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Nanocomposite Mesoporous Materials for Gas Separations of Environmental Significance. The management of greenhouse and other acid gas emissions is vital to a sustainable future of both the economy and the ecosystem. This project will develop novel nano-materials for gas separation by tethering organic functional groups to the surface of porous inorganic supports. These materials offer the promise of combining the high selectivity and high capacity of liquid phase absorption systems with the rapi ....Nanocomposite Mesoporous Materials for Gas Separations of Environmental Significance. The management of greenhouse and other acid gas emissions is vital to a sustainable future of both the economy and the ecosystem. This project will develop novel nano-materials for gas separation by tethering organic functional groups to the surface of porous inorganic supports. These materials offer the promise of combining the high selectivity and high capacity of liquid phase absorption systems with the rapid transport rates of gas-solid adsorption systems. Success would open up several new possibilities for reengineering gas separation systems based on the use of these materials in solution, as solid phase adsorbents (pressure swing adsorption) and/or as permeselective gas membranes.Read moreRead less
Design of adsorbents for kinetic separation of gases. The purpose of this project is to design, synthesise and test a new family of adsorbents for separation of gas mixtures of environmental and energy significance. The outcome will be a thorough understanding of diffusion in adsorbents and preparation of several candidate adsorbents with superior separation characteristics.
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0668449
Funder
Australian Research Council
Funding Amount
$158,000.00
Summary
Advanced Surface and Porosity Characterization Facility. Material properties and processing play a significant role in many Australian industries. The benefits of research with this infrastructure to the greater community lies in the technological development of superior materials and processes to support the continued development of these industries. In addition to technological advances, this will have economic benefits due to improved business market share and profitability in these industrie ....Advanced Surface and Porosity Characterization Facility. Material properties and processing play a significant role in many Australian industries. The benefits of research with this infrastructure to the greater community lies in the technological development of superior materials and processes to support the continued development of these industries. In addition to technological advances, this will have economic benefits due to improved business market share and profitability in these industries, as well as educational development through completion of high quality research higher degree students.Read moreRead less
TiO2 nanoparticle design and photocatalysis applications. The aim is to design nanosized TiO2 photocatalsysts with superior photoactivity using various synthesis paths. Nanosized TiO2 particles will be prepared using sol-gel, aerosol and plasma processing, their physical and chemical properties will be closely studied and their photocatalytic ability will be assessed. Such tailor-made photocatalysts have significant commercial potential value, as they would be highly suitable for the photooxidat ....TiO2 nanoparticle design and photocatalysis applications. The aim is to design nanosized TiO2 photocatalsysts with superior photoactivity using various synthesis paths. Nanosized TiO2 particles will be prepared using sol-gel, aerosol and plasma processing, their physical and chemical properties will be closely studied and their photocatalytic ability will be assessed. Such tailor-made photocatalysts have significant commercial potential value, as they would be highly suitable for the photooxidation of organic compounds and the photoreduction of metal ions in wastewaters. Findings from this work will pave the way for a "green" technology such as photocatalysis to become more efficient and hence a competitive alternative to conventional water treatment methods.Read moreRead less
From Nanostructured Catalysts to Process Innovation. The results of this research will help to advance the fundamental scientific understanding of industrially important chemical reactions and give clear leads as to how to improve them. In particular, new catalysts (i.e. agents that increase the speed and selectivity of chemical reactions) will be generated and the first steps towards process innovation will be taken, using high-throughput equipment unique in the Southern Hemisphere. These new c ....From Nanostructured Catalysts to Process Innovation. The results of this research will help to advance the fundamental scientific understanding of industrially important chemical reactions and give clear leads as to how to improve them. In particular, new catalysts (i.e. agents that increase the speed and selectivity of chemical reactions) will be generated and the first steps towards process innovation will be taken, using high-throughput equipment unique in the Southern Hemisphere. These new catalysts will be the basis for the design of new and/or improved industrial processes that will be ?greener?, safer, use fewer resources, produce less waste and are generally more efficient and effective. As a result the Australian chemicals industry will be more competitive.Read moreRead less
Molecular Recognition in Chiral Ionic Liquids as Basis for the Design and Synthesis of New Enantioselective Heterogeneous Catalysts and Membranes. Molecules that can exist as mirror images, each with different, e.g., beneficial vs. toxic properties, underpin the pharmaceutical industry and increasingly new highly selective pesticides, and flavours/fragrances.
Current commercial pathways often make mixtures of the mirror images that then need to be separated laboriously. These routes are ineffic ....Molecular Recognition in Chiral Ionic Liquids as Basis for the Design and Synthesis of New Enantioselective Heterogeneous Catalysts and Membranes. Molecules that can exist as mirror images, each with different, e.g., beneficial vs. toxic properties, underpin the pharmaceutical industry and increasingly new highly selective pesticides, and flavours/fragrances.
Current commercial pathways often make mixtures of the mirror images that then need to be separated laboriously. These routes are inefficient, creating waste and use resources poorly.
We aim to create solutions for these problems, using supported thin films of special, new types of salts that are liquid at room temperature, and which have other unusual chemical properties that make them ideally suited to enable efficient conversions.Read moreRead less
New Catalysed Routes to the Efficient Synthesis of Biologically Active Molecules. Enhancing the economic viability and the energy efficiency of chemical transformations is of fundamental importance in the chemicals industry, and is essential in the targeted production of drugs and fine chemicals for frontier technologies. By using multiple metal centres to simultaneously promote series of reaction steps in a single pot, this project will develop an innovative approach to efficient syntheses of b ....New Catalysed Routes to the Efficient Synthesis of Biologically Active Molecules. Enhancing the economic viability and the energy efficiency of chemical transformations is of fundamental importance in the chemicals industry, and is essential in the targeted production of drugs and fine chemicals for frontier technologies. By using multiple metal centres to simultaneously promote series of reaction steps in a single pot, this project will develop an innovative approach to efficient syntheses of biologically active molecules. The new methods and new catalysts for enhancing the synthesis of highly functionalised compounds will improve significantly the environmental impact of chemical processes by reducing the amount of chemicals required, and reducing waste and energy requirements.Read moreRead less
Development of Reactive Ionic Liquids for Future Industrial Applications in Australia. This project creates the opportunity for a consortium of leading scientists to develop reactive ionic liquids concepts to support Australian Chemistry. The aim is to radically improve materials and processes within the manufacturing, mining and building industries by paradigm shift in chemical methodology. This will be achieved through cooperation between the major Australian chemical company, Orica, and CSIRO ....Development of Reactive Ionic Liquids for Future Industrial Applications in Australia. This project creates the opportunity for a consortium of leading scientists to develop reactive ionic liquids concepts to support Australian Chemistry. The aim is to radically improve materials and processes within the manufacturing, mining and building industries by paradigm shift in chemical methodology. This will be achieved through cooperation between the major Australian chemical company, Orica, and CSIRO - CMIT, and two leading Australian Universities, Melbourne and Monash. The majority of the manufacturing and mining industries, which will benefit from this activity and as a result become more internationally competitive, are based in regional Victoria, NSW, Queensland, South Australia, and Western Australia. Read moreRead less
The mechanism of scale formation and inhibition in alkaline industrial process streams. Scaling, which reduces flow and heating efficiency, is a serious problem in single stream alumina Bayer plants. This project will potentially save the Australian alumina industry many tens of millions of dollars a year by the development of more effective on-line scale mitigation strategies based on the fundamental understanding of the processes involved.
Improved catalysts for liquid phase hydrocarbon oxidation. Hydrocarbon oxidation is the largest industrial catalytic application of molecular transition metal catalysts. Despite its widespread application, the cyclohexane oxidation process is inefficient as it operates at low conversions, with a requirement to continuously recycle large quantities of hydrocarbon feedstock. Because of the scale of the process, increasing the yield from 4.5% to even 6% (33% increase) would represent a drastic im ....Improved catalysts for liquid phase hydrocarbon oxidation. Hydrocarbon oxidation is the largest industrial catalytic application of molecular transition metal catalysts. Despite its widespread application, the cyclohexane oxidation process is inefficient as it operates at low conversions, with a requirement to continuously recycle large quantities of hydrocarbon feedstock. Because of the scale of the process, increasing the yield from 4.5% to even 6% (33% increase) would represent a drastic improvement, with flow-on economic and environmental effects. The proposal aims to combine novel modifiers into the structure of the catalysts, to effect this increase and develop cleaner, more efficient, catalysts.Read moreRead less