Utilising nature's complexity - understanding fundamental organometallic binding modes of furans and coordination of bioderived furans. The earth's decreasing reserves of fossil fuels has prompted an intense push to utilise the renewable bioresources to replace the many products and fuels derived from petroleum. One of the promising developments is the production of so-called Furanics, useful molecules produced easily from carbohydrates found in waste materials from the sugar, corn and forestry ....Utilising nature's complexity - understanding fundamental organometallic binding modes of furans and coordination of bioderived furans. The earth's decreasing reserves of fossil fuels has prompted an intense push to utilise the renewable bioresources to replace the many products and fuels derived from petroleum. One of the promising developments is the production of so-called Furanics, useful molecules produced easily from carbohydrates found in waste materials from the sugar, corn and forestry industries. Given Australia's wealth of agricultural resources, discovering the full power of these potentially useful furanic compounds should be a major priority. This research aims to link Australia's biomass potential with the plastics, pharmaceutical, fine and agrichemical industries.Read moreRead less
Organometallic Transformations of Organic Compounds. The program will develop new metal-based catalysts for two main purposes (i) transforming basic hydrocarbons eg. natural gas and low-molecular-weight petroleum products into more advanced compounds (such as alcohols, alkenes and carboxylic acids); and (ii) converting nitrogen gas into nitrogen-containing compounds eg. ammonia or ammonia derivatives. In both projects, the aim is to take readily available and abundant starting materials that ar ....Organometallic Transformations of Organic Compounds. The program will develop new metal-based catalysts for two main purposes (i) transforming basic hydrocarbons eg. natural gas and low-molecular-weight petroleum products into more advanced compounds (such as alcohols, alkenes and carboxylic acids); and (ii) converting nitrogen gas into nitrogen-containing compounds eg. ammonia or ammonia derivatives. In both projects, the aim is to take readily available and abundant starting materials that are currently difficult to utilise and to design and develop specific reagents to convert them to "value-added" products. The program will also explore the mode of action of metal-based reagents leading to better reagent and catalyst design.Read moreRead less
High Oxidation State and Related Chemistry of Organic Compounds of Palladium. Palladium is able to form compounds containing palladium-carbon bonds, and compounds of this type occur in applications such as synthesis of organic compounds. The fundamental chemistry of this class of palladium compound is to be explored, in particular for the oxidation state +IV for palladium and with a focus on reactions that are relevant to processes occurring in organic synthesis applications. Particular emphas ....High Oxidation State and Related Chemistry of Organic Compounds of Palladium. Palladium is able to form compounds containing palladium-carbon bonds, and compounds of this type occur in applications such as synthesis of organic compounds. The fundamental chemistry of this class of palladium compound is to be explored, in particular for the oxidation state +IV for palladium and with a focus on reactions that are relevant to processes occurring in organic synthesis applications. Particular emphasis is placed on chemistry involving phosphorus compounds and unsaturated organic groups bonded to palladium, and on compounds containing groups that are able to join together to depart from palladium as organic compounds containing carbon-oxygen bonds.Read moreRead less
New Directions in Alkynylpalladium and Platinum Chemistry. Reactions involving palladium or platinum compounds with organic reagents are important for the synthesis of new materials and organic molecules, including pharmaceuticals. This research program will provide a better understanding of applications involving these metals, together with advances in fundamental chemistry of wide general interest at an international level, and high quality research training in an area essential for the conti ....New Directions in Alkynylpalladium and Platinum Chemistry. Reactions involving palladium or platinum compounds with organic reagents are important for the synthesis of new materials and organic molecules, including pharmaceuticals. This research program will provide a better understanding of applications involving these metals, together with advances in fundamental chemistry of wide general interest at an international level, and high quality research training in an area essential for the continued development of modern chemical and related industries in Australia.Read moreRead less
Resolving Critical Knowledge Gaps Relating to Light and Free-Radical Mediated Transformations of Iron and Copper in Oxic Natural Waters. Understanding the transformation kinetics of iron and copper species is critical to maintaining Australia's water resources since i) iron transformations are key to generation and transport of acid in Australia's coastal environment; ii) growth of toxic algae are stimulated by dissolution of iron-rich sediments with subsequent release of nutrients phosphorus an ....Resolving Critical Knowledge Gaps Relating to Light and Free-Radical Mediated Transformations of Iron and Copper in Oxic Natural Waters. Understanding the transformation kinetics of iron and copper species is critical to maintaining Australia's water resources since i) iron transformations are key to generation and transport of acid in Australia's coastal environment; ii) growth of toxic algae are stimulated by dissolution of iron-rich sediments with subsequent release of nutrients phosphorus and iron, and iii) algal toxicity is related to iron and copper nutrition and interplay of these metals with oxygen. Additionally, global cycles of carbon, phosphorus and nitrogen are influenced by iron and copper interactions with light and oxygen. Improved understanding of these processes should lead to an awareness of how to prevent these problems and, if they occur, approaches to their mitigation.Read moreRead less
Cyclophane Carbene Complexes as Catalysts: An Integrated Synthetic, Structural, and Mechanistic Approach. Metal-carbene complexes are emerging as efficient catalysts for chemical processes of immense importance to the pharmaceutical and fine chemicals industries. This project will build on the recent discovery of a family of complexes that exhibits the highest activity yet reported for metal-carbene catalysts in carbon-carbon bond-forming reactions. Insights into the ways the new catalysts work ....Cyclophane Carbene Complexes as Catalysts: An Integrated Synthetic, Structural, and Mechanistic Approach. Metal-carbene complexes are emerging as efficient catalysts for chemical processes of immense importance to the pharmaceutical and fine chemicals industries. This project will build on the recent discovery of a family of complexes that exhibits the highest activity yet reported for metal-carbene catalysts in carbon-carbon bond-forming reactions. Insights into the ways the new catalysts work will be gained through a combination of synthetic, mechanistic, and structural studies. This detailed investigation of structure/reactivity relationships will provide an understanding of why these catalyst are so efficient and hence give synthetic leads for the development of superior new catalysts suitable for industrial application.Read moreRead less
Organometallic Transformations of Organic Molecules. Simple hydrocarbons such as natural gas and petroleum are amongst the most abundant and readily available natural feedstocks for the organic chemical industry. However, apart from simply burning them for fuel, there are very few methods for using these materials as starting materials for industry. In chemical terms, simple hydrocarbons are very stable and this makes them difficult substances to convert cleanly to other more useful compounds. ....Organometallic Transformations of Organic Molecules. Simple hydrocarbons such as natural gas and petroleum are amongst the most abundant and readily available natural feedstocks for the organic chemical industry. However, apart from simply burning them for fuel, there are very few methods for using these materials as starting materials for industry. In chemical terms, simple hydrocarbons are very stable and this makes them difficult substances to convert cleanly to other more useful compounds. This research program investigates new approaches for converting hydrocarbons to more useful materials by using metals such as iron and ruthenium. This research program will provide a new route to ?value-added? products from hydrocarbons and develop new uses for these abundant raw materials.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE100100013
Funder
Australian Research Council
Funding Amount
$170,000.00
Summary
Eddy correlation lander array. The proposed Eddy Correlation Lander Array will be the first in world and, as such, will allow ground-breaking research to be undertaken resulting in advances in a variety of fields. As such, this equipment will significantly enhance many core research programs at Southern Cross University and Monash University and enhance our ability to deliver high quality research in the National Research Priority Area of An Environmentally Sustainable Australia, with priority g ....Eddy correlation lander array. The proposed Eddy Correlation Lander Array will be the first in world and, as such, will allow ground-breaking research to be undertaken resulting in advances in a variety of fields. As such, this equipment will significantly enhance many core research programs at Southern Cross University and Monash University and enhance our ability to deliver high quality research in the National Research Priority Area of An Environmentally Sustainable Australia, with priority goals in water resources, responding to climate change and variability, overcoming soil loss, salinity and acidity and sustainable use of Australia's biodiversity.Read moreRead less
A new route to linear alpha olefins - catalytic isomerisation of internal olefins. Linear alpha olefins are an extremely important class of chemical building blocks used for everyday consumer products, such as plastics, detergents and lubricants. This research aims to develop a new platform technology for the production of these materials from low cost precursors.
A radical approach to the design of components for molecular electronics. This project aims to develop highly conductive organometallic molecular wires for use in future molecular electronics technology. Metal complexes have immense potential as components in future electronic circuits, offering function on a size impossible to meet in conventional solid-state devices, and helping overcome limits in 'top-down' scaling. Whilst organic molecules that display electronic function are known, their pe ....A radical approach to the design of components for molecular electronics. This project aims to develop highly conductive organometallic molecular wires for use in future molecular electronics technology. Metal complexes have immense potential as components in future electronic circuits, offering function on a size impossible to meet in conventional solid-state devices, and helping overcome limits in 'top-down' scaling. Whilst organic molecules that display electronic function are known, their performance remains poor. Just as doping a semiconductor results in higher electrical conductance by placing additional electrons (holes) into the conduction (valence) band, this project will use transition metal organometallic complexes bearing radical ligands as innovative motifs in the design of novel molecular components.Read moreRead less