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Reversible Addition Fragmentation Chain Transfer (RAFT) Free Radical Copolymerizations of Various Monomers. The proposed project will investigate the structure and properties of statistical copolymers prepared via living free radical polymerization. We will study the characteristics of a wide variety of Reversible Addition Fragmentation Chain Transfer (RAFT) copolymerizations using a range of monomers, including those interesting for biomedical and material science applications. We expect to gai ....Reversible Addition Fragmentation Chain Transfer (RAFT) Free Radical Copolymerizations of Various Monomers. The proposed project will investigate the structure and properties of statistical copolymers prepared via living free radical polymerization. We will study the characteristics of a wide variety of Reversible Addition Fragmentation Chain Transfer (RAFT) copolymerizations using a range of monomers, including those interesting for biomedical and material science applications. We expect to gain a deeper understanding of the influence of the RAFT process on the kinetics and mechanism of copolymerization and the properties of the resulting polymers in order to tailor specific polymer materials for biomedial applications.Read moreRead less
Branching in acrylic polymers: analysis and mechanistic understanding. Some polymers can be branched. This branching has major effects on the end-product performance of a polymer, for example in adhesives and the flexibility of rubbery materials. Full quantification of this branching (the lengths of branches and the rates of the processes that create them) has been impossible hitherto. Two new complementary techniques, a new analytical method developed by the applicant Fellow in Paris, and a new ....Branching in acrylic polymers: analysis and mechanistic understanding. Some polymers can be branched. This branching has major effects on the end-product performance of a polymer, for example in adhesives and the flexibility of rubbery materials. Full quantification of this branching (the lengths of branches and the rates of the processes that create them) has been impossible hitherto. Two new complementary techniques, a new analytical method developed by the applicant Fellow in Paris, and a new synthesis technique developed in Sydney, will be used as the platforms to devise the first means of determining this information and thus understanding and quantifying branching.Read moreRead less
Cross-linking in free-radical polymerizations: kinetics and mechanical properties. Cross-linked polymer chains are joined together in a ?ladder? topology. This often occurs either deliberately or accidentally in industrial systems, and affects polymer properties. However, cross-linking mechanisms are poorly understood, and there are no general means of quantitatively controlling effects on mechanical properties. As a by-product from a previous IREX grant, a means was found to grow polymers with ....Cross-linking in free-radical polymerizations: kinetics and mechanical properties. Cross-linked polymer chains are joined together in a ?ladder? topology. This often occurs either deliberately or accidentally in industrial systems, and affects polymer properties. However, cross-linking mechanisms are poorly understood, and there are no general means of quantitatively controlling effects on mechanical properties. As a by-product from a previous IREX grant, a means was found to grow polymers with controlled cross-linking. This proposal exploits this method to synthesize polymers with different amounts of cross-linking, and to examine their formation mechanisms and mechanical properties. This has the potential of improving means of making rubber-based materials by polymer modification.Read moreRead less
Cumulenes and Heterocumulenes - Stellar Molecules and New Materials. This project involves the formation and characterisation of transient neutrals (formed in the mass spectrometer by neutralisation of charged precursor ions) which are either found in stellar dust clouds, or related molecules which may be either potential stellar molecules or have importance in the development of new materials. This work may lead to a better understanding of how biomolecules are formed in interstellar environs. ....Cumulenes and Heterocumulenes - Stellar Molecules and New Materials. This project involves the formation and characterisation of transient neutrals (formed in the mass spectrometer by neutralisation of charged precursor ions) which are either found in stellar dust clouds, or related molecules which may be either potential stellar molecules or have importance in the development of new materials. This work may lead to a better understanding of how biomolecules are formed in interstellar environs. The Adelaide and Berlin groups are internationally known, already with ongoing collaboration. This application seeks to extend the scope of this world-class research, and to train the premier graduate students in astrochemistry.Read moreRead less
Genealogy and Topology: A Constellational Comparison of Nietzsche and Heidegger. This research is fundamental in character addressing basic questions about the nature and history of philosophy. It will have direct academic benefits in advancing disciplinary knowledge, in enhancing the reputation of Australian philosophy in Germany and internationally, and in promoting contact between Australian and German philosophers, but is also likely to have longer term benefits in furthering our understandi ....Genealogy and Topology: A Constellational Comparison of Nietzsche and Heidegger. This research is fundamental in character addressing basic questions about the nature and history of philosophy. It will have direct academic benefits in advancing disciplinary knowledge, in enhancing the reputation of Australian philosophy in Germany and internationally, and in promoting contact between Australian and German philosophers, but is also likely to have longer term benefits in furthering our understanding of the nature of concepts, and of conceptual creativity.Read moreRead less
Development of Novel Detergents for Green Solvent Systems and Their Self-Assembly into Nanostructures. Successful outcomes from this collaborative project will lead to the development of new commercially viable green solvent systems for the chemical industry, e.g. dry cleaning. This has the potential to impact the community on the economic and environmental level, by significantly reducing the costs of current green solvent systems, resulting in greater likelihood of conventional toxic solvent ....Development of Novel Detergents for Green Solvent Systems and Their Self-Assembly into Nanostructures. Successful outcomes from this collaborative project will lead to the development of new commercially viable green solvent systems for the chemical industry, e.g. dry cleaning. This has the potential to impact the community on the economic and environmental level, by significantly reducing the costs of current green solvent systems, resulting in greater likelihood of conventional toxic solvents being replaced. The project will also expand the training of junior and early career scientists by allowing them to work in overseas laboratories.Read moreRead less
Polymer nanoobjects functionalized by polymer brushes: preparation, organization and integration in devices. The proposed project targets the collaboration between two leading research teams. The University of Marburg is leading in the area of the preparation of nanoobjects, while the research team at CAMD (UNSW) focuses on the preparation of well-controlled polymer structures via RAFT polymerisation. The combined strength of both groups seeks to improve the properties of nanodevices by the atta ....Polymer nanoobjects functionalized by polymer brushes: preparation, organization and integration in devices. The proposed project targets the collaboration between two leading research teams. The University of Marburg is leading in the area of the preparation of nanoobjects, while the research team at CAMD (UNSW) focuses on the preparation of well-controlled polymer structures via RAFT polymerisation. The combined strength of both groups seeks to improve the properties of nanodevices by the attachment of well-defined polymer layers. We expect therefore an optimum scientific output with both groups focusing on their research potency next to being able to access new knowledge. The visit to the German research group enables the Australian researchers access to a leading team in nanotechnology.Read moreRead less
Living Free Radical Polymerization for Nano Technology Applications. The proposed linkage project centres on a series of core projects from both the Australian and German collaborators. These core projects range from the synthesis of multifunctional nano- and micro-sphere particles, block copolymer systems used as efficient vehicles for drug delivery purposes to polymer brushes for nano-wires. The collaborating teams will carry out joint research tasks in the above mentioned fields via the excha ....Living Free Radical Polymerization for Nano Technology Applications. The proposed linkage project centres on a series of core projects from both the Australian and German collaborators. These core projects range from the synthesis of multifunctional nano- and micro-sphere particles, block copolymer systems used as efficient vehicles for drug delivery purposes to polymer brushes for nano-wires. The collaborating teams will carry out joint research tasks in the above mentioned fields via the exchange of the CIs and PhD students. The project is planned for a duration of three years to ensure an in-depth approach to the proposed projects.Read moreRead less
Conformationally constrained and immobilized beta-peptides. The research builds on world-class expertise in Australia (particularly Adelaide) in proteomics to provide a basis for fundamental advances in chemistry that will underpin the development of new pharmaceuticals and smart materials, and future technologies and industries. We create a mix of research at the interface of disciplines within academia and industry, with linkages to the very best international researchers and centres. A new cr ....Conformationally constrained and immobilized beta-peptides. The research builds on world-class expertise in Australia (particularly Adelaide) in proteomics to provide a basis for fundamental advances in chemistry that will underpin the development of new pharmaceuticals and smart materials, and future technologies and industries. We create a mix of research at the interface of disciplines within academia and industry, with linkages to the very best international researchers and centres. A new critical mass of expertise in a number of advancing areas of chemistry, biology, and materials science will be introduced to Australia. This will enhance existing strengths and opportunities in proteomics and biomedical research for the treatment of disease.Read moreRead less
Expressive power and complexity of temporal logics for model-checking. Hardware verification based upon mathematical logic is now routinely
used in industry to verify the correctness of large digital circuits
using a technique called model-checking. Such discrete systems move
from one state to another according to the regular ticks of a clock.
The challenge now is to find tractable methods for reasoning about
real-time systems and hybrid systems that move in a continuous manner
with respec ....Expressive power and complexity of temporal logics for model-checking. Hardware verification based upon mathematical logic is now routinely
used in industry to verify the correctness of large digital circuits
using a technique called model-checking. Such discrete systems move
from one state to another according to the regular ticks of a clock.
The challenge now is to find tractable methods for reasoning about
real-time systems and hybrid systems that move in a continuous manner
with respect to time: examples include aeroplanes flying according to
the laws of physics and a moving robot arm. We shall invent new logics
which are specifically tailored for tractable reasoning about
real-time and hybrid systems.Read moreRead less