New reactivity from unusual main group compounds. This project will develop new, fundamentally important, yet unusual main group compounds and investigate their reactivity. The project will lead to important fundamental advance in main group chemistry and will form the basis for cheaper and cleaner future synthetic methodologies and technologies.
Synthesis, Synergy and Sustainability: Development of active-metal reagents. The design and realisation of new and important molecules requires innovative and efficient methods. This project will create a new store of active-metal molecular tools for the selective, catalytic and atom efficient construction of a diverse library of phosphorus heterocyclic scaffolds and chemical feedstocks relevant to biological, medicinal, and materials chemistry, and the fine chemical industry. Parallel studies e ....Synthesis, Synergy and Sustainability: Development of active-metal reagents. The design and realisation of new and important molecules requires innovative and efficient methods. This project will create a new store of active-metal molecular tools for the selective, catalytic and atom efficient construction of a diverse library of phosphorus heterocyclic scaffolds and chemical feedstocks relevant to biological, medicinal, and materials chemistry, and the fine chemical industry. Parallel studies employing environmentally friendly and benign deep eutectic solvents will allow for replacement of traditional hazardous volatile organic solvents, putting the newly created active-metal reagents at the forefront of the necessary shift towards a more sustainable and 'green' polar organometallic chemistry. Read moreRead less
Aluminium at the centre of sustainable catalysis. The project aims to establish new directions in the field of Lewis acid catalysis by creating a unique set of aluminium compounds. As catalysis is an important principle of green chemistry and as aluminium is the most abundant metal in the Earth's crust (i.e. sustainable), the project's aims are exceptionally well aligned with the society's targets to alleviate the negative effects of human activities on the environment. Expected outcomes of this ....Aluminium at the centre of sustainable catalysis. The project aims to establish new directions in the field of Lewis acid catalysis by creating a unique set of aluminium compounds. As catalysis is an important principle of green chemistry and as aluminium is the most abundant metal in the Earth's crust (i.e. sustainable), the project's aims are exceptionally well aligned with the society's targets to alleviate the negative effects of human activities on the environment. Expected outcomes of this project include significant advances related to industrially relevant processes, potentially degradable polymers and valorisation of the most prevalent greenhouse gas. Thus, the overall project should provide significant benefit to our collective efforts to mediate human impact on climate change.Read moreRead less
The systematic development of fundamentally important group 15 compounds: their applications to innovative industrial and environmental processes. The strong coordinating ability of organo-phosphorus/arsonic acids will be harnessed to support a series of metallic clusters that will be exploited for their use as magnetic materials in gas storage and as catalysts. The novel acids will be investigated for use as water soluble purification agents for, for example, mercury, uranium and lead.
Logarithmic conformal field theory and the 4D/2D correspondence. Conformal field theory provides powerful methods for attacking problems in theoretical physics and furnishes beautiful connections between seemingly disparate branches of pure mathematics. This proposal aims to greatly expand our knowledge of the logarithmic conformal field theories that have recently witnessed a resurgence of interest in physics. Advancing these theories is crucial to progress in high-energy physics and pure mathe ....Logarithmic conformal field theory and the 4D/2D correspondence. Conformal field theory provides powerful methods for attacking problems in theoretical physics and furnishes beautiful connections between seemingly disparate branches of pure mathematics. This proposal aims to greatly expand our knowledge of the logarithmic conformal field theories that have recently witnessed a resurgence of interest in physics. Advancing these theories is crucial to progress in high-energy physics and pure mathematics. Expected outcomes include a completely new understanding of the mathematical structure of these theories which will, in turn, facilitate applications in 4D gauge theory. This will boost research capacity and further cement Australia's reputation as an international leader in mathematical physics research.Read moreRead less
Structure of relations: algebra and applications. Relations and relational structures form the fundamental mathematical essence required for studying computational problems and computational systems. This project will provide new algebraic methods for solving old problems in the theory of relations, informing our understanding of computational complexity and the nature of computing.