Diatom lipids to reveal sea-ice history in remote Antarctic regions. This project aims to understand seasonal Antarctic sea-ice extent using molecular, geochemical, elemental and genomic characteristics of specific marine phytoplankton (diatoms). Little is known of the seasonal sea-ice variation and the position of the summer sea-ice extent a million years before satellite records, but this information is critical to determining air-sea gas exchange and ecosystem food web regulation. This projec ....Diatom lipids to reveal sea-ice history in remote Antarctic regions. This project aims to understand seasonal Antarctic sea-ice extent using molecular, geochemical, elemental and genomic characteristics of specific marine phytoplankton (diatoms). Little is known of the seasonal sea-ice variation and the position of the summer sea-ice extent a million years before satellite records, but this information is critical to determining air-sea gas exchange and ecosystem food web regulation. This project will unite geochemical and biological approaches to provide the data to improve past Antarctic ecosystem and climate models where sea-ice data is missing. Studying diatom biomarkers in deep sea cores from Australia’s Southern Ocean will redefine knowledge of Antarctic climate and provide data necessary to improve global ecosystem and climate models.Read moreRead less
Fire and rain: Drivers of deep-time ecosystem assembly in Australia. This project aims to investigate the influence of bushfires and shifting rainfall patterns on the development of Australia’s dominant ecosystems. By combining a range of novel geochemical, isotopic and palaeontological techniques, this research seeks to reveal the causes and consequences of Australia’s transformation from a forested to mainly open landscape of grassland, shrubland and savannah. The expected outcome is detailed ....Fire and rain: Drivers of deep-time ecosystem assembly in Australia. This project aims to investigate the influence of bushfires and shifting rainfall patterns on the development of Australia’s dominant ecosystems. By combining a range of novel geochemical, isotopic and palaeontological techniques, this research seeks to reveal the causes and consequences of Australia’s transformation from a forested to mainly open landscape of grassland, shrubland and savannah. The expected outcome is detailed knowledge of how changes in fire and rain shaped the ecology and evolution of plants and animals. This knowledge is key to understanding how Australian ecosystems function and to protecting their cultural, economic and environmental values, especially as climate and fire regimes continue to change into the future.Read moreRead less
Gas Phase Studies to Catalyze a Better Understanding of Metal Reactivity. The proposed research will increase knowledge of fundamental questions related to the mechanisms of catalysis and metal ion reactivity. The insights gained will be an important addition to the knowledge base of our culture, both nationally and in the wider international context. We note that research into the behaviour and design of catalysts is a burgeoning field which reflects the great importance of this area in the int ....Gas Phase Studies to Catalyze a Better Understanding of Metal Reactivity. The proposed research will increase knowledge of fundamental questions related to the mechanisms of catalysis and metal ion reactivity. The insights gained will be an important addition to the knowledge base of our culture, both nationally and in the wider international context. We note that research into the behaviour and design of catalysts is a burgeoning field which reflects the great importance of this area in the international scientific community. Our proposal will add to fundamental knowledge and may also result in practical applications. More importantly, we will train and equip talented young people with a spectrum of skills which will make them well placed to meet the demand for highly skilled professional scientists.Read moreRead less
Source to spectrum: Finding deposits beyond the Fe oxide-Cu-Au envelope. Source to spectrum: Finding deposits beyond the Fe oxide-Cu-Au envelope. This project aims to improve exploration models for the spectrum of deposits at Olympic Dam. The giant Olympic Dam iron–oxide–copper–gold (IOCG) deposit in the Gawler Craton, discovered 40 years ago, has contributed billions of dollars to the economy. A fluid flow event in the Olympic Dam created a vast, crustal-scale alteration system with a spectrum ....Source to spectrum: Finding deposits beyond the Fe oxide-Cu-Au envelope. Source to spectrum: Finding deposits beyond the Fe oxide-Cu-Au envelope. This project aims to improve exploration models for the spectrum of deposits at Olympic Dam. The giant Olympic Dam iron–oxide–copper–gold (IOCG) deposit in the Gawler Craton, discovered 40 years ago, has contributed billions of dollars to the economy. A fluid flow event in the Olympic Dam created a vast, crustal-scale alteration system with a spectrum of different mineral deposits, many of which are under-explored. This project aims to constrain the source of metal and fluids in the Gawler Craton deposits, determine crustal fertility for deposit formation and develop metal specific 'prospectivity maps' to improve exploration efficiency.Read moreRead less
The geomicrobiology and (bio)geochemistry of platinum, palladium and rhodium. Few economic (Platinum) Pt, (Palladium) Pd or (Rhodium) Rh deposits are known in Australia despite an abundance of potential host rock. By improving onshore exploration techniques this project will ensure the supply of these strategic metals to the Australian economy. By integrating geochemical, molecular microbial and microanalyses (e.g., synchrotron) techniques this project will also: (i) enhance Australia's status i ....The geomicrobiology and (bio)geochemistry of platinum, palladium and rhodium. Few economic (Platinum) Pt, (Palladium) Pd or (Rhodium) Rh deposits are known in Australia despite an abundance of potential host rock. By improving onshore exploration techniques this project will ensure the supply of these strategic metals to the Australian economy. By integrating geochemical, molecular microbial and microanalyses (e.g., synchrotron) techniques this project will also: (i) enhance Australia's status in the breakthrough science of Geomicrobiology; (ii) secure a leading role for Australian science in the assessment of anthropogenic Pt, Pd and Rh pollution; (iii) access expertise developed overseas by fostering international collaborations; and (iv) explore the transformational capabilities of microbiota for ore-processing of and nano-particle production.Read moreRead less
Reverse engineering nature: metal extraction through mineral replacement. This project aims to find new methods of copper recovery from low grade copper ores, which are currently uneconomic to mine. In nature, at the top of ore deposits and just below the water-table, is a region known as the supergene zone. Here mild oxidizing reactions take place causing primary ore minerals such as chalcopyrite to be replaced by more copper-rich, less refractory minerals. These processes are driven by disso ....Reverse engineering nature: metal extraction through mineral replacement. This project aims to find new methods of copper recovery from low grade copper ores, which are currently uneconomic to mine. In nature, at the top of ore deposits and just below the water-table, is a region known as the supergene zone. Here mild oxidizing reactions take place causing primary ore minerals such as chalcopyrite to be replaced by more copper-rich, less refractory minerals. These processes are driven by dissolution re-precipitation reactions (CDR reactions) and in many CDR reactions, the reaction mechanism, rather than intensive properties such as pressure and temperature, control the nature of the products and the overall reaction process. This project will explore the mechanism and controls on these reactions to see if they can be utilized in the mining industry to economically extract copper from low grade ores.
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Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0989067
Funder
Australian Research Council
Funding Amount
$950,000.00
Summary
The future of palaeoclimate and archaeological research in Australia: next generation instrumentation for chronology and environmental reconstruction. The outcomes of this project will promote a better understanding of Australia's arid continent and its surrounding marine environment, contribute to studies of global climate change, and provide new insights into the response of fragile ecosystems to such events and processes. The project addresses directly the National Research Priority 'Water - ....The future of palaeoclimate and archaeological research in Australia: next generation instrumentation for chronology and environmental reconstruction. The outcomes of this project will promote a better understanding of Australia's arid continent and its surrounding marine environment, contribute to studies of global climate change, and provide new insights into the response of fragile ecosystems to such events and processes. The project addresses directly the National Research Priority 'Water - a critical resource', 'Responding to climate change and variability', 'Overcoming soil loss, salinity and acidity', 'Sustainable use of Australia's biodiversity' and 'Understanding our region and the world'. It provides a consortium-type platform for highly productive collaborative research and training across eight universities and one research organisation in Australia.Read moreRead less
Transport of metals in vapours and brines: new insights into the formation of the Earth's mineral deposits. Traditional models for the formation of hydrothermal ore deposits assume that aqueous fluids transported the metals. This view is challenged by new observations showing that gold and copper are preferentially enriched in vapours coexisting with salty aqueous fluids in some deposits. This project uses state-of-the-art techniques and develops new instruments to measure experimentally the par ....Transport of metals in vapours and brines: new insights into the formation of the Earth's mineral deposits. Traditional models for the formation of hydrothermal ore deposits assume that aqueous fluids transported the metals. This view is challenged by new observations showing that gold and copper are preferentially enriched in vapours coexisting with salty aqueous fluids in some deposits. This project uses state-of-the-art techniques and develops new instruments to measure experimentally the partitioning of metals between solid, fluid and vapour at temperatures typical for natural ore deposits (350-550C, pressures varying for vapour saturated to 1 kb). By improving our understanding of metal transport within the Earth's crust, these data will lead to improved models and technologies for exploring and processing base and precious metals.Read moreRead less
A new molecular platform for catalytic synthesis of heterocycles. This project aims to address the lack of efficient methods to prepare cyclic molecules of biological relevance by utilising novel molecular platforms developed in our laboratories. This project expects to generate new cyclic molecules using these innovative molecular platforms by employing catalysts to reduce raw material and energy cost. The expected outcomes of this project include enhanced chemical technology to prepare cyclic ....A new molecular platform for catalytic synthesis of heterocycles. This project aims to address the lack of efficient methods to prepare cyclic molecules of biological relevance by utilising novel molecular platforms developed in our laboratories. This project expects to generate new cyclic molecules using these innovative molecular platforms by employing catalysts to reduce raw material and energy cost. The expected outcomes of this project include enhanced chemical technology to prepare cyclic molecules of pharmaceutical importance and the training of highly skilled PhD students. This should provide significant benefits, such as increased capacity for the development of new pharmaceuticals and advanced materials.Read moreRead less
Gas Phase Reactivity of Charged Peptide and DNA Radicals: Fundamentals and Applications. Radicals derived from the "molecules of life", proteins and DNA, play both beneficial (e.g. enzyme catalysis) and deleterious roles (e.g. protein and DNA damage associated with disease). Two electrospray ionisation mass spectrometry approaches have been discovered to generate charged radicals of related models systems (e.g. peptides and nucleobases). The gas phase chemistry of these species is a largely unch ....Gas Phase Reactivity of Charged Peptide and DNA Radicals: Fundamentals and Applications. Radicals derived from the "molecules of life", proteins and DNA, play both beneficial (e.g. enzyme catalysis) and deleterious roles (e.g. protein and DNA damage associated with disease). Two electrospray ionisation mass spectrometry approaches have been discovered to generate charged radicals of related models systems (e.g. peptides and nucleobases). The gas phase chemistry of these species is a largely unchartered area! We will examine the fundamental chemistry (unimolecular and bimolecular reactions) of these systems and build upon some exciting preliminary results which suggest potential applications (e.g. as a proteomics tool to sequence and distinguish between leucine and isoleucine residues in peptides).Read moreRead less