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Specific-ion effects in non-aqueous solvents. A test for Hofmeister. A colloidal solution is a liquid that contains a finely dispersed material. The properties of these solutions are critical in many industrially important practices and in the everyday processes of life. Though not understood, it is observed that the type of salt in solution controls how the colloid behaves. Through a series of very careful experiments we seek to learn precisely how different salts influence the properties of a ....Specific-ion effects in non-aqueous solvents. A test for Hofmeister. A colloidal solution is a liquid that contains a finely dispersed material. The properties of these solutions are critical in many industrially important practices and in the everyday processes of life. Though not understood, it is observed that the type of salt in solution controls how the colloid behaves. Through a series of very careful experiments we seek to learn precisely how different salts influence the properties of a colloidal solution. This world-leading research will enable us to improve our fundamental understanding of colloids and thereby facilitate advances in topics as diverse as enzymatic action and minerals purification, ensuring Australia remains at the forefront of science in this field.Read moreRead less
Maximizing solid state Nuclear Magnetic Resonance (NMR) with maximum entropy. Nuclear magnetic resonance is an essential technology for the characterisation of important industrial and biomedical molecules, molecular chains and complexes. This project aims to considerably expand the fundamental capability of experimental techniques for the study of materials in the solid state, in particular for a new class of biological nanoparticle. These advances will have important global implications for re ....Maximizing solid state Nuclear Magnetic Resonance (NMR) with maximum entropy. Nuclear magnetic resonance is an essential technology for the characterisation of important industrial and biomedical molecules, molecular chains and complexes. This project aims to considerably expand the fundamental capability of experimental techniques for the study of materials in the solid state, in particular for a new class of biological nanoparticle. These advances will have important global implications for research into life-saving therapeutic strategies aimed at many pharmaceutical targets embedded in cell membranes, protein misfolding disorders such as Alzheimer's disease and Huntington's disease, as well as development of the next generation of "green" plastics and other advanced polymers.Read moreRead less
Designed peptides as functional surfactants. Surfactants are essential in many applications for making oil-water mixtures, e.g. in dissolving drugs, extracting crude oil or spraying crops. However, chemical surfactants are toxic and can accumulate in the environment. This work will develop biodegradable surfactants that can be switched "on" and "off" as needed and do not cause toxicity to living organisms. One of many potential applications is in vaccines for use in remote Aboriginal communities ....Designed peptides as functional surfactants. Surfactants are essential in many applications for making oil-water mixtures, e.g. in dissolving drugs, extracting crude oil or spraying crops. However, chemical surfactants are toxic and can accumulate in the environment. This work will develop biodegradable surfactants that can be switched "on" and "off" as needed and do not cause toxicity to living organisms. One of many potential applications is in vaccines for use in remote Aboriginal communities. In these communities, skin infections from scabies and streptococcus are epidemic, and can lead to kidney failure and heart disease. A non-damaging skin cream based on the peptides could both treat short-term discomfort and deliver a vaccine to prevent long-term health consequences.Read moreRead less
Discovering new organic chemistry using an inorganic touch. This project aims to discover new organic chemistry by treating carbon like a metal atom. Advances in fundamental organic chemistry have been important in developing products, including medicines, plastics and television display technology. Much research activity relies on applying existing organic chemistry, but inventing genuinely new organic chemistry is more difficult. By viewing carbon as a metal, this project will try to solve imp ....Discovering new organic chemistry using an inorganic touch. This project aims to discover new organic chemistry by treating carbon like a metal atom. Advances in fundamental organic chemistry have been important in developing products, including medicines, plastics and television display technology. Much research activity relies on applying existing organic chemistry, but inventing genuinely new organic chemistry is more difficult. By viewing carbon as a metal, this project will try to solve important problems in organic chemistry that have been unresolved for decades, and synthesise valuable chemicals normally generated using expensive precious metal catalysts.Read moreRead less
Fill it, Squeeze it, Crush it: Extreme Gas Uptake in Microporous Materials . Porous materials have the potential to be used as exceptional carbon capture materials, as well as for trapping and releasing other useful gases, such as those used in medical applications. They work, because they contain small holes where these gases can be trapped. Unfortunately, finding gas inside these holes experimentally is incredibly difficult, making it challenging to make better porous materials. In this pro ....Fill it, Squeeze it, Crush it: Extreme Gas Uptake in Microporous Materials . Porous materials have the potential to be used as exceptional carbon capture materials, as well as for trapping and releasing other useful gases, such as those used in medical applications. They work, because they contain small holes where these gases can be trapped. Unfortunately, finding gas inside these holes experimentally is incredibly difficult, making it challenging to make better porous materials. In this project, I will use extreme pressures to saturate these holes with gas molecules, allowing us to ‘see’ them. Not only will this mean that better porous materials can be designed and made, but will provide a unique approach to storing and trapping gases to be used in a variety of applications, from the energy to medical sectors.Read moreRead less
Unravelling how liquids wet surfaces with new dynamic measurements. This project aims to transform our understanding of how liquids wet surfaces in order to provide a step-change in advanced material design. This will be achieved by developing a unifying theory of surface wetting by integrating new microscale models of dynamic wetting with new macroscale automated measurement techniques capable of rapidly generating large datasets, to determine precisely how surface chemistry and surface roughne ....Unravelling how liquids wet surfaces with new dynamic measurements. This project aims to transform our understanding of how liquids wet surfaces in order to provide a step-change in advanced material design. This will be achieved by developing a unifying theory of surface wetting by integrating new microscale models of dynamic wetting with new macroscale automated measurement techniques capable of rapidly generating large datasets, to determine precisely how surface chemistry and surface roughness influence wetting. Expected outcomes include predictive models of surface wetting across multiple scales, and robust high-throughput measurement methods informing optimal design of next-generation materials for all applications where liquids and surfaces interact.Read moreRead less
Moving supramolecular assembly of functional systems into water. Smart materials that are pre-programmed to assemble in water have already been shown to have wide applicability from industry to medicine. This project will develop novel display and drug release materials and lead to novel means to control these programmable building blocks thus promoting Australia’s standing in the area of smart materials.
Enhancing our understanding of metallochemistry in neurobiology with modern electron paramagnetic resonance (EPR) spectroscopy. Many neurological diseases involve protein accumulation that appears causally linked to abnormal levels of metal ions in the brain. This project will use a special technique called electron paramagnetic resonance to uncover how these metals interact with specific proteins at the molecular level and how drug treatments can modify these interactions.
Next generation supramolecular frameworks. This project aims to prepare new supramolecular frameworks assembled by hydrogen or halogen bonds. It is anticipated that this work will increase fundamental understanding of supramolecular self-assembly processes and the dynamic processes that are possible within these rearrangeable systems. The project aims to prepare a family of related frameworks, which will allow a detailed comparison of the stability, porosity and biotechnological applicability of ....Next generation supramolecular frameworks. This project aims to prepare new supramolecular frameworks assembled by hydrogen or halogen bonds. It is anticipated that this work will increase fundamental understanding of supramolecular self-assembly processes and the dynamic processes that are possible within these rearrangeable systems. The project aims to prepare a family of related frameworks, which will allow a detailed comparison of the stability, porosity and biotechnological applicability of new supramolecular materials. The expected outcomes are the development of lightweight and benign organic systems that will have applications in the removal of toxic organic and heavy metal pollutants from water, and in the encapsulation and stabilisation of catalytically-active enzymes.Read moreRead less
Photonic circuitry from the noble metals: nanocrystal coupling. Linear arrays of crystalline nanoparticles are able to act in a manner analogous to an optical fibre, but with much smaller dimensions. This project will investigate the underlying principles of waveguiding within the arrays and aims to build and test sections of such optical fibres, thereby assessing their use in optical circuits.