Discovery Early Career Researcher Award - Grant ID: DE230100978
Funder
Australian Research Council
Funding Amount
$406,818.00
Summary
A new Iron Age! Making Iron complexes fit for C-C cross-coupling catalysis. This project aims to develop new iron catalysts as alternatives to the expensive and increasingly rare noble metals currently used in C-C bond forming reactions, the most important single-step in the fine-chemicals sector.
This project expects to create a flexible yet robust framework by introducing a hemilabile ligand into the backbone of the iron complex to control the number of vacant coordination sites.
Expected outc ....A new Iron Age! Making Iron complexes fit for C-C cross-coupling catalysis. This project aims to develop new iron catalysts as alternatives to the expensive and increasingly rare noble metals currently used in C-C bond forming reactions, the most important single-step in the fine-chemicals sector.
This project expects to create a flexible yet robust framework by introducing a hemilabile ligand into the backbone of the iron complex to control the number of vacant coordination sites.
Expected outcomes of this project are 1) iron complexes able to catalyse biaryl couplings from sustainable substrates and 2) knowledge on structure-property relationships of iron-based catalytic processes.
Australia will benefit by applying its own resources and help preserving the valuable noble metals for processes relying on them.Read moreRead less
Redesigning Landcare policy to better coordinate across landholders. This project aims to study how landscape-sensitive economic incentives and social norms can be leveraged to enhance the short- and long-term effectiveness of conservation programs. It will yield new knowledge for innovative designs in conservation contracting that is urgently needed to address worsening environmental threats in Australia and worldwide. In collaboration with Nobel laureate Vernon Smith’s team, new methods and pr ....Redesigning Landcare policy to better coordinate across landholders. This project aims to study how landscape-sensitive economic incentives and social norms can be leveraged to enhance the short- and long-term effectiveness of conservation programs. It will yield new knowledge for innovative designs in conservation contracting that is urgently needed to address worsening environmental threats in Australia and worldwide. In collaboration with Nobel laureate Vernon Smith’s team, new methods and protocols will improve our ability to generate better data and better understand how social and incentive mechanisms can constructively interact to facilitate collaborative environmental action. Results will help make the achievement of environmental targets and the use of public funds more cost-effective. Read moreRead less
Three-dimensional solar-energy-driven hydrogen generation from ammonia. This project aims to address the challenges of hydrogen generation, transportation and storage by conceptualising a novel three-dimensional, solar-driven system for ammonia splitting on ultralight catalyst materials. The project expects to generate new knowledge in the area of advanced materials enabled hydrogen technologies through interdisciplinary approaches involving materials science, novel catalysis, and nanotechnology ....Three-dimensional solar-energy-driven hydrogen generation from ammonia. This project aims to address the challenges of hydrogen generation, transportation and storage by conceptualising a novel three-dimensional, solar-driven system for ammonia splitting on ultralight catalyst materials. The project expects to generate new knowledge in the area of advanced materials enabled hydrogen technologies through interdisciplinary approaches involving materials science, novel catalysis, and nanotechnology. Expected outcomes include new catalyst materials, design strategies, and advanced ammonia splitting technologies. This should provide significant benefits, such as newly created knowledge, technological innovation, research training, contributing to hydrogen economy and net zero for a greener environment.Read moreRead less
Mechanisms of Ammonia (NH3) Combustion and Nitrogen Oxides (NOx) Formation. A mature commodity that can be readily made from renewable resources, ammonia (NH3) offers an environmentally sustainable and low-cost means of transition from fossil fuels to a clean, low-carbon and renewable energy future. The technical challenge is to combust NH3 efficiently with low nitrogen oxides (NOx) emissions. This project will advance the science of NH3 combustion and NOx formation. By applying innovative fixed ....Mechanisms of Ammonia (NH3) Combustion and Nitrogen Oxides (NOx) Formation. A mature commodity that can be readily made from renewable resources, ammonia (NH3) offers an environmentally sustainable and low-cost means of transition from fossil fuels to a clean, low-carbon and renewable energy future. The technical challenge is to combust NH3 efficiently with low nitrogen oxides (NOx) emissions. This project will advance the science of NH3 combustion and NOx formation. By applying innovative fixed-bed and fluidised-bed reactor techniques and kinetic modelling, the research will unravel fundamental characteristics and mechanisms of NH3 combustion, NOx formation and in-situ destruction that underpin the development and deployment of practical combustion systems for power generation using NH3 as a carbon-free fuel.Read moreRead less
ARC Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide. ARC Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide. This Centre aims to advance carbon dioxide electrochemistry innovations to enable the conversion of carbon dioxide into valuable products and transition Australia to a carbon-neutral economy. This Centre expects to generate new knowledge using experimental and computational approaches to develop systems-level understanding to fu ....ARC Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide. ARC Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide. This Centre aims to advance carbon dioxide electrochemistry innovations to enable the conversion of carbon dioxide into valuable products and transition Australia to a carbon-neutral economy. This Centre expects to generate new knowledge using experimental and computational approaches to develop systems-level understanding to furnish industry-ready carbon dioxide utilisation technologies. Expected outcomes include enhanced capacity through collaborations establishing the Centre as an international hub for research, training, technology translation and strategic advice for stakeholders and policymakers. This should accelerate Australia’s progress towards net zero emissions targets and grow a sustainable economy and create future jobs.Read moreRead less
Carbon-Supported Iron Catalysts for Selective Catalytic Reduction of NO. Nitric oxide (NO) is a major pollutant from combustion systems. This project aims to develop cost-effective and environmentally benign zerovalent iron catalysts supported on carbon material for selective catalytic reduction (SCR) of NO using CO and unburned hydrocarbons as in-situ reductants. By applying differential reactor experimentation, kinetic modelling and advanced material characterisation techniques, the research w ....Carbon-Supported Iron Catalysts for Selective Catalytic Reduction of NO. Nitric oxide (NO) is a major pollutant from combustion systems. This project aims to develop cost-effective and environmentally benign zerovalent iron catalysts supported on carbon material for selective catalytic reduction (SCR) of NO using CO and unburned hydrocarbons as in-situ reductants. By applying differential reactor experimentation, kinetic modelling and advanced material characterisation techniques, the research will unravel complex relationships among catalyst structural features and activity, NO reduction mechanisms, and catalyst performance under practically relevant combustion conditions that underpin the development of an effective yet affordable SCR technology to control NO emission from industrial utilities and automobiles.Read moreRead less