Polymers for Novel Surfactants. The aim of the proposed research is to develop novel surface-active polymers with complex architectures and more efficient strategies for the synthesis of surface-active polymers in general. We will exploit the polymerization characteristics of the novel catalytic chain transfer and radical addition-fragmentation transfer polymerization techniques to achieve polymerization control that has been virtually impossible hitherto. The proposed research will thus make ....Polymers for Novel Surfactants. The aim of the proposed research is to develop novel surface-active polymers with complex architectures and more efficient strategies for the synthesis of surface-active polymers in general. We will exploit the polymerization characteristics of the novel catalytic chain transfer and radical addition-fragmentation transfer polymerization techniques to achieve polymerization control that has been virtually impossible hitherto. The proposed research will thus make accessible a wide range of novel surface-active polymers that have been impossible to synthesise to date, and which we expect to be more efficient and hence leads to greener technologies.
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Novel Complex Architecture Polymers via a Combination of RAFT Chemistry and Pericyclic Reactions: Synthesis and Characterization. The project aims at advancing the synthetic limits and broadening the synthetic scope of living free radical polymerization and thus enhancing the library of polymer structures available for applications ranging from drug delivery to opto-electronics. Current material design for these applications is yet to reach its full potential through innovative synthetic approac ....Novel Complex Architecture Polymers via a Combination of RAFT Chemistry and Pericyclic Reactions: Synthesis and Characterization. The project aims at advancing the synthetic limits and broadening the synthetic scope of living free radical polymerization and thus enhancing the library of polymer structures available for applications ranging from drug delivery to opto-electronics. Current material design for these applications is yet to reach its full potential through innovative synthetic approaches. The proposal critically underpins and further advances Australia's leading position in both breakthrough science as well as advanced materials. Due to its significant scientific breadth and large coverage of both synthetic and physical aspects of polymer science, the project also provides a significant platform for research training at both honours and PhD level.Read moreRead less
Establishing In-Depth Understanding of Molecular Degradation Processes in Acrylic Based Polymer Coil-Coatings for Domestic Roofing Applications. The national benefit is multipronged: (i) BlueScope Steel will maintain its technology leadership through continued innovation by taking advantage of the scientific insights that the project delivers for the introduction of next generation long lasting coil coatings for steel, based on an environmentally friendly production processes. (ii) The applicati ....Establishing In-Depth Understanding of Molecular Degradation Processes in Acrylic Based Polymer Coil-Coatings for Domestic Roofing Applications. The national benefit is multipronged: (i) BlueScope Steel will maintain its technology leadership through continued innovation by taking advantage of the scientific insights that the project delivers for the introduction of next generation long lasting coil coatings for steel, based on an environmentally friendly production processes. (ii) The application of mass spectrometry for the analysis of polymer degradation has been pioneered by the CI and BlueScope Steel. The project will demonstrate the power of this technique and secure Australia's place at the forefront of molecular polymer degradation research. (iii) The project has a strong educational component, training a PhD student at the interface of application and fundamental research.Read moreRead less
Fundamentals of the Performance Chemistry of Water-borne Acrylic Polymer based Surface Coatings for Pre-painted Steel Employed in Domestic Roofing Applications. The proposed project will systematically investigate the structure-performance relationships of acrylic emulsion based surface coatings and provide a detailed understanding of their degradation mechanisms. The improved understanding of these coatings will lead to the development of an optimum coating for steel roofs with extremely high d ....Fundamentals of the Performance Chemistry of Water-borne Acrylic Polymer based Surface Coatings for Pre-painted Steel Employed in Domestic Roofing Applications. The proposed project will systematically investigate the structure-performance relationships of acrylic emulsion based surface coatings and provide a detailed understanding of their degradation mechanisms. The improved understanding of these coatings will lead to the development of an optimum coating for steel roofs with extremely high durability and resistance against degradation and gloss loss in typical tropical and sub-tropical Australian climates.Read moreRead less
Nanoparticles with designed morphology for surface-coating applications. Significantly improved water-based paints, with zero volatile organic content and organic opacifiers, are highly desirable for environmental and health reasons. The science needed to produce such paints has been persistently elusive. USyd and Dulux will collaborate to achieve these paints by using Australian-developed platform technologies that allow polymer architecture to be controlled at molecular and nanoscale levels. T ....Nanoparticles with designed morphology for surface-coating applications. Significantly improved water-based paints, with zero volatile organic content and organic opacifiers, are highly desirable for environmental and health reasons. The science needed to produce such paints has been persistently elusive. USyd and Dulux will collaborate to achieve these paints by using Australian-developed platform technologies that allow polymer architecture to be controlled at molecular and nanoscale levels. This will give us the means to make structured nanoparticles with morphologies that had been regarded as unachievable, and that are the key to dispensing with harmful ingredients in paints.Read moreRead less
Pro-Fluorescent Aryl Nitroxides: New Probes for Polymer Lifetime and Kinetics Research. Internal aryl rings present in novel probes developed for this project impart fluorescence which is efficiently and internally quenched by the presence of a paramagnetic nitroxide group. Scavenging of radicals by the nitroxide however "switches on" the fluorescence and this enables powerful new fluorescence-based detection levels for the technique of nitroxide free radical scavenging. Such sensitivity is a ....Pro-Fluorescent Aryl Nitroxides: New Probes for Polymer Lifetime and Kinetics Research. Internal aryl rings present in novel probes developed for this project impart fluorescence which is efficiently and internally quenched by the presence of a paramagnetic nitroxide group. Scavenging of radicals by the nitroxide however "switches on" the fluorescence and this enables powerful new fluorescence-based detection levels for the technique of nitroxide free radical scavenging. Such sensitivity is applicable to polymerization kinetics studies, as well as providing new means for the determination of materials lifetimes. The development of pro-fluorescent markers as indicators for polymer degradation would be a significant outcome for materials where component failure has a major negative impact.Read moreRead less
Defining Polymer Structures in Radical Polymerization Systems: Chain Birth, Chain Growth and Complex Macromolecular Architectures. The project underpins and extends Australia's leading position in the development and application of novel methods to generate advanced polymeric materials. By carefully studying the reaction pathways underpinning the polymerization processes, an in-depth picture of the polymerization is obtained. The research outcomes will strongly benefit the preparation of the com ....Defining Polymer Structures in Radical Polymerization Systems: Chain Birth, Chain Growth and Complex Macromolecular Architectures. The project underpins and extends Australia's leading position in the development and application of novel methods to generate advanced polymeric materials. By carefully studying the reaction pathways underpinning the polymerization processes, an in-depth picture of the polymerization is obtained. The research outcomes will strongly benefit the preparation of the coming generations of intelligent polymer materials of a highly controlled structure, responsive to their environment, with an even broader range of applications than existing polymers. In addition, the project has a substantial educational component providing training embedded in cutting polymer science for several honours and 1 PhD student.Read moreRead less
Novel Coatings For Steel. The aim of this project is to design coatings for steel that have high flexibility and high resistance to scatching and hardness. This will be achieved by the introduction of liquid crystalline phases in the coatings. The outcome will be a new generation of steel coatings with novel properties
Characterization of star nanogels by advanced transmission electron microscopy. This project will provide an excellent opportunity to combine research expertise from The Polymer Science Group at The University of Melbourne and The Polymer Morphology Group at North Carolina State University (NCSU) to develop and characterize novel star nanogels with unique macromolecular architectures. The success of the project will reveal the absolute structures of these molecules and the proposed studies are b ....Characterization of star nanogels by advanced transmission electron microscopy. This project will provide an excellent opportunity to combine research expertise from The Polymer Science Group at The University of Melbourne and The Polymer Morphology Group at North Carolina State University (NCSU) to develop and characterize novel star nanogels with unique macromolecular architectures. The success of the project will reveal the absolute structures of these molecules and the proposed studies are both intellectually challenging in the cutting-edge of leading research in the field and important to provide vital information for the design of new structures of these new materials for their application in many areas, such as drug delivery, new membrane formation, advance high density memory chips and possibly the next generation of automotive coating.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0346891
Funder
Australian Research Council
Funding Amount
$200,000.00
Summary
Characterization facilities for new macromolecular architectures. The proposed facility is essential for characterization of the new polymeric architectures such as copolymers for tissue engineering, nanogels for automotive paints and biodegradable polymeric packaging. The facilities include characterizations of (1) molar mass and molecular sizes of novel polymer architectures (MU); (2) viscoelastic mechanical properties of tensile, bending, bulk and flow (RMIT); and (3) thermal properties of c ....Characterization facilities for new macromolecular architectures. The proposed facility is essential for characterization of the new polymeric architectures such as copolymers for tissue engineering, nanogels for automotive paints and biodegradable polymeric packaging. The facilities include characterizations of (1) molar mass and molecular sizes of novel polymer architectures (MU); (2) viscoelastic mechanical properties of tensile, bending, bulk and flow (RMIT); and (3) thermal properties of compositions (CSIRO). These new polymeric architectures cannot be sufficiently characterized by existing facilities. The success of the project will significantly enhance the new macromolecular research and facilitate collaborations. This project also falls within the nano and biomaterials of the Designated Priority area of Research.Read moreRead less