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Fluorous Chemistry: New tagging agents and heterocyclic-based fluorous surfactants. Fluorous chemistry is emerging as a powerful adjunct to areas of conventional parallel and combinatorial organic syntheses, and its introduction has revolutionised separation technologies. In this project two new fluorous tagging strategies will be investigated in an effort to broaden the scope of reagents that can used in synthesis. Efforts will be directed to chiral auxiliaries and to fluorous catalyst ligands. ....Fluorous Chemistry: New tagging agents and heterocyclic-based fluorous surfactants. Fluorous chemistry is emerging as a powerful adjunct to areas of conventional parallel and combinatorial organic syntheses, and its introduction has revolutionised separation technologies. In this project two new fluorous tagging strategies will be investigated in an effort to broaden the scope of reagents that can used in synthesis. Efforts will be directed to chiral auxiliaries and to fluorous catalyst ligands. In addition, a novel class of fluorous surfactant will be investigated, for its surface properties (including its ability to self assemble) and for its utility in two specific applications, selective membrane-bound protein extraction (relevant to proteomics) and ophthalmics (biomaterials).Read moreRead less
Improving explosive emulsions by understanding surfactant interactions. This project will design new surfactants that will lead to more cost effective, stable and reliable explosive emulsions. The pressure required to force dispersed phase droplets to coalesce will be measured both directly and by osmotic stress. These parameters have not previously been measured for an inverse emulsion system. The measurements made will be correlated to the structure of the stabilising surfactant enabling new a ....Improving explosive emulsions by understanding surfactant interactions. This project will design new surfactants that will lead to more cost effective, stable and reliable explosive emulsions. The pressure required to force dispersed phase droplets to coalesce will be measured both directly and by osmotic stress. These parameters have not previously been measured for an inverse emulsion system. The measurements made will be correlated to the structure of the stabilising surfactant enabling new and more effective surfactants to be designed.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0560679
Funder
Australian Research Council
Funding Amount
$932,870.00
Summary
Materials and Surface Characterisation Facility. Australian scientists are well positioned to be at the forefront of nanotechnology, biotechnology and advanced materials development. The proposed Facility, housing state-of-the-art equipment, will enable cutting-edge research in these areas by internationally renowned researchers at the University of Melbourne, Monash University, RMIT University, and CSIRO. Such research will facilitate the development of advanced materials for diverse applicatio ....Materials and Surface Characterisation Facility. Australian scientists are well positioned to be at the forefront of nanotechnology, biotechnology and advanced materials development. The proposed Facility, housing state-of-the-art equipment, will enable cutting-edge research in these areas by internationally renowned researchers at the University of Melbourne, Monash University, RMIT University, and CSIRO. Such research will facilitate the development of advanced materials for diverse applications including drug delivery, quantum computing, photonics and tissue engineering. The multi-user Facility will enable closer collaboration with researchers in academia and industry, and will be integral in training the next generation of Australian scientists in the nano- and biosciences.Read moreRead less
Controlled Macromolecular Architectures for Functional Nanomaterials Design. The research involves an exciting and innovative collaboration between two internationally recognized Australian research groups, cementing Australia's position as a leading country for research in polymer science and nanotechnology. Advanced polymer chemistry will be used to make ?smart? polymers that can controllably respond to changes in their surroundings. These will then be assembled to form materials with dimensio ....Controlled Macromolecular Architectures for Functional Nanomaterials Design. The research involves an exciting and innovative collaboration between two internationally recognized Australian research groups, cementing Australia's position as a leading country for research in polymer science and nanotechnology. Advanced polymer chemistry will be used to make ?smart? polymers that can controllably respond to changes in their surroundings. These will then be assembled to form materials with dimensions of the order of millionths of millimeters - forming so-called "smart nanomaterials". The materials prepared are expected to find application in the agricultural and pharmaceutical sectors, contributing to the well-being of Australian citizens and the development of a robust Australian industry.Read moreRead less
Electrochemistry of redox-active non-metal compounds. Unsaturated compounds of heavier non-metal elements can exist in multiple stable redox states. The interconversion is best assessed by electrochemical techniques, which can measure the energetics and the mechanism of the redox processes involved in both solution and solid state phases. Compounds to be studied will be prepared in the Canadian laboratories of the partner investigator. The electrochemical and spectroelectrochemical properties ....Electrochemistry of redox-active non-metal compounds. Unsaturated compounds of heavier non-metal elements can exist in multiple stable redox states. The interconversion is best assessed by electrochemical techniques, which can measure the energetics and the mechanism of the redox processes involved in both solution and solid state phases. Compounds to be studied will be prepared in the Canadian laboratories of the partner investigator. The electrochemical and spectroelectrochemical properties will initially be investigated in Australia during the visit of the partner investigator to Monash University with follow up studies in both countries. The mutual skills of synthesis and electrochemistry in the Canadian-Australian laboratories are essential to the project.Read moreRead less
Advanced nanoparticle stabilisation and functionalisation: small particles with huge potential. Australia is strongly investing in nanotechnology and through the governments priority goals 'Frontier Technologies for Building and Transforming Australian Industries' it has been recognised as an important area for investment. This proposal will help develop an internationally recognised nano-industry. It is envisaged that the particles made during this work will have direct implications for the pub ....Advanced nanoparticle stabilisation and functionalisation: small particles with huge potential. Australia is strongly investing in nanotechnology and through the governments priority goals 'Frontier Technologies for Building and Transforming Australian Industries' it has been recognised as an important area for investment. This proposal will help develop an internationally recognised nano-industry. It is envisaged that the particles made during this work will have direct implications for the public - creating a new class of medical diagnostic particles with better resolution and specificity. These particles have the potential to diagnose patients more precisely and at an earlier stage than is currently available. Additionally, these particles could be designed to load drugs and hence could be used to treat diseases such as cancer.Read moreRead less
Bubble Stabilization and Density Control in Self-Supporting Explosive Emulsions. The mining industry in Australia employs about 70,000 people and has a total sales and service income of about $55B. Most mining outputs are commodities and a reduction in cost is the primary method of increasing market share. DNAP is a major supplier of explosive services to mines that produce coal, iron ore and gold for export. The work in this project will lead to more efficient explosives emulsions and allow mi ....Bubble Stabilization and Density Control in Self-Supporting Explosive Emulsions. The mining industry in Australia employs about 70,000 people and has a total sales and service income of about $55B. Most mining outputs are commodities and a reduction in cost is the primary method of increasing market share. DNAP is a major supplier of explosive services to mines that produce coal, iron ore and gold for export. The work in this project will lead to more efficient explosives emulsions and allow mining tolower total cost per unit sold. Such improvements in mining efficiencies will have a direct impact of the selling price of the product. Increased export earnings and a greater number of people employed in the industry would be direct results of the successful completion of the work proposed.Read moreRead less
Understanding Electron Transfer through Surface Bound Rigid Molecular Constructs: From Fundamental Studies to New Sensing and Photovoltaic Applications. Electron transfer is not only a vital process in biological systems but is the cornerstone of the new generation of nanoscale devices such as molecular electronics, photovoltaic devices and biosensors. For most applications electron transfer occurs close to a surface but the influence of the surface is not well understood. This project aims ....Understanding Electron Transfer through Surface Bound Rigid Molecular Constructs: From Fundamental Studies to New Sensing and Photovoltaic Applications. Electron transfer is not only a vital process in biological systems but is the cornerstone of the new generation of nanoscale devices such as molecular electronics, photovoltaic devices and biosensors. For most applications electron transfer occurs close to a surface but the influence of the surface is not well understood. This project aims to increase our understanding of the role of surfaces on the electron transfer behaviour using a novel range of rigid 'molecular wires'. The knowledge gained will be exploited in the development of novel biosensors for environmental and health monitoring and new highly efficient solar cells for energy conversion.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0775550
Funder
Australian Research Council
Funding Amount
$345,000.00
Summary
Characterisation Equipment for Advanced Gas Separation Applications. The proposed research will lead to the synthesis of new advanced materials capable of performing new and existing separations more efficiently than previous methods. We therefore expect the new materials to directly benefit the community through improved removal and recovery of a wide range of pollutants which would otherwise enter the environment. This research is directly aligned to the National Research Priority of Frontie ....Characterisation Equipment for Advanced Gas Separation Applications. The proposed research will lead to the synthesis of new advanced materials capable of performing new and existing separations more efficiently than previous methods. We therefore expect the new materials to directly benefit the community through improved removal and recovery of a wide range of pollutants which would otherwise enter the environment. This research is directly aligned to the National Research Priority of Frontier Technologies for Building and Transforming Australian Industries: Advanced Materials.Read moreRead less
Designer Surfactants for Creation of Emulsion Properties. We propose new approaches to the design of surfactants for stabilising water in oil emulsions. New block copolymer surfactants may be "tailored" for head group structure and a pre-chosen hydrophilic/lipophilic balance at the oil-water interface using the Australian developed RAFT polymer synthesis method and polymeric inorganic species. The proposers have an extensive background in these areas.
X-ray and neutron scattering techniques, de ....Designer Surfactants for Creation of Emulsion Properties. We propose new approaches to the design of surfactants for stabilising water in oil emulsions. New block copolymer surfactants may be "tailored" for head group structure and a pre-chosen hydrophilic/lipophilic balance at the oil-water interface using the Australian developed RAFT polymer synthesis method and polymeric inorganic species. The proposers have an extensive background in these areas.
X-ray and neutron scattering techniques, developed by us, allow the interfacial structure of the surfactant to be found and the intellectual "loop" closed in the design process. Preliminary screening will be done using the surface balance and bulk emulsion synthesis.Read moreRead less