Life Extension of Equipment Suffering Environmentally-Assisted Cracking: An Innovative Approach to Mitigation by Engineering of Materials in Service. Environmentally-assisted cracking (EAC) represents a serious threat to infrastructure exposed to caustic and chloride environments in process, marine, energy and chemical industries in Australia. Despite extensive research, there is no consensus mechanism for EAC. This project will investigate a fresh approach to life extension of in-service equipm ....Life Extension of Equipment Suffering Environmentally-Assisted Cracking: An Innovative Approach to Mitigation by Engineering of Materials in Service. Environmentally-assisted cracking (EAC) represents a serious threat to infrastructure exposed to caustic and chloride environments in process, marine, energy and chemical industries in Australia. Despite extensive research, there is no consensus mechanism for EAC. This project will investigate a fresh approach to life extension of in-service equipment suffering EAC, by developing and testing a mitigation measure reasonably independent of the EAC mechanisms. The task includes development of a consolidated strategy based on: accurate determination of the fundamental parameters for crack propagation, and in-situ thermomechnical treatment for local manipulation of material at and ahead of crack-tip, in order to retard/stop crack propagation.Read moreRead less
Single walled carbon nanotubes of one stereochemistry - material for the oncoming carbon age. Carbon nanotubes are finding application in nanotechnology. However currently they are prepared as a mixture of zig-zag, chiral and armchair isomers. Their properties could be improved if they could be prepared with one stereochemistry. The approach here is to use a nanocrystallisation and thermal maturation process involving stereo controlling additives. The new carbons are expected to have outstandin ....Single walled carbon nanotubes of one stereochemistry - material for the oncoming carbon age. Carbon nanotubes are finding application in nanotechnology. However currently they are prepared as a mixture of zig-zag, chiral and armchair isomers. Their properties could be improved if they could be prepared with one stereochemistry. The approach here is to use a nanocrystallisation and thermal maturation process involving stereo controlling additives. The new carbons are expected to have outstanding flexibility and strength and novel thermal and electrical properties. The new products could give Australia a lead in new battery, hydrogen storage, flat screen technology and nanoelectronics.Read moreRead less
Nanostructured Degradable Polymer for Drug Delivery. The success of synthesising nanostructured degradable polymers will position Australia at the world forefront in the field of nanotechnology, bioengineering and healthcare sectors in both fundamental and applied research. This multi-disciplinary research has the potential to generate patentable technologies with economic benefits to Australia. The project also involves fundamental research into surface chemistry, nanostructure, polymer science ....Nanostructured Degradable Polymer for Drug Delivery. The success of synthesising nanostructured degradable polymers will position Australia at the world forefront in the field of nanotechnology, bioengineering and healthcare sectors in both fundamental and applied research. This multi-disciplinary research has the potential to generate patentable technologies with economic benefits to Australia. The project also involves fundamental research into surface chemistry, nanostructure, polymer sciences and will be a meaningful contribution to the advancement of scientific knowledge in Australia. All these will enhance the international competitive profile of Australia in the field of nanotechnology for drug delivery.Read moreRead less
Engineering models for inland atmospheric corrosion of steel infrastructure considering microbiological and environmental influences. Some 2-3% of Gross Domestic Product is estimated to be lost every year to corrosion and by measures to counteract it. Of this a significant proportion relates to steel infrastructure, which includes buildings, bridges, transmission towers, ships, offshore and coastal structures, tanks and pipelines. Better understanding and modelling of corrosion will improve our ....Engineering models for inland atmospheric corrosion of steel infrastructure considering microbiological and environmental influences. Some 2-3% of Gross Domestic Product is estimated to be lost every year to corrosion and by measures to counteract it. Of this a significant proportion relates to steel infrastructure, which includes buildings, bridges, transmission towers, ships, offshore and coastal structures, tanks and pipelines. Better understanding and modelling of corrosion will improve our capability for assessing the long-term safety and serviceability of infrastructure. It may also be useful in improving the composition of steel to resist rusting and in the formulation of protective coatings. This project will contribute to better understanding of the likely involvement of bacteria in the longer-term corrosion of steel exposed to various inland environments.Read moreRead less
Mathematical and mechanical modeling of nano particulate flow. Nano particulates are the basis for many new technologies, including coatings in the electronics industry, composite materials and medical and pharmaceutical applications. Worldwide industrial competition is increasingly determined by our capacity to handle such highly cohesive materials, and to exploit their novel physical, chemical and mechanical characteristics. Devising handling mechanisms and understanding nano particulate flows ....Mathematical and mechanical modeling of nano particulate flow. Nano particulates are the basis for many new technologies, including coatings in the electronics industry, composite materials and medical and pharmaceutical applications. Worldwide industrial competition is increasingly determined by our capacity to handle such highly cohesive materials, and to exploit their novel physical, chemical and mechanical characteristics. Devising handling mechanisms and understanding nano particulate flows depends on formulating accurate mathematical models which reflect the correct underlying physics. This APF proposal will utilise advanced continuum mechanics to develop the correct underlying conceptual ideas to resolve fundamental nanomechanical particulate flows, which will lead to the next generation of engineering tools.
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Designer Surfactants for Creation of Emulsion Properties. We propose new approaches to the design of surfactants for stabilising water in oil emulsions. New block copolymer surfactants may be "tailored" for head group structure and a pre-chosen hydrophilic/lipophilic balance at the oil-water interface using the Australian developed RAFT polymer synthesis method and polymeric inorganic species. The proposers have an extensive background in these areas.
X-ray and neutron scattering techniques, de ....Designer Surfactants for Creation of Emulsion Properties. We propose new approaches to the design of surfactants for stabilising water in oil emulsions. New block copolymer surfactants may be "tailored" for head group structure and a pre-chosen hydrophilic/lipophilic balance at the oil-water interface using the Australian developed RAFT polymer synthesis method and polymeric inorganic species. The proposers have an extensive background in these areas.
X-ray and neutron scattering techniques, developed by us, allow the interfacial structure of the surfactant to be found and the intellectual "loop" closed in the design process. Preliminary screening will be done using the surface balance and bulk emulsion synthesis.Read moreRead less
High Internal Phase Emulsions - Structure and Rheology Control. Our first SPIRT Grant with ORICA Australia Ltd has successfully identified nanostructures in high internal phase emulsions which confer useful stability and robustness on these industrially important systems. The aim now is to ramify those discoveries both scientifically and technologically in the design of emulsion structure using our, now established, techniques. In particular, the objective is to control both nanoscale and mes ....High Internal Phase Emulsions - Structure and Rheology Control. Our first SPIRT Grant with ORICA Australia Ltd has successfully identified nanostructures in high internal phase emulsions which confer useful stability and robustness on these industrially important systems. The aim now is to ramify those discoveries both scientifically and technologically in the design of emulsion structure using our, now established, techniques. In particular, the objective is to control both nanoscale and mesoscale structure in emulsion formulation, as well as the rheology and stability of emulsion preparations. To do this we plan to use mixed surfactant systems and to study intersurfactant synergic effects on the structure and fluidity of the interfacial material. We believe that the proposed work is unique and that the outcomes will be scientifically novel and also valuable for Australian industry.Read moreRead less
Milk protein denaturation and stabilisation at surfaces. The Australian Dairy Industry, valued at $2.8 billion in 2003-4, is ranked third among rural industries in Australia. Australia exports over 50% of its annual milk production, contributing to 13% of world trade. Exports of dairy products are valued at $2.4 billion. In order for Australia to maintain this position, Australia needs to keep up with its major competitors by ensuring quality and consistency of dairy products is maintained, and ....Milk protein denaturation and stabilisation at surfaces. The Australian Dairy Industry, valued at $2.8 billion in 2003-4, is ranked third among rural industries in Australia. Australia exports over 50% of its annual milk production, contributing to 13% of world trade. Exports of dairy products are valued at $2.4 billion. In order for Australia to maintain this position, Australia needs to keep up with its major competitors by ensuring quality and consistency of dairy products is maintained, and by developing new applications and innovative products. The proposal expects to recruit an exceptional young Australian graduate - a former Rhodes Scholar from Oxford University.Read moreRead less
Development of Reactive Ionic Liquids for Future Industrial Applications in Australia. This project creates the opportunity for a consortium of leading scientists to develop reactive ionic liquids concepts to support Australian Chemistry. The aim is to radically improve materials and processes within the manufacturing, mining and building industries by paradigm shift in chemical methodology. This will be achieved through cooperation between the major Australian chemical company, Orica, and CSIRO ....Development of Reactive Ionic Liquids for Future Industrial Applications in Australia. This project creates the opportunity for a consortium of leading scientists to develop reactive ionic liquids concepts to support Australian Chemistry. The aim is to radically improve materials and processes within the manufacturing, mining and building industries by paradigm shift in chemical methodology. This will be achieved through cooperation between the major Australian chemical company, Orica, and CSIRO - CMIT, and two leading Australian Universities, Melbourne and Monash. The majority of the manufacturing and mining industries, which will benefit from this activity and as a result become more internationally competitive, are based in regional Victoria, NSW, Queensland, South Australia, and Western Australia. Read moreRead less
Development and Use of Ionic Liquids in Metal Recovery from Ores, Concentrates and Mattes. Ionic liquids, which are liquid over a wide temperature range and can dissolve a wide range of solutes to high concentrations, promise new and yet unexplored approaches in processing ores. We aim to prepare ionic liquids and apply these to increase the intensity of copper and gold sulfide processing, and to explore more efficient separation of platinum group metals from mattes. New oxidative leaching techn ....Development and Use of Ionic Liquids in Metal Recovery from Ores, Concentrates and Mattes. Ionic liquids, which are liquid over a wide temperature range and can dissolve a wide range of solutes to high concentrations, promise new and yet unexplored approaches in processing ores. We aim to prepare ionic liquids and apply these to increase the intensity of copper and gold sulfide processing, and to explore more efficient separation of platinum group metals from mattes. New oxidative leaching techniques will be developed to diminish ore passivation and enhance recovery; high current electrowinning of copper in ionic liquids will be probed. Evolving technology should yield economic and environmental benefits for a nationally important industry.Read moreRead less