Cooperativity in Spin Crossover Systems: Memory, Magnetism and Microporosity. Spin-crossover centres are a well known form of inorganic electronic switch for which variation of temperature, pressure and irradiation leads to a change in d-electron configuration and therefore changes to structure, colour and magnetism. Here we aim to synthesise and study a wide variety of new spin-crossover systems where cooperativitiy between centres, induced by careful supramolecular design, will lead to molecul ....Cooperativity in Spin Crossover Systems: Memory, Magnetism and Microporosity. Spin-crossover centres are a well known form of inorganic electronic switch for which variation of temperature, pressure and irradiation leads to a change in d-electron configuration and therefore changes to structure, colour and magnetism. Here we aim to synthesise and study a wide variety of new spin-crossover systems where cooperativitiy between centres, induced by careful supramolecular design, will lead to molecules and materials having memory retention, magnetic ordering and/or microporosity. The significance of these aims covers several fundamental questions in the science of electronic systems. We also identify a number of potential nanochemical switching applications for the unique systems proposed.Read moreRead less
Cooperativity in Spin-Crossover Systems: Memory, Magnetism and Microporosity. Spin-crossover centres are a well known form of inorganic electronic switch for which variation of temperature, pressure and irradiation leads to a change in d-electron configuration and therefore changes to structure, colour and magnetism. Here we aim to synthesise and study a wide variety of new spin-crossover systems where cooperativity between centres, induced by careful supramolecular design, will lead to molecule ....Cooperativity in Spin-Crossover Systems: Memory, Magnetism and Microporosity. Spin-crossover centres are a well known form of inorganic electronic switch for which variation of temperature, pressure and irradiation leads to a change in d-electron configuration and therefore changes to structure, colour and magnetism. Here we aim to synthesise and study a wide variety of new spin-crossover systems where cooperativity between centres, induced by careful supramolecular design, will lead to molecules and materials having memory retention, magnetic ordering and/or microporosity. The significance of these aims covers several fundamental questions in the science of electronic systems. We also identify a number of potential nanochemical switching applications for the unique systems proposed.Read moreRead less
Centre for Quantum Computer Technology. Development of a quantum computer (QC) for massively parallel computing is one of the major challenges in science and engineering this century. Since 2000 the Centre has achieved two major breakthroughs in this field: constructing the key functional element of a silicon solid-state QC; and co-inventing a scheme for efficient linear optics QC. The proposed CoE aims to align these two nationally co-ordinated research programs with the world's existing comput ....Centre for Quantum Computer Technology. Development of a quantum computer (QC) for massively parallel computing is one of the major challenges in science and engineering this century. Since 2000 the Centre has achieved two major breakthroughs in this field: constructing the key functional element of a silicon solid-state QC; and co-inventing a scheme for efficient linear optics QC. The proposed CoE aims to align these two nationally co-ordinated research programs with the world's existing computer and IT industries to realise a fault-tolerant multiple qubit quantum processor with integrated control and qubit chips, and develop a scaleable optical quantum processor providing significant economic benefit to Australia.Read moreRead less