Environmentally benign polymer solar cells. The project aims to prepare polymer solar cells, by developing water-compatible conjugated materials for the active layer. This technology would be cost-efficient and not use environmentally harmful solvents. The project would achieve aqueous compatibility of these hydrophobic molecules through substitution and careful positioning of functional groups. Fabrication processes will be optimised to incorporate these materials into solar cells, with a focus ....Environmentally benign polymer solar cells. The project aims to prepare polymer solar cells, by developing water-compatible conjugated materials for the active layer. This technology would be cost-efficient and not use environmentally harmful solvents. The project would achieve aqueous compatibility of these hydrophobic molecules through substitution and careful positioning of functional groups. Fabrication processes will be optimised to incorporate these materials into solar cells, with a focus on controlling the morphology of the active material. Determining the relationships between conjugated molecular design and cell performance should provide a new direction in solar-cell technology.Read moreRead less
Active channel organic transistors. The objective of our project is to create the next generation of electronic transistors based upon organic semiconductors. Specifically, the project will create devices for use in applications such as low power lighting, chemical sensing and lasers.
Using anisotropic thermal expansion in organic semiconductor thin films. This project aims to capitalise upon the recent discovery of negative thermal expansion in high-performance organic semiconductor films. Certain molecules’ chemical structures have a planar conjugated core and flexible sidechains. When highly anisotropic thermal expansion occurs, the sidechains take up most of the thermal expansion. When a negative thermal expansion occurs, the pi-pi stacking distance decreases upon anneali ....Using anisotropic thermal expansion in organic semiconductor thin films. This project aims to capitalise upon the recent discovery of negative thermal expansion in high-performance organic semiconductor films. Certain molecules’ chemical structures have a planar conjugated core and flexible sidechains. When highly anisotropic thermal expansion occurs, the sidechains take up most of the thermal expansion. When a negative thermal expansion occurs, the pi-pi stacking distance decreases upon annealing. This effect has been linked with higher charge mobilities, and a tighter molecular packing is locked in upon cooling. The potential applications of these high performance organic semiconductors includes chemical/biosensors, electronic paper, and radio frequency identification cards.Read moreRead less
Improvement in Stress Corrosion Cracking Resistance of Stainless Steels in Environments Conducive to Localized Pitting Damage. Stress corrosion cracking (SCC) represents a serious threat to infrastructure exposed to chloride and caustic environments. The proposed project will characterize the chloride-SCC crack propagation parameters for a super duplex stainless steel, which is the material of construction for vessels for stripping vinyl chloride monomer in a PVC processing plant. Alarmingly hig ....Improvement in Stress Corrosion Cracking Resistance of Stainless Steels in Environments Conducive to Localized Pitting Damage. Stress corrosion cracking (SCC) represents a serious threat to infrastructure exposed to chloride and caustic environments. The proposed project will characterize the chloride-SCC crack propagation parameters for a super duplex stainless steel, which is the material of construction for vessels for stripping vinyl chloride monomer in a PVC processing plant. Alarmingly high numbers the welds (nearly 50%) in the vessel had suffered extensive pitting (which is a well-known SCC initiator) and SCC cracking. For the mitigation measures, the project will also investigate pitting and SCC susceptibility of weldments of alternative varieties of stainless steels, such as Zeron 100.Read moreRead less
Understanding nanostructure in lead-containing piezoceramics - the key to improved and environmentally-friendly materials. Lead-containing piezoelectric ceramics form the basis of multi-billion dollar industries, posing an increasingly serious environmental threat due to the toxicity of lead. By obtaining a detailed understanding of how their properties arise from their nanoscale structure and chemistry, our research will lead to improvements in existing materials and aid the quest for environme ....Understanding nanostructure in lead-containing piezoceramics - the key to improved and environmentally-friendly materials. Lead-containing piezoelectric ceramics form the basis of multi-billion dollar industries, posing an increasingly serious environmental threat due to the toxicity of lead. By obtaining a detailed understanding of how their properties arise from their nanoscale structure and chemistry, our research will lead to improvements in existing materials and aid the quest for environmentally-friendly alternatives. We will use a methodology for the elucidation of local structure and dynamics in which we are world leaders. The project will further enhance our standing in the field, provide excellent research training for students and early-career researchers and highlight the power and potential of Australia's new Synchrotron and OPAL research reactor.Read moreRead less
Magnetic liquid marbles: a new droplet manipulation technique for channel-free microfluidics. The project will explore the feasibility of developing a new droplet-manipulation strategy by using magnetically responsive liquid marbles capable of hosting various liquid droplets. It will significantly advance the development of a new generation of microfluidic devices: magnetic field-actuated channel-free droplet microfluidics.
Development of Deformation-Mechanism Based Parameters for Improved Design of Hard Coatings. The use of thin hard abrasion-resistant coatings is an important method for significantly improving the operational lifetime of components in a wide range of mechanical, biomedical and sensory applications. The optimal design of these coatings is however severely restricted by a lack of detailed knowledge of their material deformation mechanisms. The proposed project will use novel nano-indentation and el ....Development of Deformation-Mechanism Based Parameters for Improved Design of Hard Coatings. The use of thin hard abrasion-resistant coatings is an important method for significantly improving the operational lifetime of components in a wide range of mechanical, biomedical and sensory applications. The optimal design of these coatings is however severely restricted by a lack of detailed knowledge of their material deformation mechanisms. The proposed project will use novel nano-indentation and electron microscope techniques to create a basis for mechanism-based deformation models. These models will then be used to develop new coating architectures with improved operational lifetimes as well as predicting coating lifetimes and developing simple tools for coating assessment.Read moreRead less
Synthesis and processing of fine powders and nano-materials by electric discharge assisted milling under hot and cold plasmas. The discovery of a new materials synthesis and processing technique, called Electric Discharge Assisted Ball Milling, has generated great interest within the materials science community. Preliminary results, recently published in Nature, have demonstrated that mechanical milling using both hot and cold plasmas can result in extremely rapid synthesis of a wide range of ma ....Synthesis and processing of fine powders and nano-materials by electric discharge assisted milling under hot and cold plasmas. The discovery of a new materials synthesis and processing technique, called Electric Discharge Assisted Ball Milling, has generated great interest within the materials science community. Preliminary results, recently published in Nature, have demonstrated that mechanical milling using both hot and cold plasmas can result in extremely rapid synthesis of a wide range of materials. The fundamental mechanisms for this rapid mechano-synthesis method will be elucidated by detailed studies of a range of technologically important materials including, ultrafine, nanostructural and nanosized powders, carbides, nitrides and borides, and energy efficient high surface area products for hydrogen storage and electrode applications.Read moreRead less
Interplay of Microbiological Corrosion and Alloy Microstructure in Failures of Advanced Stainless Steels and their Weldments in Marine Environments. The proposed research program investigates the role of microbiologically-induced corrosion (MIC) on stress corrosion cracking (SCC) of weldments of advanced stainless steels (SS). Extensive premature SCC failures of SS weldments have lately become increasingly significant in Australian marine industry, following the inability of advanced SCC-resista ....Interplay of Microbiological Corrosion and Alloy Microstructure in Failures of Advanced Stainless Steels and their Weldments in Marine Environments. The proposed research program investigates the role of microbiologically-induced corrosion (MIC) on stress corrosion cracking (SCC) of weldments of advanced stainless steels (SS). Extensive premature SCC failures of SS weldments have lately become increasingly significant in Australian marine industry, following the inability of advanced SCC-resistant SS to alleviate failures. Inconsistencies in SCC data call for an improved understanding of the role of MIC on SCC, particularly because recent failure analyses have indicated a profound role of microbiological activity on localised corrosion (viz., pitting) of stainless steels and their weldments, as well as because pitting is known to facilitate SCC initiation.Read moreRead less
Bio-inspired electro catalysts for gas reduction reactions: towards electrochemical ammonia production under ambient conditions. This project will develop solutions to replace the current energy inefficient method for ammonia production, which are a significant contribution to Greenhouse Gas emissions. A more energy efficient system will be developed from a new class of composite gas-reduction catalysts integrated into functional electrochemical cells.