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Aggregate structure of humic organic matter. Soil aquatic organic matter is important in plant growth, nutrient supply and water quality and in affecting pollutants and metal ions in the environment. Indeed the survival of life on the planet depends on the way geo-organic matter functions. We have recently developed a new host guest theory on the way this material binds important substances such as metal ions and pollutants. This project aims to use this theory to investigate the structure of th ....Aggregate structure of humic organic matter. Soil aquatic organic matter is important in plant growth, nutrient supply and water quality and in affecting pollutants and metal ions in the environment. Indeed the survival of life on the planet depends on the way geo-organic matter functions. We have recently developed a new host guest theory on the way this material binds important substances such as metal ions and pollutants. This project aims to use this theory to investigate the structure of these materials and how they work in Nature by understanding molecular composition at a level hitherto thought impossible.Read moreRead less
Host-guest structure of humic organic matter - the key to understanding soil organic properties. Soil and aquatic organic matter is important in plant growth, nutrient supply and water quality and in affecting pollutants and metal ions in the environment. Indeed, the survival of life on the planet depends on the way geo-organic matter functions. We have recently developed a new host?guest theory on the way this material binds important substances such as metal ions and pollutants. This proje ....Host-guest structure of humic organic matter - the key to understanding soil organic properties. Soil and aquatic organic matter is important in plant growth, nutrient supply and water quality and in affecting pollutants and metal ions in the environment. Indeed, the survival of life on the planet depends on the way geo-organic matter functions. We have recently developed a new host?guest theory on the way this material binds important substances such as metal ions and pollutants. This project aims to use this theory to investigate the structure of these materials and how they work in Nature by understanding molecular composition at a level hitherto thought impossible.Read moreRead less
Using chemistry to illuminate sulfoglycolysis, a major organosulfur pathway. This project aims to develop a detailed molecular description of the sulfoglycolysis pathway, a major pathway involved in cycling an abundant sulfolipid. The project will use an integrated chemical, biochemical and structural approach to illuminate how sulfoglycolysis degrades sulfolipid to access its elemental and energy constituents. Expected outcomes include an advanced understanding of the biosulfur cycle, the devel ....Using chemistry to illuminate sulfoglycolysis, a major organosulfur pathway. This project aims to develop a detailed molecular description of the sulfoglycolysis pathway, a major pathway involved in cycling an abundant sulfolipid. The project will use an integrated chemical, biochemical and structural approach to illuminate how sulfoglycolysis degrades sulfolipid to access its elemental and energy constituents. Expected outcomes include an advanced understanding of the biosulfur cycle, the development of new chemical approaches to manipulate sulfur cycling for agricultural and biotechnology applications, and deepened ties to leading international researchers. Potential benefits include new strategies to reduce dependence on agricultural fertilisers, promote gut wellbeing, and control insect pests.Read moreRead less
Connecting soil nitrogen and plant uptake for greener agriculture. This project will use synthetic organic chemistry, biochemistry, root and rhizosphere biology and rhizosphere modelling to establish detailed mechanistic knowledge of the nitrogen (N) transport and uptake processes at the soil-root interface to develop new, efficient urease and nitrification inhibitors for reliable provision of N to the plant/root system. The reduction of excessive N fertilisation has significant environmental be ....Connecting soil nitrogen and plant uptake for greener agriculture. This project will use synthetic organic chemistry, biochemistry, root and rhizosphere biology and rhizosphere modelling to establish detailed mechanistic knowledge of the nitrogen (N) transport and uptake processes at the soil-root interface to develop new, efficient urease and nitrification inhibitors for reliable provision of N to the plant/root system. The reduction of excessive N fertilisation has significant environmental benefits by reducing greenhouse gas emissions and water pollution. This project will lead to a breakthrough for the triple challenge of food security, environmental degradation and climate change, while improving plant productivity and increasing the profitability of agriculture through lower fertiliser costs.Read moreRead less
Australian clays as raw materials of slow-release phosphate fertiliser. Phosphorus (P) fertiliser input in Australia is a significant problem for its inefficient plant uptake, leaching to natural water bodies and stocking of insoluble P in soil. The project aims to develop activated clays using Australian raw clay minerals to formulate effective slow-release phosphate (P) fertilisers (SRF) and delivery material for P-solubilising bacteria. Composite of these will supply P controllably even amid ....Australian clays as raw materials of slow-release phosphate fertiliser. Phosphorus (P) fertiliser input in Australia is a significant problem for its inefficient plant uptake, leaching to natural water bodies and stocking of insoluble P in soil. The project aims to develop activated clays using Australian raw clay minerals to formulate effective slow-release phosphate (P) fertilisers (SRF) and delivery material for P-solubilising bacteria. Composite of these will supply P controllably even amid environmental fluctuations but when a plant needs as it grows. Development of multifunctional, nontoxic and plant growth-driven P fertiliser would benefit improve soil fertility in a sustainable way where efficiency of P input is maximised with a minimised environmental burden.Read moreRead less
Multi-Scale, Multi-Form Approach to the Modelling, Design and Control of Complex Particulate Processes. Many particulate processes suffer from high recycle rates and instability due to lack of knowledge at various scale levels, and on the fitness between model forms and applications. This project will develop a complete model hierarchy ranging from the microscopic scale to full plant scale using a multi-scale, multi-form approach. The joint force of two world class teams will tackle the complex ....Multi-Scale, Multi-Form Approach to the Modelling, Design and Control of Complex Particulate Processes. Many particulate processes suffer from high recycle rates and instability due to lack of knowledge at various scale levels, and on the fitness between model forms and applications. This project will develop a complete model hierarchy ranging from the microscopic scale to full plant scale using a multi-scale, multi-form approach. The joint force of two world class teams will tackle the complex interaction problems covering granulation fundamentals, dynamic modelling, process design and advanced control. The work will lead to significantly improved productivity and quality for a wide range of industrial particulate processes using innovative design and model based control strategies.Read moreRead less
Engineered graphene-based nanofertilizers to improve crop nutrition. This project seeks to evaluate the unique properties of graphene to more effectively engineer novel fertilizers with properties that can enhance nutrient efficiency and reduce losses to the environment. More efficient and effective fertilizer formulations are needed to improve nutrient use efficiency in agricultural systems globally, and for effective biofortification of staple food crops with essential micronutrients. Nitrogen ....Engineered graphene-based nanofertilizers to improve crop nutrition. This project seeks to evaluate the unique properties of graphene to more effectively engineer novel fertilizers with properties that can enhance nutrient efficiency and reduce losses to the environment. More efficient and effective fertilizer formulations are needed to improve nutrient use efficiency in agricultural systems globally, and for effective biofortification of staple food crops with essential micronutrients. Nitrogen may be lost from soil through leaching and gaseous losses to the atmosphere. Phosphorus, as well as copper, manganese and zinc, are prone to reactions in soils and during manufacturing which reduces their effectiveness.Read moreRead less
Plasma driven electrochemical synthesis of urea. Urea is the most used nitrogen fertilizer in the world, with more urea manufactured by mass than any other organic chemical. However, the world is experiencing a major shortage of the compound, impacting our food costs and security along with dependent products such as AdBlue (diesel exhaust fluid). Commercial urea production relies on a complex reaction between ammonia and carbon dioxide at high temperatures, which consumes more than 2% of the w ....Plasma driven electrochemical synthesis of urea. Urea is the most used nitrogen fertilizer in the world, with more urea manufactured by mass than any other organic chemical. However, the world is experiencing a major shortage of the compound, impacting our food costs and security along with dependent products such as AdBlue (diesel exhaust fluid). Commercial urea production relies on a complex reaction between ammonia and carbon dioxide at high temperatures, which consumes more than 2% of the world’s energy. This project aims to produce more sustainable urea driven by electricity and using air and captured CO2, through the use of a plasma-driven electrochemical technology, providing farmers with a low-cost fertilizer under a decentralized and secure supply. Read moreRead less
New Horizons in Diels-Alder Chemistry. Using a unique joint experimental-computational approach, we will develop reliable ways to predict the outcome of one of the most important chemical reactions. Practical applications of these new predictive tools will be developed involving powerful new versions of the reaction. Several different classes of biologically active natural products will be prepared including molecules with antitumor and antiretroviral activities. Libraries of structurally-relate ....New Horizons in Diels-Alder Chemistry. Using a unique joint experimental-computational approach, we will develop reliable ways to predict the outcome of one of the most important chemical reactions. Practical applications of these new predictive tools will be developed involving powerful new versions of the reaction. Several different classes of biologically active natural products will be prepared including molecules with antitumor and antiretroviral activities. Libraries of structurally-related analogues of natural compounds will be synthesised for biological evaluation.Read moreRead less
Experimental and Computational Investigations into Enantioselective Domino Sequences. This research program aims to develop more efficient methods for the chemical synthesis of organic substances: the materials that make up all known life forms, our medicines, and many designed materials. This research involves primarily the invention of new, enabling science. Specifically, we are trying to develop new and very general strategies to make organic compounds selectively and more efficiently than be ....Experimental and Computational Investigations into Enantioselective Domino Sequences. This research program aims to develop more efficient methods for the chemical synthesis of organic substances: the materials that make up all known life forms, our medicines, and many designed materials. This research involves primarily the invention of new, enabling science. Specifically, we are trying to develop new and very general strategies to make organic compounds selectively and more efficiently than before. A more efficient chemical synthesis means less waste, lower energy consumption and less environmental impact. Research of this kind is absolutely essential for the development of new medicines and materials. Australia lags behind many of the world's developed countries in this very important area of endeavour.Read moreRead less