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Transformer 3D Nanostructures: Stimuli Responsive Polymers. This research program will develop smart nanostructures that will be capable of producing high value added products using cheap polymer materials but achieving a much greater design capacity for end-use functions. The knowledge gained from this project will have potential applications in many areas where nanomaterials and polymers are used, including high strength coatings, conducting coatings for the electronic industry, drug and vacci ....Transformer 3D Nanostructures: Stimuli Responsive Polymers. This research program will develop smart nanostructures that will be capable of producing high value added products using cheap polymer materials but achieving a much greater design capacity for end-use functions. The knowledge gained from this project will have potential applications in many areas where nanomaterials and polymers are used, including high strength coatings, conducting coatings for the electronic industry, drug and vaccine delivery devices, tissue scaffolds, nanosensors, and gene delivery. These polymer techniques will enable Australian Industry to significantly improve product performance by providing advanced features and capabilities previously unavailable.Read moreRead less
Innovations in Green Chemical Manufacture from Synchrotron based Techniques. This project aims to find sustainable ways to produce commodity chemicals by developing new catalysts. New synchrotron techniques will be developed and applied to provide new knowledge about the spatial and temporal factors affecting the selectivity and efficiency of electron transfer, redox reactions and diffusion, key for catalyst design. Expected outcomes include the development of new catalysts, new catalyst design ....Innovations in Green Chemical Manufacture from Synchrotron based Techniques. This project aims to find sustainable ways to produce commodity chemicals by developing new catalysts. New synchrotron techniques will be developed and applied to provide new knowledge about the spatial and temporal factors affecting the selectivity and efficiency of electron transfer, redox reactions and diffusion, key for catalyst design. Expected outcomes include the development of new catalysts, new catalyst design concepts and a knowledge repository/database of analytical observations key for unlocking new materials knowledge. This should provide significant economic and environmental benefits by placing Australia at the forefront of the sustainable production of commodity chemicals.Read moreRead less
Solar-Driven C-H Functionalization Reactions. This project aims to investigate the functionalization reaction of unreactive C-H bonds using light as the source of energy. Light is a transformative change to synthesis as thermal activation is exchanged to solar activation. The latter gives access to excited state chemistry and enables reaction steps that are thermally inaccessible. It is a key strategy to leverage synthesis to the demands of the 21st century and to minimise its ecologic footprint ....Solar-Driven C-H Functionalization Reactions. This project aims to investigate the functionalization reaction of unreactive C-H bonds using light as the source of energy. Light is a transformative change to synthesis as thermal activation is exchanged to solar activation. The latter gives access to excited state chemistry and enables reaction steps that are thermally inaccessible. It is a key strategy to leverage synthesis to the demands of the 21st century and to minimise its ecologic footprint. At the same time this strategy provides a lever to profoundly impact and drive new concepts in synthesis. Significant benefits are expected, such as increase in fundamental knowledge on photochemical processes, but also the access to new materials for applications as drugs or OLEDs.Read moreRead less
Plasmonic nanoparticle catalysis for nitrogen-based synthesis. Light can generate an optical force to capture small objects. This requires intense light – a laser, which limits optical trapping in catalysis applications. This project aims to apply plasmonic nanoparticles with normal-intensity light to take advantage of plasmonic-generated optical forces for catalytic chemical synthesis. The optical trapping/releasing of small molecules is highly selective and responsive to molecule structure and ....Plasmonic nanoparticle catalysis for nitrogen-based synthesis. Light can generate an optical force to capture small objects. This requires intense light – a laser, which limits optical trapping in catalysis applications. This project aims to apply plasmonic nanoparticles with normal-intensity light to take advantage of plasmonic-generated optical forces for catalytic chemical synthesis. The optical trapping/releasing of small molecules is highly selective and responsive to molecule structure and so presents a great opportunity to radically alter chemical synthesis pathways, which will be illustrated with reactions on liquid-solid and gas-solid interfaces. This highly innovative strategy will be used to discover new nitrogen-based syntheses which are both fundamentally and industrially important.Read moreRead less
Open framework organic materials for CO2 capture and conversion. The reduction of CO2 emissions from coal-fired power plants is a technological challenge of global significance. This project will address this challenge by developing a unique system, based upon open framework materials, that will selectively capture CO2 from gas streams and then catalyse its transformation into industrially useful chemicals.
Light driven degradation of persistent organic pollutants. This project aims to address the accumulation of pollutants in our environment by developing and optimising materials that utilise light energy to breakdown these persistent chemicals. Combining novel techniques and approaches, this project expects to generate new knowledge in the field of materials science and photochemistry. The anticipated outcomes of this project include an advancement of environmental remediation methods and the cap ....Light driven degradation of persistent organic pollutants. This project aims to address the accumulation of pollutants in our environment by developing and optimising materials that utilise light energy to breakdown these persistent chemicals. Combining novel techniques and approaches, this project expects to generate new knowledge in the field of materials science and photochemistry. The anticipated outcomes of this project include an advancement of environmental remediation methods and the capture of pollutants at their source. This should provide significant benefits to both humans and the environment through preventing the adverse impacts of pollutant exposure.Read moreRead less
Computer-Aided Design of High-Performance Photocatalysts for Solar Hydrogen Production Based on Red Titanium Dioxide. Large-scale generation of energy by solar conversion is critical for future sustainability. This project aims to develop high performance materials to efficiently convert solar energy to hydrogen - a clean fuel. Starting from the newly developed material red titanium dioxide, novel strategies for improved photocatalytic materials will be proposed and evaluated by advanced computa ....Computer-Aided Design of High-Performance Photocatalysts for Solar Hydrogen Production Based on Red Titanium Dioxide. Large-scale generation of energy by solar conversion is critical for future sustainability. This project aims to develop high performance materials to efficiently convert solar energy to hydrogen - a clean fuel. Starting from the newly developed material red titanium dioxide, novel strategies for improved photocatalytic materials will be proposed and evaluated by advanced computational approaches. Key issues for solar-to-hydrogen conversion will be clarified. The materials, knowledge and strategies achieved by this project will dramatically enhance current solar technology and in particular will advance the development of low-cost hydrogen production from water. Read moreRead less
Engineered redox polymers for catalytic water purification. This project aims to develop a novel family of chemically and structurally controlled redox polymer as metal-free catalysts for wastewater micropollutant treatment. Innovations lie in the synthesis of high-performance and nanostructured carbon-based materials, multiscale modeling, and in situ characterizations for understanding structure-property relationship in carbon catalysis. Expected outcomes will deliver innovations in functional ....Engineered redox polymers for catalytic water purification. This project aims to develop a novel family of chemically and structurally controlled redox polymer as metal-free catalysts for wastewater micropollutant treatment. Innovations lie in the synthesis of high-performance and nanostructured carbon-based materials, multiscale modeling, and in situ characterizations for understanding structure-property relationship in carbon catalysis. Expected outcomes will deliver innovations in functional materials, mechanism, catalytic engineering, and sustainable separation processes. This project will provide significant benefits in renovating smart nanomaterials in advanced manufacturing and clean environmental technologies, promoting Australia’s economic development and environment protection.Read moreRead less
Sequence-defined polymers and green chemistry. This project aims to synthesise polymers that have precise chemical structure and mimic the biological activities of natural biopolymers like peptides and proteins. Monomer sequence regulation in these natural biopolymers is important in biology and necessary for crucial features of life, such as molecular recognition, self-replication and catalysis. Current artificial techniques for biopolymer synthesis are time consuming and present low yields at ....Sequence-defined polymers and green chemistry. This project aims to synthesise polymers that have precise chemical structure and mimic the biological activities of natural biopolymers like peptides and proteins. Monomer sequence regulation in these natural biopolymers is important in biology and necessary for crucial features of life, such as molecular recognition, self-replication and catalysis. Current artificial techniques for biopolymer synthesis are time consuming and present low yields at high costs. This project expects its new materials will increase manufacturing sustainability, chemical diversity and industrial viability; produce health benefits for Australia by improving chemotherapy and diagnosis for diseases; and benefit the Australian economy.Read moreRead less
High productivity of hybrid plasma electrocatalytic fertiliser production. Non-thermal plasma-driven electrocatalytic production of nitrogen fertilisers. The project aims to develop scalable technology for ambient production of fertilisers using renewable energy, air, water, and captured CO2. This project is anticipated to generate new knowledge in plasma catalysis and electrochemical coupling through designing and fine-tuning catalyst-loaded 3D scaffolds. Expected outcomes of this project inclu ....High productivity of hybrid plasma electrocatalytic fertiliser production. Non-thermal plasma-driven electrocatalytic production of nitrogen fertilisers. The project aims to develop scalable technology for ambient production of fertilisers using renewable energy, air, water, and captured CO2. This project is anticipated to generate new knowledge in plasma catalysis and electrochemical coupling through designing and fine-tuning catalyst-loaded 3D scaffolds. Expected outcomes of this project include increasing the capacity to adopt low-cost and decentralised methods for renewable energy utilisation. This should provide substantial technological capacity that can be applied to other sectors of Australia's developing hydrogen economy and expand the use of renewable energy Power-to-X for zero-emissions energy vectors.Read moreRead less