Surface Processing of Photo-Sensitive Semiconducting Oxides for Solar-Hydrogen. Aim: To enhance the performance of titania-based semiconducting photo-electrodes for the generation of hydrogen from water using sunlight. Means: Engineering of the surface and near-surface layers so as to increase photo-sensitivity and reactivity with water. Significance: Success will provide the key functional component of photo-electrochemical cells for the mass production of renewable and clean hydrogen. In ....Surface Processing of Photo-Sensitive Semiconducting Oxides for Solar-Hydrogen. Aim: To enhance the performance of titania-based semiconducting photo-electrodes for the generation of hydrogen from water using sunlight. Means: Engineering of the surface and near-surface layers so as to increase photo-sensitivity and reactivity with water. Significance: Success will provide the key functional component of photo-electrochemical cells for the mass production of renewable and clean hydrogen. Innovation: For the first time, the properties controlling photo-sensitivity (defect disorder; charge transport; and chemically-induced, local, surface electric fields) will be modified. Outcomes: Technologies for the production of fuel (hydrogen) using renewable energy (solar energy) and a renewable resource (water).
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P-Type Titanium Dioxide for Hydrogen Generation from Water using Solar Energy. This project aims to develop a completely new processing technology for photo-sensitive oxide materials based on titanium dioxide for the conversion of renewable energy (solar energy) into chemical energy (hydrogen) or electrical energy (photovoltaic). When commercialised, the resultant technology will allow Australia to achieve the following: a) reduction in air pollution, b) reduction in greenhouse gas emissions, c) ....P-Type Titanium Dioxide for Hydrogen Generation from Water using Solar Energy. This project aims to develop a completely new processing technology for photo-sensitive oxide materials based on titanium dioxide for the conversion of renewable energy (solar energy) into chemical energy (hydrogen) or electrical energy (photovoltaic). When commercialised, the resultant technology will allow Australia to achieve the following: a) reduction in air pollution, b) reduction in greenhouse gas emissions, c) reduction in reliance on foreign energy sources, d) development of a range of ancillary technologies and infrastructure, and e) export of solar energy in the form of solar-hydrogen. This project addresses National Priorities #1 and #3.Read moreRead less
PROCESSING OF REDUCED-BAND-GAP TITANIA FOR SOLAR-HYDROGEN. The present project involves the development of materials and devices for solar-hydrogen using photo-assisted water decomposition. The research focusses on the processing of titanium dioxide (titania) with substantially enhanced photo-sensitivity and, consequently, increased efficiency of the conversion of solar energy into chemical energy (hydrogen) through imposition of the optimal Ti/O ratio. Significance: processing technology of tit ....PROCESSING OF REDUCED-BAND-GAP TITANIA FOR SOLAR-HYDROGEN. The present project involves the development of materials and devices for solar-hydrogen using photo-assisted water decomposition. The research focusses on the processing of titanium dioxide (titania) with substantially enhanced photo-sensitivity and, consequently, increased efficiency of the conversion of solar energy into chemical energy (hydrogen) through imposition of the optimal Ti/O ratio. Significance: processing technology of titania for photo-electrochemical devices for hydrogen generation and water decontamination. Innovation: processing of titania with reduced band-gap to be achieved through optimised oxygen nonstoichiometry. Outcome: processing technology of titania with outstanding photo-sensitivity.Read moreRead less
TITANIA-BASED MATERIALS WITH ENHANCED PHOTO-SENSITIVITY FOR SOLAR-HYDROGEN. Aims: Enhancement of the photo-sensitivity of titania photo-electrodes will be achieved through the effect of aliovalent ions in the titania lattice, leading to, at a high density of states, the imposition of mid-gap bands. This will result in the reduction of the effective band gap required for ionisation. Significance: The practical application of titania for the photolysis of water using solar energy at efficiencies s ....TITANIA-BASED MATERIALS WITH ENHANCED PHOTO-SENSITIVITY FOR SOLAR-HYDROGEN. Aims: Enhancement of the photo-sensitivity of titania photo-electrodes will be achieved through the effect of aliovalent ions in the titania lattice, leading to, at a high density of states, the imposition of mid-gap bands. This will result in the reduction of the effective band gap required for ionisation. Significance: The practical application of titania for the photolysis of water using solar energy at efficiencies sufficiently high for commercialisation (greater than 10%). Innovation: Examination for the first time of the impact of the electronic structure on the photo-sensitivity of oxide materials, including titania single crystals and polycrystals.Read moreRead less
Increase in Photocatalytic Activity of TiO2 through Intervalence Charge Transfer. Titanium dioxide (TiO2) has many proposed and realised applications in energy and the environment. The main problem that has hindered development and commercialisation of devices using TiO2 is its low photocatalytic activity, which results from its poor absorption of visible and infrared light. Most researchers modify the properties of TiO2 by conventional electrochemical methods to improve its performance but the ....Increase in Photocatalytic Activity of TiO2 through Intervalence Charge Transfer. Titanium dioxide (TiO2) has many proposed and realised applications in energy and the environment. The main problem that has hindered development and commercialisation of devices using TiO2 is its low photocatalytic activity, which results from its poor absorption of visible and infrared light. Most researchers modify the properties of TiO2 by conventional electrochemical methods to improve its performance but these attempts have been of limited success. The present research involves a completely new approach to the problem, which is based on the method used in the heat treatment of sapphire to improve its colour. This approach uses a phenomenon involving the modification of the optical properties to improve its absorption of light.Read moreRead less
Dislocation motion and anelastic recovery in layered ceramic titanate. This project aims to research deformation and facture in brittle ceramic nanowire materials and anelastic behaviour in tensile deformation. Layered sodium titanate is used in energy storage and water treatment, but in-situ tensile tests have observed unconventional deformation behaviour, with significant dislocation motion and anelastic recovery. This project will study the deformation mechanism in layered sodium titanate nan ....Dislocation motion and anelastic recovery in layered ceramic titanate. This project aims to research deformation and facture in brittle ceramic nanowire materials and anelastic behaviour in tensile deformation. Layered sodium titanate is used in energy storage and water treatment, but in-situ tensile tests have observed unconventional deformation behaviour, with significant dislocation motion and anelastic recovery. This project will study the deformation mechanism in layered sodium titanate nanowires through molecular dynamics simulations, empirical interatomic potential, and in situ TEM experiments. Expected outcomes include knowledge of the deformation mechanism of this layered titanate which can be broadened to technologically important layered ceramic materials.Read moreRead less
Development of new-generation autoclaved cellulose fibre-cement composites using alumina-silica rich industrial waste. Autoclaved cellulose fibre-cement (FC) composites are used for construction purposes globally. Alumina-silica rich industrial waste, such as fired clay bricks and tiles, are proven to be highly reactive under autoclaving conditions and are generated in abundance either during the production process or demolition of buildings worldwide. The project aims to utilise this renewable ....Development of new-generation autoclaved cellulose fibre-cement composites using alumina-silica rich industrial waste. Autoclaved cellulose fibre-cement (FC) composites are used for construction purposes globally. Alumina-silica rich industrial waste, such as fired clay bricks and tiles, are proven to be highly reactive under autoclaving conditions and are generated in abundance either during the production process or demolition of buildings worldwide. The project aims to utilise this renewable waste for the manufacture of improved FC products. The successful outcomes of the project could allow a new range of cost-effective building products which need less energy for their manufacture, to be realised for both developed and developing countries.Read moreRead less
Design of Non-Equilibrium Architectures: Leveraging High Entropy Materials. Novel metallic alloys, termed as ‘high entropy materials’, will be investigated as surface coatings in order to provide improved strength, corrosion and wear performance under extreme industrial environments. This new evolution in materials engineering is created by mixing at least 5 elements in equal ratios and has recently been proven to provide excellent functionality in the bulk form. The novelty of this project is t ....Design of Non-Equilibrium Architectures: Leveraging High Entropy Materials. Novel metallic alloys, termed as ‘high entropy materials’, will be investigated as surface coatings in order to provide improved strength, corrosion and wear performance under extreme industrial environments. This new evolution in materials engineering is created by mixing at least 5 elements in equal ratios and has recently been proven to provide excellent functionality in the bulk form. The novelty of this project is that thermal spray engineering will be employed to manufacture bespoke coatings for industries such as the mining and power generation sectors. We now need to understand the materials science for a technological tipping point that directly impacts manufacturing industries for improved performance, efficiency and reliability.Read moreRead less
Development of high-performance lead-free piezoelectric superlattices for environmentally-friendly and biocompatible piezoelectric micromachined ultrasonic transducers (pMUTs) applications. This program is aimed at development of environmentally friendly and biocompatible lead-free piezoelectric thin films and superlattices for the potential applications in pMUTs. The expected outcome includes deposition of BNT and BZT-based thin films and superlattices, and enhancement of their physical propert ....Development of high-performance lead-free piezoelectric superlattices for environmentally-friendly and biocompatible piezoelectric micromachined ultrasonic transducers (pMUTs) applications. This program is aimed at development of environmentally friendly and biocompatible lead-free piezoelectric thin films and superlattices for the potential applications in pMUTs. The expected outcome includes deposition of BNT and BZT-based thin films and superlattices, and enhancement of their physical properties by strain and interface engineering.Read moreRead less
New Generation Lead-free Piezoelectric Ceramics for Acoustic Sensor Technologies. Cooperative research between University of NSW and Thales Australia to design new Lead-free piezoceramics is of critical importance to Australia's strategic leadership in underwater acoustic technology. This area has been identified by the Department of Defence to be a critical defence capability and essential to Australia's exploration of oil, gas, and minerals. Improved and new transducer components will provide ....New Generation Lead-free Piezoelectric Ceramics for Acoustic Sensor Technologies. Cooperative research between University of NSW and Thales Australia to design new Lead-free piezoceramics is of critical importance to Australia's strategic leadership in underwater acoustic technology. This area has been identified by the Department of Defence to be a critical defence capability and essential to Australia's exploration of oil, gas, and minerals. Improved and new transducer components will provide significant economic benefit to Australia through increased export of sonar technology, particularly to Europe and all Restriction of Hazardous Substances (RoHS) compliant countries. The project will produce highly skilled graduates ensuring an on-going basis for Australia's future innovation in this area.Read moreRead less