The Interface of Oil-in-Water Emulsions. The interface between two immiscible liquids controls many phenomena including the formation and properties of emulsions, the nature of many chemical separation processes and the behaviour of biological systems. There are few methods to study such interfaces and most of these are susceptible to trace contamination by adventitious surfactants, but emulsions with their large surface area avoid this problem. Significant advances are possible with the new Aus ....The Interface of Oil-in-Water Emulsions. The interface between two immiscible liquids controls many phenomena including the formation and properties of emulsions, the nature of many chemical separation processes and the behaviour of biological systems. There are few methods to study such interfaces and most of these are susceptible to trace contamination by adventitious surfactants, but emulsions with their large surface area avoid this problem. Significant advances are possible with the new Australian technique of electroacoustics, complemented by neutron scattering, nmr, rheological and dielectric response measurements on concentrated emulsions. Our surfactant-free emulsions provide a fundamental breakthrough in such studies, leading to new materials from nanostructures.Read moreRead less
Poly-crystalline Thin Films for LASER Applications. This project is based on a recent discovery which reports LASER emission in disordered media such as polycrystalline ZnO. This behaviour appears to be related to the crystallographic properties of ZnO (wurztite) material. Using a novel deposition process the defect density, size of crystallites and macroscopic orientation within such thin films will be controlled independently. This will provide an opportunity to study the fundamental basis of ....Poly-crystalline Thin Films for LASER Applications. This project is based on a recent discovery which reports LASER emission in disordered media such as polycrystalline ZnO. This behaviour appears to be related to the crystallographic properties of ZnO (wurztite) material. Using a novel deposition process the defect density, size of crystallites and macroscopic orientation within such thin films will be controlled independently. This will provide an opportunity to study the fundamental basis of such behaviour. In conjunction with this the development of structure in similarly produced GaN (wurztite) films will be examined. This work should also provide practical information concerning the potential performance of LASER devices based on disordered materials.Read moreRead less
Smart Materials Between Two and Three Dimensions. Shape-memory alloys involving martensitic transformations, are important as smart materials. Both the transformation nucleation and the sample morphology are unsolved issues relevant for these applications. Of particular note are the softening of certain lattice-vibrational frequencies, the development of a tweed-like microstructure on cooling the material and the role of defects, particularly the sample surface, in the transformation process. ....Smart Materials Between Two and Three Dimensions. Shape-memory alloys involving martensitic transformations, are important as smart materials. Both the transformation nucleation and the sample morphology are unsolved issues relevant for these applications. Of particular note are the softening of certain lattice-vibrational frequencies, the development of a tweed-like microstructure on cooling the material and the role of defects, particularly the sample surface, in the transformation process. This project addresses these issues using model materials in thin-film and bulk-crystal forms. Capacitance dilatometry, optical, electron and scanning-probe microscopies, and x-ray techniques, will unlock an understanding of the physical and metallurgical conditions controlling these transformations.Read moreRead less
Interfacial Nanofluids. The fundamental understanding of Colloid and Surface Chemistry will be significantly enhanced through the understanding of the formation and properties of interfacial nanofluids. In addition, this project will provide the knowledge of the influence of nanofluids on the lubrication and the surface interaction. The future results will likely have great impact on the development of miniature devices, lab-on-a-chip and microfludics or nanofluidics systems, water treatment, m ....Interfacial Nanofluids. The fundamental understanding of Colloid and Surface Chemistry will be significantly enhanced through the understanding of the formation and properties of interfacial nanofluids. In addition, this project will provide the knowledge of the influence of nanofluids on the lubrication and the surface interaction. The future results will likely have great impact on the development of miniature devices, lab-on-a-chip and microfludics or nanofluidics systems, water treatment, minerals processing, the food industries, pumping of fuel and water, and other processes. And the research described in this proposal will help to maintain the high international profile of Australian science in the field of Colloid and Surface Research. Read moreRead less
Thin Films of Oxide Ceramics. Aluminium oxide films are used extensively in the Australian industries of Protective & Decorative Coatings (examples include door-knobs and cutting-tools). The industry will be offered a remarkably simple process for preparation of high quality films. In the microelectronic industry, the uses of aluminium oxide films as a dielectric alternative to silicon dioxide has just started to emerge world - wide and this new process would make a dramatic impact with commerci ....Thin Films of Oxide Ceramics. Aluminium oxide films are used extensively in the Australian industries of Protective & Decorative Coatings (examples include door-knobs and cutting-tools). The industry will be offered a remarkably simple process for preparation of high quality films. In the microelectronic industry, the uses of aluminium oxide films as a dielectric alternative to silicon dioxide has just started to emerge world - wide and this new process would make a dramatic impact with commercial benefits for Australia. Read moreRead less
Stream power and river morphology in partly-confined valleys of coastal New South Wales, Australia. Rivers in the escarpment-dominated catchments of coastal NSW are characterised by confined and partly-confined valley-settings in which channels have little capacity to adjust. The key aim of this project is to determine controls on the distribution of floodplains in this landscape. Particular attention will be placed on the role played by stream power in determining the relationship between val ....Stream power and river morphology in partly-confined valleys of coastal New South Wales, Australia. Rivers in the escarpment-dominated catchments of coastal NSW are characterised by confined and partly-confined valley-settings in which channels have little capacity to adjust. The key aim of this project is to determine controls on the distribution of floodplains in this landscape. Particular attention will be placed on the role played by stream power in determining the relationship between valley incision and lateral expansion processes along river courses. Understanding controls on these rivers is critical in determining how they modify their form in response to various disturbance events (whether 'natural' of human-induced). Results will provide a rigorous basis with which to explain cross-catchment variability in river forms and processes, aiding our capacity to predict future adjustments to disturbance and develop river management strategies that 'work with nature'.Read moreRead less
Template-Free Synthesis of Zeolite Nanocrystals and Their Application for Zeolite-Polymer Nanocomposites. A novel method is proposed for template-free synthesis of zeolite nanocrystals, in which polymer hydrogels will be used, in-situ, to control zeolite nucleation and growth from precursor solutions. The as-synthesised and surface modified zeolite nanocrystals will be used to fabricate zeolite-polymer nanocomposites, which will have significant applications in areas including gas separation, ca ....Template-Free Synthesis of Zeolite Nanocrystals and Their Application for Zeolite-Polymer Nanocomposites. A novel method is proposed for template-free synthesis of zeolite nanocrystals, in which polymer hydrogels will be used, in-situ, to control zeolite nucleation and growth from precursor solutions. The as-synthesised and surface modified zeolite nanocrystals will be used to fabricate zeolite-polymer nanocomposites, which will have significant applications in areas including gas separation, catalysts and fuel cells.Read moreRead less
Structure of Exotic Neutron-Rich Nuclei Populated Using Novel Reaction Mechanisms. Over half of the nuclei believed to be stable to particle decay have not been studied due to the lack of available nuclear reactions. We have played a leading role in developing innovative techniques using incomplete-fusion and deep-inelastic reactions to access neutron-rich nuclei that were inaccessible prior to this work. This project aims to study new phenomena in exotic, neutron-rich nuclei, building on Aust ....Structure of Exotic Neutron-Rich Nuclei Populated Using Novel Reaction Mechanisms. Over half of the nuclei believed to be stable to particle decay have not been studied due to the lack of available nuclear reactions. We have played a leading role in developing innovative techniques using incomplete-fusion and deep-inelastic reactions to access neutron-rich nuclei that were inaccessible prior to this work. This project aims to study new phenomena in exotic, neutron-rich nuclei, building on Australia's existing investment in this area, and, through international scientific leadership, facilitating the access of Australian researchers to highly competitive overseas facilities.Read moreRead less
Understanding, prediction and control of polymorphism in pharmaceuticals. The proposed research will lead, through a better understanding of polymorphism, to more efficient production of pharmaceuticals and will enhance the establishment and protection of patents. The work will have flow-on in other areas such as the manufacture of pigments, dyes and explosives. The project uses methodology for the elucidation of local structure and function at the atomic to nanoscale level in which Australia is ....Understanding, prediction and control of polymorphism in pharmaceuticals. The proposed research will lead, through a better understanding of polymorphism, to more efficient production of pharmaceuticals and will enhance the establishment and protection of patents. The work will have flow-on in other areas such as the manufacture of pigments, dyes and explosives. The project uses methodology for the elucidation of local structure and function at the atomic to nanoscale level in which Australia is a world leader. The project will further enhance our standing in this field and will provide excellent research training opportunities in areas particularly pertinent to future exploitation of the Australian Synchrotron and the new Research Reactor OPAL, which open in 2007. Read moreRead less
The Antarctic ice sheet through the Last Glacial Cycle - numerical modelling constrained by field evidence. The response of the world's largest ice mass to climate change is important because melting leads to a rise in sea level. Our ability to predict changes in ice volume and sea level under a warming climate, will be enhanced by better understanding of past ice sheet responses to changes in atmospheric carbon dioxide. Improved numerical models now exist that allow realistic simulations of Ant ....The Antarctic ice sheet through the Last Glacial Cycle - numerical modelling constrained by field evidence. The response of the world's largest ice mass to climate change is important because melting leads to a rise in sea level. Our ability to predict changes in ice volume and sea level under a warming climate, will be enhanced by better understanding of past ice sheet responses to changes in atmospheric carbon dioxide. Improved numerical models now exist that allow realistic simulations of Antarctic ice. These models will be developed further and constrained against existing and new field evidence for the Last Glacial Cycle (last 125,000 years), the period for which we can best define past ice sheet behaviour.Read moreRead less