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All-solid-state: new hybrid materials for next-generation lithium batteries. The aim of the project is an economically viable design for “all-solid-state” rechargeable batteries. Eliminating organic liquid electrolytes from lithium-ion batteries will dramatically increase safety, range of operating conditions, lifetimes, and energy density. The key technical challenge is keeping solid-solid interfaces intact over thousands of charge/discharge cycles. We will address this by inserting inorganic i ....All-solid-state: new hybrid materials for next-generation lithium batteries. The aim of the project is an economically viable design for “all-solid-state” rechargeable batteries. Eliminating organic liquid electrolytes from lithium-ion batteries will dramatically increase safety, range of operating conditions, lifetimes, and energy density. The key technical challenge is keeping solid-solid interfaces intact over thousands of charge/discharge cycles. We will address this by inserting inorganic interfacial layers that change smoothly from hard ceramic to flexible glass and back again, through rigorous chemical design and synthetic control. This will reduce the stress that causes mechanical failure, while increasing chemical stability so that the latest generation of high-power electrodes can be brought into service.Read moreRead less
Advanced Molecular Frameworks for Sodium Battery Electrode Applications. This project aims to develop new molecular materials capable of high capacity sodium-ion insertion. Through an innovative interdisciplinary approach that targets the synthesis and detailed characterisation of an extensive family of materials this project expects to generate major advances in the understanding of how the chemical, physical and structural attributes of the materials relate to their electrical charge/discharge ....Advanced Molecular Frameworks for Sodium Battery Electrode Applications. This project aims to develop new molecular materials capable of high capacity sodium-ion insertion. Through an innovative interdisciplinary approach that targets the synthesis and detailed characterisation of an extensive family of materials this project expects to generate major advances in the understanding of how the chemical, physical and structural attributes of the materials relate to their electrical charge/discharge behaviours. Significant anticipated outcomes and benefits include the development of new material design approaches that optimise battery electrode performance across a diverse parameter space, and the generation of advanced new materials worthy of commercial development in low-cost, large-scale battery applications.Read moreRead less
Scaffolding layered structures to improve insertion electrodes. This project aims to change how positive electrodes are designed and improve battery performance. The positive electrode is arguably the largest bottleneck in battery performance. Modifying layered electrodes to produce better batteries has ramifications ranging from longer-lasting portable power for everyday devices and vehicles to energy storage solutions for intermittent power generation sources (i.e., renewables). This project w ....Scaffolding layered structures to improve insertion electrodes. This project aims to change how positive electrodes are designed and improve battery performance. The positive electrode is arguably the largest bottleneck in battery performance. Modifying layered electrodes to produce better batteries has ramifications ranging from longer-lasting portable power for everyday devices and vehicles to energy storage solutions for intermittent power generation sources (i.e., renewables). This project will develop scaffolded layered crystal structures to improve the ease, speed and amount of ion insertion/extraction. These structures will be incorporated into lithium and sodium ion batteries, resulting in better battery lifetime, energy density and charge/discharge speed (capability). This is expected to improve batteries for the future and decrease reliance on fossil fuels for energy.Read moreRead less
Shifting the trend in radical battery research . The project aims to address a growing problem of increasing energy consumption by storing intermittent energy from the sun in affordable and efficient flow batteries. The project expects to generate new knowledge in the areas of materials science and battery research by using innovative theoretical chemistry approaches to studying electrochemical properties of nitroxide radicals in ionic media. The project aims to develop radical organic flow batt ....Shifting the trend in radical battery research . The project aims to address a growing problem of increasing energy consumption by storing intermittent energy from the sun in affordable and efficient flow batteries. The project expects to generate new knowledge in the areas of materials science and battery research by using innovative theoretical chemistry approaches to studying electrochemical properties of nitroxide radicals in ionic media. The project aims to develop radical organic flow batteries by utilising ionic liquids to stabilise radicals. Intended outcomes of the project include improved efficiency of flow batteries that can store energy from widely used solar panels. This should provide significant benefits to Australia’s effort to switch to renewable energy technologies. Read moreRead less
Electrode-Supported Ionogels for Reversible Energy Storage. The project aims to generate an understanding of electrode-supported ionic liquid gel films to form the basis for the rational design and development of new energy storage technology. For the world to truly move into a new age of low carbon power, it needs transformational battery technology. The creation of novel ionic liquid systems to capture redox-active species would allow for revolutionary designs with the potential to eliminate m ....Electrode-Supported Ionogels for Reversible Energy Storage. The project aims to generate an understanding of electrode-supported ionic liquid gel films to form the basis for the rational design and development of new energy storage technology. For the world to truly move into a new age of low carbon power, it needs transformational battery technology. The creation of novel ionic liquid systems to capture redox-active species would allow for revolutionary designs with the potential to eliminate membranes, with major advantages for charging/discharging speed and deep cyclability. This would directly translate to storage systems that combine high power with high energy density.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE160100596
Funder
Australian Research Council
Funding Amount
$372,000.00
Summary
Lithium-Ion Conducting Sulfide Cathodes for All-Solid-State Li–S Batteries. The aim of the project is to develop lithium-ion conducting sulphide cathode materials for high-performance all-solid-state lithium-sulphur (Li–S) batteries. Substituting solid-state electrolyte for liquid electrolyte is the most efficient approach to eliminate the polysulfide shuttle effect, which is the biggest obstacle for the practical application of Li–S batteries based on liquid electrolytes. The project aims to de ....Lithium-Ion Conducting Sulfide Cathodes for All-Solid-State Li–S Batteries. The aim of the project is to develop lithium-ion conducting sulphide cathode materials for high-performance all-solid-state lithium-sulphur (Li–S) batteries. Substituting solid-state electrolyte for liquid electrolyte is the most efficient approach to eliminate the polysulfide shuttle effect, which is the biggest obstacle for the practical application of Li–S batteries based on liquid electrolytes. The project aims to develop novel Li2S-rich cathode materials with high lithium-ion conductivity, which will form the basis of all-solid-state Li–S batteries with high energy density. The new battery is expected to have wide applications in portable electronic devices, electric vehicles and grid-scale renewable energy storage.Read moreRead less
Bioinspired tuneable catalysts for renewable ammonia production. The project will design a new solar-powered system for electrosynthesis of ammonia to replace the current energy intensive, non-sustainable process that generates 1.5% of global CO2 emissions. An innovative new system will be developed by combining cutting edge electrochemical, spectroscopic and theoretical methods. Expected key outcomes include novel concepts in the design of advanced materials, and an efficient process for the gr ....Bioinspired tuneable catalysts for renewable ammonia production. The project will design a new solar-powered system for electrosynthesis of ammonia to replace the current energy intensive, non-sustainable process that generates 1.5% of global CO2 emissions. An innovative new system will be developed by combining cutting edge electrochemical, spectroscopic and theoretical methods. Expected key outcomes include novel concepts in the design of advanced materials, and an efficient process for the green ammonia synthesis. Given the strategic importance of ammonia as a future energy carrier for the export of Australian renewables and as a major source of fertilisers, this project should provide significant national economic and ecological benefits and is expected to have a broad reaching global impact.Read moreRead less
Sodium ion interactions with biomass-derived hard carbon electrodes. This project aims to investigate sodium ion behavior when electrochemically interacting with hard carbon electrode materials by using both in-situ and ex-situ techniques in combination with advanced computational methods. This project expects to generate new knowledge and establish structure-property-performance correlations, thus providing guidelines and strategies for synthesising cost-effective electrode materials from bioma ....Sodium ion interactions with biomass-derived hard carbon electrodes. This project aims to investigate sodium ion behavior when electrochemically interacting with hard carbon electrode materials by using both in-situ and ex-situ techniques in combination with advanced computational methods. This project expects to generate new knowledge and establish structure-property-performance correlations, thus providing guidelines and strategies for synthesising cost-effective electrode materials from biomass for developing sustainable sodium-ion batteries. The intended outcome of this project includes knowledge advancement, enhanced capability to build international collaborations, training of early career researchers and students, and positioning Australia on the world map as a world-leading nation in energy storage.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE220100350
Funder
Australian Research Council
Funding Amount
$450,000.00
Summary
Sodium inventory for sodium-ion batteries. This project aims to increase the energy density and cycle life of sodium-ion batteries by investigating practical ways to increase the amount of cycleable sodium ions. This project expects to generate new knowledge in the field of energy storage using an innovative approach to address the key issues facing sodium-ion batteries. Expected outcomes of this project include the development of a novel high-energy sodium-ion battery, achieved by practical sod ....Sodium inventory for sodium-ion batteries. This project aims to increase the energy density and cycle life of sodium-ion batteries by investigating practical ways to increase the amount of cycleable sodium ions. This project expects to generate new knowledge in the field of energy storage using an innovative approach to address the key issues facing sodium-ion batteries. Expected outcomes of this project include the development of a novel high-energy sodium-ion battery, achieved by practical sodium inventory solutions and fundamental understanding of internal battery processes. This should provide significant benefits including lowering the cost of energy storage, decreasing the reliance on lithium, and facilitating society’s shift towards renewable and sustainable energy sources.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE160100237
Funder
Australian Research Council
Funding Amount
$389,754.00
Summary
A new method to realise zero thermal expansion materials. The aim of the project is to produce a novel method to create zero thermal expansion materials. It is anticipated that this new method will be faster and provide an unprecedented level of control of the thermal expansion properties of the materials. Since thermal degradation plagues components in industry, for example in all engines and electronics, a zero thermal expansion material can indefinitely avoid such problems and thereby increas ....A new method to realise zero thermal expansion materials. The aim of the project is to produce a novel method to create zero thermal expansion materials. It is anticipated that this new method will be faster and provide an unprecedented level of control of the thermal expansion properties of the materials. Since thermal degradation plagues components in industry, for example in all engines and electronics, a zero thermal expansion material can indefinitely avoid such problems and thereby increase the life of the components or devices. This project will also potentially deliver an understanding of the mechanisms behind zero thermal expansion, thus allowing the rational design of future materials that could increase the lifespan and durability of a range of products.Read moreRead less