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A Midas touch for electrophiles in new reaction development. This project aims to address the lack of knowledge about how high-value organic molecules are formed in gold-catalysed reactions by advancing a novel mode of catalysis. This project expects to generate new knowledge about these gold-catalysed reactions using an innovative, interdisciplinary approach incorporating computational and synthetic techniques. Expected outcomes of this project include the optimisation and development of import ....A Midas touch for electrophiles in new reaction development. This project aims to address the lack of knowledge about how high-value organic molecules are formed in gold-catalysed reactions by advancing a novel mode of catalysis. This project expects to generate new knowledge about these gold-catalysed reactions using an innovative, interdisciplinary approach incorporating computational and synthetic techniques. Expected outcomes of this project include the optimisation and development of important organic reactions and enhancing collaboration nationally and internationally between computational and synthetic chemists. This should provide significant benefits in the form of improved chemical reactions for chemists to prepare new pharmaceuticals, agrochemicals and materials.Read moreRead less
Metal complexes for activation and scission of small, multiply-bonded molecules. The outcome of this work is a series of metal complexes capable of cleaving the strong bonds in a number of small molecules of chemical importance. This will have a significant impact on industry by providing cheaper and safer alternatives to currently expensive and hazardous processes for producing nitrogen and phosphorus containing compounds.
Switchable and stereocontrolled photoredox catalysis. This project aims to develop new catalytic synthetic reactions for the rapid and more direct functionalisation of organic compounds under mild conditions with the use of visible light. An integrated experimental and computational approach will be used to design potent visible-light photocatalysts that retain the advantages of standard photoredox catalysis but with the added ability to intercept and, thus control, reactive intermediates in sit ....Switchable and stereocontrolled photoredox catalysis. This project aims to develop new catalytic synthetic reactions for the rapid and more direct functionalisation of organic compounds under mild conditions with the use of visible light. An integrated experimental and computational approach will be used to design potent visible-light photocatalysts that retain the advantages of standard photoredox catalysis but with the added ability to intercept and, thus control, reactive intermediates in situ. This will enable the control of stereochemistry in photoredox reactions – not possible with standard catalysts - and establish other useful synthetic transformations. These strategies will make it easier to prepare valuable classes of organic molecules – efficiently, safely, and cost-effectively.
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A new route to linear alpha olefins - catalytic isomerisation of internal olefins. Linear alpha olefins are an extremely important class of chemical building blocks used for everyday consumer products, such as plastics, detergents and lubricants. This research aims to develop a new platform technology for the production of these materials from low cost precursors.
Polymer nanoparticles and their assembled supracolloidal monolithic structures for applications in separation science. This project will generate new polymeric materials that will improve the analysis of complex samples. This will be applied in a wide range of areas of national importance including: pharmaceutical analysis and drug discovery; environmental, clinical and forensic analysis; and energy generation and foods.
Unraveling ocean mixing and air-sea forcing along the Indo-Pacific exchange. This project aims to collect unprecedented observations and develop high resolution model simulations to examine changes in the Indonesian Throughflow (ITF) north of Australia. This project expects to develop new knowledge of ocean-atmosphere interactions along the path of the ITF from the Pacific to the Indian Ocean, which are the powerhouse that drives changes in winds and rainfall around Australia and the entire Indo ....Unraveling ocean mixing and air-sea forcing along the Indo-Pacific exchange. This project aims to collect unprecedented observations and develop high resolution model simulations to examine changes in the Indonesian Throughflow (ITF) north of Australia. This project expects to develop new knowledge of ocean-atmosphere interactions along the path of the ITF from the Pacific to the Indian Ocean, which are the powerhouse that drives changes in winds and rainfall around Australia and the entire Indo-Pacific region. Expected outcomes include a 1000-fold increase in the observations of mixing in the Indonesian seas and new understanding of the ocean-atmosphere processes that control water property change along the ITF. This should lead to strong improvement in the skill of climate forecast models in the Australian region.Read moreRead less
A survey of the interstellar medium in the Milky Way and Magellanic Clouds using the Australian Square Kilometre Array Pathfinder. Between the stars in the Milky Way there are clouds of gas and dust; old stars eject heavy elements into this interstellar medium, and new stars form when interstellar clouds collapse under their own gravity. This survey is making maps of the interstellar gas using spectral lines at radio wavelengths to trace the cycle of star formation.
Understanding spread in sea level rise projections. This project aims to investigate changes in water properties and ocean circulation mechanisms leading to intermodel spread in sea-level projections. Sea-level rise projections for this 21st century largely disagree in magnitude and spatial changes between climate models, particularly in hotspots. The expected outcomes will contribute towards more rigorous constraints on the likelihood of future warming and sea-level rise projections, and are al ....Understanding spread in sea level rise projections. This project aims to investigate changes in water properties and ocean circulation mechanisms leading to intermodel spread in sea-level projections. Sea-level rise projections for this 21st century largely disagree in magnitude and spatial changes between climate models, particularly in hotspots. The expected outcomes will contribute towards more rigorous constraints on the likelihood of future warming and sea-level rise projections, and are aligned with scientific deliverables required to address key questions in support of Australia’s climate change policy. They are also aligned with international scientific deliverables in support of the World Climate Research Programme Grand Challenge on Regional Sea Level Change and Coastal Impacts.Read moreRead less
Observations of remarkable eastward flows in the South Indian Ocean. The Indian Ocean drives much of the variability of Australian weather and rainfall and is rapidly evolving. Innovative new observations of remarkable eastward flows in the South Indian Ocean will be combined with models to understand these circulations in a region that has significant economic value for Australia.
Calcification and shell chemistry response of Southern Ocean planktic foraminifers to ocean acidification and changing climates. Plankton that form tiny calcium carbonate shells will be cultured to determine how they will respond to acidification of the Southern Ocean caused by rising CO2 in the atmosphere. The same experiments will be used to gauge from their fossil shells how the Southern Ocean has caused and responded to changing atmosphere CO2 over the last glacial climate cycle