Polymer Composites. Advanced composites are used in high value-added applications such as computer chip packaging and aerospace applications. In these applications epoxy systems are used despite their inherent brittleness. Much research has focused on toughening epoxy systems, but most tougheners cause a reduction in processing or material properties. This project focuses on developing novel epoxy tougheners during the polymerisation of the epoxy-based composite. Specifically we will ....Novel Tough Polymer Composites. Advanced composites are used in high value-added applications such as computer chip packaging and aerospace applications. In these applications epoxy systems are used despite their inherent brittleness. Much research has focused on toughening epoxy systems, but most tougheners cause a reduction in processing or material properties. This project focuses on developing novel epoxy tougheners during the polymerisation of the epoxy-based composite. Specifically we will use novel hyperbranched [star-like] polymers that have excellent processing properties, high reactivity for structure control and the ability to control toughening at the molecular and macroscopic level to produce novel technology for advanced composites.
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Efficient CO and CO2 conversion to biopolymers using phototrophic bacteria. This project aims to deliver efficient processes for the large-scale production of biopolymers from low cost inputs, using phototrophic bacteria. Feedstocks include syngas from solid wastes and carbon-dioxide-hydrogen mixes from fossil and renewable sources. The choice of phototrophic bacteria avoids the energy losses associated with existing technologies, since photons are used instead of chemical energy for metabolic n ....Efficient CO and CO2 conversion to biopolymers using phototrophic bacteria. This project aims to deliver efficient processes for the large-scale production of biopolymers from low cost inputs, using phototrophic bacteria. Feedstocks include syngas from solid wastes and carbon-dioxide-hydrogen mixes from fossil and renewable sources. The choice of phototrophic bacteria avoids the energy losses associated with existing technologies, since photons are used instead of chemical energy for metabolic needs. This project enables the production and optimisation of biopolymers through collaborations between engineers, polymer scientists and molecular biologists. The project will deliver technologies to produce tough, flexible and affordable biopolymers, converting wastes and greenhouse gases to a valuable product.Read moreRead less
Bioinspired Ceramifiable Fire-Retardant Composite Coatings. This project aims to design bioinspired, adhesive, ceramifiable fire-retardant coatings through understanding their composition-property relationship and fire-retardant mechanism. The fire-retardant coatings are then applied to typical polymer foams to create fire-safe building thermal insulation materials. This project will generate new knowledge in materials science that helps to expedite next-generation advanced fire-retardant coatin ....Bioinspired Ceramifiable Fire-Retardant Composite Coatings. This project aims to design bioinspired, adhesive, ceramifiable fire-retardant coatings through understanding their composition-property relationship and fire-retardant mechanism. The fire-retardant coatings are then applied to typical polymer foams to create fire-safe building thermal insulation materials. This project will generate new knowledge in materials science that helps to expedite next-generation advanced fire-retardant coatings for a variety of flammable substrates. Expected outcomes of this project are cost-effective fire-retardant coatings and fire-safe, inexpensive thermal insulation materials. This project will bring significant economic benefits to Australia and help to create fire-resilient and energy-efficient buildings.Read moreRead less
Pro-Fluorescent Aryl Nitroxides: New Probes for Polymer Lifetime and Kinetics Research. Internal aryl rings present in novel probes developed for this project impart fluorescence which is efficiently and internally quenched by the presence of a paramagnetic nitroxide group. Scavenging of radicals by the nitroxide however "switches on" the fluorescence and this enables powerful new fluorescence-based detection levels for the technique of nitroxide free radical scavenging. Such sensitivity is a ....Pro-Fluorescent Aryl Nitroxides: New Probes for Polymer Lifetime and Kinetics Research. Internal aryl rings present in novel probes developed for this project impart fluorescence which is efficiently and internally quenched by the presence of a paramagnetic nitroxide group. Scavenging of radicals by the nitroxide however "switches on" the fluorescence and this enables powerful new fluorescence-based detection levels for the technique of nitroxide free radical scavenging. Such sensitivity is applicable to polymerization kinetics studies, as well as providing new means for the determination of materials lifetimes. The development of pro-fluorescent markers as indicators for polymer degradation would be a significant outcome for materials where component failure has a major negative impact.Read moreRead less
Encoding Interactions and Printability into Hairy Colloidal Biomaterials. Printing mixtures of live cells and biomaterials (or 'BioInks') to make bespoke engineered tissues has the potential to enable personalised platforms for therapeutic discovery and organ replacement. Using a novel high throughput approach to materials synthesis, BioInk design and process optimisation, this project aims to discover new biomaterials and printing nozzles to help realise this potential. It will produce new insi ....Encoding Interactions and Printability into Hairy Colloidal Biomaterials. Printing mixtures of live cells and biomaterials (or 'BioInks') to make bespoke engineered tissues has the potential to enable personalised platforms for therapeutic discovery and organ replacement. Using a novel high throughput approach to materials synthesis, BioInk design and process optimisation, this project aims to discover new biomaterials and printing nozzles to help realise this potential. It will produce new insights in colloid science, cell-laden biomaterials design, and BioInk processing. Structure-property-function guides for colloid-based BioInks and quality-assured bioprinting as outcomes represent significant benefits for researchers and industries alike engaged in biofabrication, cell therapy and biotherapeutics.Read moreRead less