Cross-linking in free-radical polymerizations: kinetics and mechanical properties. Cross-linked polymer chains are joined together in a ?ladder? topology. This often occurs either deliberately or accidentally in industrial systems, and affects polymer properties. However, cross-linking mechanisms are poorly understood, and there are no general means of quantitatively controlling effects on mechanical properties. As a by-product from a previous IREX grant, a means was found to grow polymers with ....Cross-linking in free-radical polymerizations: kinetics and mechanical properties. Cross-linked polymer chains are joined together in a ?ladder? topology. This often occurs either deliberately or accidentally in industrial systems, and affects polymer properties. However, cross-linking mechanisms are poorly understood, and there are no general means of quantitatively controlling effects on mechanical properties. As a by-product from a previous IREX grant, a means was found to grow polymers with controlled cross-linking. This proposal exploits this method to synthesize polymers with different amounts of cross-linking, and to examine their formation mechanisms and mechanical properties. This has the potential of improving means of making rubber-based materials by polymer modification.Read moreRead less
Naturally derived photoinitiators for biocompatible 3D printing. This project aims to develop an environmentally-friendly approach to naturally derived photoinitiators which are applicable to 3D printing through low-energy, visible light-induced polymerisation, and explore their application in the fabrication of biocompatible polymeric materials. Traditional polymer manufacturing processes such as thermopolymerisation employ hazardous chemicals which present health and environmental risks. This ....Naturally derived photoinitiators for biocompatible 3D printing. This project aims to develop an environmentally-friendly approach to naturally derived photoinitiators which are applicable to 3D printing through low-energy, visible light-induced polymerisation, and explore their application in the fabrication of biocompatible polymeric materials. Traditional polymer manufacturing processes such as thermopolymerisation employ hazardous chemicals which present health and environmental risks. This project expects to expand fundamental scientific knowledge of photochemistry, polymer chemistry and biology through the development of a novel, economical, clean, commercially-relevant platform (3D printing) for the fabrication of polymeric materials.Read moreRead less
Mechanisms and modelling of gels for protein separation. Gradipore approached Sydney University to collaborate on fundamental science needed to improve polymer gels for separation and characterization of proteins. These gels have many applications: e.g. proteomics and diagnostics. Presently, control of polymer microstructure in the synthesis of these gels is by trial and error. This project will create an accurate model of the process so pore size can be predicted. This involves novel work in ex ....Mechanisms and modelling of gels for protein separation. Gradipore approached Sydney University to collaborate on fundamental science needed to improve polymer gels for separation and characterization of proteins. These gels have many applications: e.g. proteomics and diagnostics. Presently, control of polymer microstructure in the synthesis of these gels is by trial and error. This project will create an accurate model of the process so pore size can be predicted. This involves novel work in experimental and theoretical methods developed by the Sydney University group. The result will be qualitative and quantitative understanding which can be subsequently used to tailor-make gels for new applications.Read moreRead less
Multiblock copolymer synthesis for nano-engineered materials. This project aims to develop methodology for environmentally friendly and industrially applicable synthesis of new types of advanced polymeric materials comprising multiblock copolymers. Polymeric materials play an important role in society with applications from bulk plastics to advanced technological applications. This would enable the creation of advanced materials with specific engineering targets and applications ranging from nan ....Multiblock copolymer synthesis for nano-engineered materials. This project aims to develop methodology for environmentally friendly and industrially applicable synthesis of new types of advanced polymeric materials comprising multiblock copolymers. Polymeric materials play an important role in society with applications from bulk plastics to advanced technological applications. This would enable the creation of advanced materials with specific engineering targets and applications ranging from nanomedicine to materials science.Read moreRead less
Exploiting the self-assembly of hydrophobin proteins to engineer functional nanostructuring surfaces. There is an increasing world-wide demand for advanced nano-biomaterials with novel properties. We will use natural hydrophobin proteins to coat nanodevices and make them more compatible with biological systems. Hydrophobin coatings will be applicable to biosensors, medical devices, diagnostics and drug delivery systems. The research will lead to an understanding of the basic mechanisms of protei ....Exploiting the self-assembly of hydrophobin proteins to engineer functional nanostructuring surfaces. There is an increasing world-wide demand for advanced nano-biomaterials with novel properties. We will use natural hydrophobin proteins to coat nanodevices and make them more compatible with biological systems. Hydrophobin coatings will be applicable to biosensors, medical devices, diagnostics and drug delivery systems. The research will lead to an understanding of the basic mechanisms of protein self-assembly and will have application outcomes that contribute to Australia being an important player in the field of nanotechnology. This is critical for Australia's long term competitiveness and productivity in and beyond the 21st century.Read moreRead less
Smart polymer-DNA hybrids as recognition sites for advanced DNA nanotechnology applications. This project aims to design and synthesise a new family of DNA-conjugated chain transfer agents for the positional control of DNA in a broad range of 2D and 3D 'smart' polymer-DNA hybrid materials. These bioconjugated materials will be investigated to understand the fundamental self-assembly processes which underpin emerging dynamic DNA nanotechnologies. This timely research will revolutionise the use of ....Smart polymer-DNA hybrids as recognition sites for advanced DNA nanotechnology applications. This project aims to design and synthesise a new family of DNA-conjugated chain transfer agents for the positional control of DNA in a broad range of 2D and 3D 'smart' polymer-DNA hybrid materials. These bioconjugated materials will be investigated to understand the fundamental self-assembly processes which underpin emerging dynamic DNA nanotechnologies. This timely research will revolutionise the use of biologically inspired intelligent metamaterials for use in medical diagnostics, DNA computing and DNA nanomachines.Read moreRead less
Molecular archaeology: new knowledge from molecular weight distributions of synthetic and natural polymers. This project will lead to new understanding of how natural and synthetic polymers are formed. Examples are the enzymatic processes that produce the subtle architecture of rice grains, and the processes that pose problems for developing new techniques for making novel polymer-based materials. The fundamental scientific knowledge from this project will provide a platform for the future devel ....Molecular archaeology: new knowledge from molecular weight distributions of synthetic and natural polymers. This project will lead to new understanding of how natural and synthetic polymers are formed. Examples are the enzymatic processes that produce the subtle architecture of rice grains, and the processes that pose problems for developing new techniques for making novel polymer-based materials. The fundamental scientific knowledge from this project will provide a platform for the future development of improved materials, and for superior grain varieties for food and industrial use. These advances will be of significant benefit to Australian industry and consumers.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0347258
Funder
Australian Research Council
Funding Amount
$170,000.00
Summary
Polymer Analysis Facility. The aim of this application is to establish a facility for polymer analysis. The infra-red spectrometer will be used primarily for analysis of polymerisation reactions whilst the thermal analysis equipment is essential for the characterisation of polymers and thin polymer coatings. The facility will contribute an essential analysis capability for three strong research groups who work in different aspects of polymer science. The main outcomes will improved productivity ....Polymer Analysis Facility. The aim of this application is to establish a facility for polymer analysis. The infra-red spectrometer will be used primarily for analysis of polymerisation reactions whilst the thermal analysis equipment is essential for the characterisation of polymers and thin polymer coatings. The facility will contribute an essential analysis capability for three strong research groups who work in different aspects of polymer science. The main outcomes will improved productivity within the current projects together with new collaborations, particularly between the Steel Institute (ISPP) at Wollongong and the Centre of Advanced Molecular Design (CAMD) at UNSW.Read moreRead less
Manipulating the self-assembly properties of fungal hydrophobin proteins for the design of novel biological polymers. Hydrophobin-based products will be novel biocompatible and biodegradable products with applications in the fields of medical implants, biosensors, detergents, coatings and pharmaceutical and industrial emulsions. They have the potential to directly improve the lives of all Australians and to be of benefit to the Australian economy and environment. This collaborative research pro ....Manipulating the self-assembly properties of fungal hydrophobin proteins for the design of novel biological polymers. Hydrophobin-based products will be novel biocompatible and biodegradable products with applications in the fields of medical implants, biosensors, detergents, coatings and pharmaceutical and industrial emulsions. They have the potential to directly improve the lives of all Australians and to be of benefit to the Australian economy and environment. This collaborative research project will enable Australian scientists to gain from working with a multinational company and to acquire skills in the rapidly expanding fields of structural and molecular biology. The University of Sydney will own any intellectual property arising from this work and will benefit from the commercialisation of hydrophobin-based products.Read moreRead less
Highly Crosslinked Poly(urea-co-urethane) Copolymer Concrete Floor Coatings. Recently developed, poly(urea-co-urethane) concrete floor screeds are used, in the construction industry, to provide protection against corrosive chemicals and abrasive wear; properties unmatched by other commercial floor treatments. Significantly such material has reduced environmental emissions and toxicity hazards. Factors, which affect the cure and performance of poly(urea-co-urethane) flooring materials will now ....Highly Crosslinked Poly(urea-co-urethane) Copolymer Concrete Floor Coatings. Recently developed, poly(urea-co-urethane) concrete floor screeds are used, in the construction industry, to provide protection against corrosive chemicals and abrasive wear; properties unmatched by other commercial floor treatments. Significantly such material has reduced environmental emissions and toxicity hazards. Factors, which affect the cure and performance of poly(urea-co-urethane) flooring materials will now be studied, including the uncontrolled release of carbon dioxide, which results in sporadic blister formation, leading to the on-site product failures that have severely limited the product's commercial growth. Clear understanding of cure chemistry and adhesion will be established for the first, allowing for the products further development.Read moreRead less