Soft solids rheology and filled elastomeric networks. Elastomeric networks that have imbedded particles are considerably more difficult to model than unfilled networks because the imbedded particles deform the trajectory of the chains. Any treatment must incorporate this dual nature of the network. Our work will address this important issue with particular reference to two important materials - liquid crystalline elastomers and bread dough. We aim to produce an accurate mathematical description ....Soft solids rheology and filled elastomeric networks. Elastomeric networks that have imbedded particles are considerably more difficult to model than unfilled networks because the imbedded particles deform the trajectory of the chains. Any treatment must incorporate this dual nature of the network. Our work will address this important issue with particular reference to two important materials - liquid crystalline elastomers and bread dough. We aim to produce an accurate mathematical description of filled soft viscoelastic solids, which include compressibility and yielding - two important new features.Read moreRead less
THEORETICAL AND EXPERIMENTAL STUDIES OF BLOCK COPOLYMER MELTS AS NANO-MATERIALS. We shall theoretically study and predict the possible morphologies of a wide range of block copolymer architectures with a combination of simulations and accurate numerical theories. These block copolymer melts are of great technological importance because they can self-assemble into morphological patterns which are periodic on a nano-scale. Hence they are now being intensively investigated for uses in applications ....THEORETICAL AND EXPERIMENTAL STUDIES OF BLOCK COPOLYMER MELTS AS NANO-MATERIALS. We shall theoretically study and predict the possible morphologies of a wide range of block copolymer architectures with a combination of simulations and accurate numerical theories. These block copolymer melts are of great technological importance because they can self-assemble into morphological patterns which are periodic on a nano-scale. Hence they are now being intensively investigated for uses in applications as diverse as lithographic templates for electronic and optical devices, nano-porous membranes and photonic band gap materials. We shall verify our theoretical predictions by carrying out experiments on the various molecular architectures that we have studied theoretically.Read moreRead less
Special Research Initiatives - Grant ID: SR0354521
Funder
Australian Research Council
Funding Amount
$10,000.00
Summary
Network for Advanced Materials for Engineering Applications. Advances in modern technology and a competitive manufacturing industry depend critically on new and improved materials. The pace of change is rapid, and many countries are taking steps to improve and coordinate developments. Australia has a very successful record of materials research and innovation and is developing a substantial infrastructure in the area. However, the materials research community is scattered, and research effect ....Network for Advanced Materials for Engineering Applications. Advances in modern technology and a competitive manufacturing industry depend critically on new and improved materials. The pace of change is rapid, and many countries are taking steps to improve and coordinate developments. Australia has a very successful record of materials research and innovation and is developing a substantial infrastructure in the area. However, the materials research community is scattered, and research effectiveness is sometimes lessened by a lack of critical mass. This network will bring together university, government and industry researchers, and promote collaborative research, access to each other's facilities, staff and student exchanges, improved access to existing infrastructure and coordinated planning for new acquisitions.Read moreRead less
Nanostructured Hydrogel-Carbon Nanotube Composites for Artificial Muscles. This collaboration links the expertise of the two groups in advanced functional materials for the development of improved mechanical actuators for artificial muscles. The Korean group provides key know-how in synthetic and natural hydrogels. The Wollongong team has developed expertise in carbon nanotube actuators. The hydrogel-nanotube hybrids resulting from this collaboration are likely to show improved performance co ....Nanostructured Hydrogel-Carbon Nanotube Composites for Artificial Muscles. This collaboration links the expertise of the two groups in advanced functional materials for the development of improved mechanical actuators for artificial muscles. The Korean group provides key know-how in synthetic and natural hydrogels. The Wollongong team has developed expertise in carbon nanotube actuators. The hydrogel-nanotube hybrids resulting from this collaboration are likely to show improved performance compared with existing materials. The improved actuators will be utilised in on-going projects in both countries.Read moreRead less
New Types of Biomimetic Nanostructured Adhesives. Adhesives are one of the main ways in which we join materials, and have many advantages over other methods of joining. In this work we will make a new class of adhesive using nanotechnology that attempts to copy the very fine-haired feet of animals such as geckos who can stick to almost any surface, under most conditions. We will make these adhesives over large surface areas, and thus they will have commercial possibilities in a range of high tec ....New Types of Biomimetic Nanostructured Adhesives. Adhesives are one of the main ways in which we join materials, and have many advantages over other methods of joining. In this work we will make a new class of adhesive using nanotechnology that attempts to copy the very fine-haired feet of animals such as geckos who can stick to almost any surface, under most conditions. We will make these adhesives over large surface areas, and thus they will have commercial possibilities in a range of high technology industries, as well as in harsh environments. Because we will be able to manipulate the structure and observe property changes, it should also give us a greater insight into the adhesion mechanisms used by many small animals and bugs.Read moreRead less
Molecular modelling of the structure and mechanical properties of clay-based polymer nanocomposites. Nanotechnology is one of the most rapidly growing areas in the 21st century. Its world market is expected to reach US$2.6 trillions in 2014, valued at 15% of global manufacturing output. The use of clay nanofillers as polymer reinforcement is an emerging cutting-edge research and of paramount importance in Australia in view of its heavy dependence on mineral industries. The project will tackle th ....Molecular modelling of the structure and mechanical properties of clay-based polymer nanocomposites. Nanotechnology is one of the most rapidly growing areas in the 21st century. Its world market is expected to reach US$2.6 trillions in 2014, valued at 15% of global manufacturing output. The use of clay nanofillers as polymer reinforcement is an emerging cutting-edge research and of paramount importance in Australia in view of its heavy dependence on mineral industries. The project will tackle the core problems in this field. The research outcomes will lead to highly value-added mineral products and better process control. Furthermore, the application of polymer nanocomposites in automotive and packaging industries will significantly decrease energy consumption and CO2 emission, and increase the shelf-life for food and beverage. Read moreRead less
An innovative approach to fabricate thermally stable polymer/layered silicate nanocomposites. By fully taking advantage of excellent affinity of water with polar layered silicate and polar polymer, an innovative approach to fabricate thermally stable polymer/layered silicate nanocomposites via melt extrusion with the aid of water/water vapour will be developed. In this process, the pristine layered silicate will be directly exfoliated into individual layers with nanometer thickness and high aspe ....An innovative approach to fabricate thermally stable polymer/layered silicate nanocomposites. By fully taking advantage of excellent affinity of water with polar layered silicate and polar polymer, an innovative approach to fabricate thermally stable polymer/layered silicate nanocomposites via melt extrusion with the aid of water/water vapour will be developed. In this process, the pristine layered silicate will be directly exfoliated into individual layers with nanometer thickness and high aspect ratio, and uniformly dispersed in a polymer matrix. This novel approach is environmentally benign and cost-effective since no alkyl ammonium surfactants are required. The resultant nanocomposites will exhibit excellent barrier properties, high thermal stability, environmental durability and superior mechanical properties. These qualities make them very attractive for many applications in the automotive and packaging industries.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0560981
Funder
Australian Research Council
Funding Amount
$160,940.00
Summary
Confronting the Challenges in Modern Spectroscopy of Polymers. Polymers and nanocomposites are increasingly being used in new, high value applications as diverse as medicine, structural engineering, optics and electronics. In order to control and understand polymer performance, a detailed knowledge of the chemical structure at all stages in their lifecycle is required - in the liquid, rubber and solid states and during degradation. This application seeks to establish a coordinated Polymer Spectr ....Confronting the Challenges in Modern Spectroscopy of Polymers. Polymers and nanocomposites are increasingly being used in new, high value applications as diverse as medicine, structural engineering, optics and electronics. In order to control and understand polymer performance, a detailed knowledge of the chemical structure at all stages in their lifecycle is required - in the liquid, rubber and solid states and during degradation. This application seeks to establish a coordinated Polymer Spectroscopy Network using new forms of infrared and NMR spectroscopy to probe samples (usually of an non-planar geometry) in a range of configurations. These will be used simultaneously with other techniques such as rheology or thermogravimetry, and will produce capabilities unique in Australia.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE120102784
Funder
Australian Research Council
Funding Amount
$375,000.00
Summary
Water-swellable rubber with nanoparticle-enabled super capacity as smart water-leakage sealant. A novel water-swellable rubber (WSR) sealant with continuous hydrophobic phase and isolated hydrophilic phase is developed for stopping water leakage from gaps and cracks. Nanoparticle-enabled blocks and network channels in rubber matrix effectively improve the integrity and capability of WSR as smart water-leakage sealants in various applications.
The development of super-toughened epoxies using a novel nanomaterial. Epoxy resins are widely used as structural adhesives and coatings in engineering structures. This project will address the problem of the intrinsic brittleness of epoxy by making it significantly tougher with superior performance and cost-effectiveness. Our technology for producing super-toughened epoxy will lead to a wide range of applications for new and existing products in the construction, automotive, aerospace, adhesive ....The development of super-toughened epoxies using a novel nanomaterial. Epoxy resins are widely used as structural adhesives and coatings in engineering structures. This project will address the problem of the intrinsic brittleness of epoxy by making it significantly tougher with superior performance and cost-effectiveness. Our technology for producing super-toughened epoxy will lead to a wide range of applications for new and existing products in the construction, automotive, aerospace, adhesive and microelectronics industries.Read moreRead less