Manufacturing Nanostructured Polymer Thin Films using Visible Light. This research aims the development of selective photochemical tools driven by different colours of light for the fabrication of nanostructured polymer brush thin films. By using different wavelengths to selectively activate specific chemical reactions, this will enable multiple reactions to be performed simultaneously, significantly streamlining fabrication. Additionally, the increased selectivity offers pathways to more sophis ....Manufacturing Nanostructured Polymer Thin Films using Visible Light. This research aims the development of selective photochemical tools driven by different colours of light for the fabrication of nanostructured polymer brush thin films. By using different wavelengths to selectively activate specific chemical reactions, this will enable multiple reactions to be performed simultaneously, significantly streamlining fabrication. Additionally, the increased selectivity offers pathways to more sophisticated nanoarchitectures in comparison to existing methods. This research will lead to the fabrication of 3D polymer brush architectures with unparalleled precision, which will be of high scientific and industrial value for a diverse range of applications, such as optoelectronics, nanoactuation, and sensing.Read moreRead less
Tuning catalyst reaction environments towards photoreforming of wastewater. This project aims to combine high-throughput computation and machine learning to screen photocatalysts more thoroughly for photoreforming of wastewater. The reaction environments effects on surface active units will be tailored for COx-emission-free selective organic synthesis with hydrogen production from organic-contained wastewater at ambient conditions. The project expects to expand our knowledge on the fast, reliabl ....Tuning catalyst reaction environments towards photoreforming of wastewater. This project aims to combine high-throughput computation and machine learning to screen photocatalysts more thoroughly for photoreforming of wastewater. The reaction environments effects on surface active units will be tailored for COx-emission-free selective organic synthesis with hydrogen production from organic-contained wastewater at ambient conditions. The project expects to expand our knowledge on the fast, reliable screening strategies, and the relationship between electric field (or lattice strain) and reaction pathways. This project will develop a photoreforming system for selective co-production of organics and hydrogen from wastewater, benefiting sustainable technologies development for chemical synthesis and hydrogen economy.Read moreRead less
Enhanced Synthetic Efficiency For Molecular Complexity and Diversity. This project aims to introduce new, broad-spectrum strategies that permit more efficient and selective ways to access complex organic molecules. The approach involves maximising the molecule-building potential of some of the smallest accessible molecular building blocks. Significant outcomes expected from this work include much shorter chemical syntheses of important organic substances and much improved, broad scope synthetic ....Enhanced Synthetic Efficiency For Molecular Complexity and Diversity. This project aims to introduce new, broad-spectrum strategies that permit more efficient and selective ways to access complex organic molecules. The approach involves maximising the molecule-building potential of some of the smallest accessible molecular building blocks. Significant outcomes expected from this work include much shorter chemical syntheses of important organic substances and much improved, broad scope synthetic methods. The concepts introduced by this work aims to benefit industry and manufacturing by introducing more efficient methods for fine chemical manufacture, while simultaneously lowering energy use and producing less waste.Read moreRead less
Multi-Bond-Forming Processes: Step-Economical Synthesis In Batch And Flow. This project aims to develop better ways to make and understand organic substances: the materials that make up all known life forms, our medicines, and many designed materials. Based on the previous development of powerful multi-bond-forming processes, the purpose of this project is to develop cascade sequences involving dendralenes in new and innovative ways. The project plans to generalise these processes and apply them ....Multi-Bond-Forming Processes: Step-Economical Synthesis In Batch And Flow. This project aims to develop better ways to make and understand organic substances: the materials that make up all known life forms, our medicines, and many designed materials. Based on the previous development of powerful multi-bond-forming processes, the purpose of this project is to develop cascade sequences involving dendralenes in new and innovative ways. The project plans to generalise these processes and apply them in short total syntheses; extend the boundaries of multi-bond-forming processes and break new records; and reach higher levels of synthetic efficiency and selectivity by introducing the latest flow chemistry and automated reaction optimisation technology.Read moreRead less
High activity catalysts for CO2 recycling to valuable chemical products. This proposal targets the development of novel porous solid catalysts, containing highly dispersed metal clusters that provide exceptional activity for the conversion (recycling) of carbon dioxide to fuels and other higher value chemical products. These novel materials will improve the productivity and/or reduce the energy required to facilitate the CO2 conversion, thereby reducing costs for industry, whilst also providing ....High activity catalysts for CO2 recycling to valuable chemical products. This proposal targets the development of novel porous solid catalysts, containing highly dispersed metal clusters that provide exceptional activity for the conversion (recycling) of carbon dioxide to fuels and other higher value chemical products. These novel materials will improve the productivity and/or reduce the energy required to facilitate the CO2 conversion, thereby reducing costs for industry, whilst also providing environmental benefit by carbon dioxide utilisation.Read moreRead less
New Horizons in Quinonedimethide Chemistry. Quinonedimethides (QDMs) are organic molecules with a notorious reputation for instability, hence they are poorly understood and an underexploited resource. This project will unite the ideally suited computational and experimental skills of the CIs to perform the first thorough investigation into fundamental QDM chemistry. It aims to map structure-reactivity in QDMs, investigate their ability to rapidly generate complex structures, and demonstrate thei ....New Horizons in Quinonedimethide Chemistry. Quinonedimethides (QDMs) are organic molecules with a notorious reputation for instability, hence they are poorly understood and an underexploited resource. This project will unite the ideally suited computational and experimental skills of the CIs to perform the first thorough investigation into fundamental QDM chemistry. It aims to map structure-reactivity in QDMs, investigate their ability to rapidly generate complex structures, and demonstrate their potential in spintronics and other applications. Anticipated outcomes include powerful and general new synthetic concepts, methods, strategies and tactics. This should provide significant benefits, such as better ways to manufacture important medicines and other materials.Read moreRead less
Porous transparent conducting oxides for efficient solar fuel production. This project aims to develop highly porous, transparent and electrically conducting networks of oxide nanoparticles for artificial photosynthesis applications. The majority of hydrogen is currently produced via natural gas reforming, a process that generates a significant carbon footprint due to the use of fossil fuels. This project will develop novel materials and fabrication methods to improve the efficiency of hydrogen ....Porous transparent conducting oxides for efficient solar fuel production. This project aims to develop highly porous, transparent and electrically conducting networks of oxide nanoparticles for artificial photosynthesis applications. The majority of hydrogen is currently produced via natural gas reforming, a process that generates a significant carbon footprint due to the use of fossil fuels. This project will develop novel materials and fabrication methods to improve the efficiency of hydrogen production using clean and renewable solar energy. This project will contribute to development of technologies for the chemical storage of renewable energy, and reduction of carbon dioxide emissions. This will have applications in the areas of optoelectronic devices, medical biosensors, and photocatalysis, offering downstream benefits for the society, the economy and the environment.Read moreRead less
Locally structured polar-photofunctional materials for energy conversion. This project aims to develop a novel method to engineer local chemical structures for achieving the polarity in narrow bandgap oxides via advanced thin-film growth and ion beam irradiation techniques. The developed new polar-photofunctional materials will significantly improve opto-electro-mechanical coupling and energy conversion, facilitating uses in renewable energy harvesting and smart optomechanical devices. The proje ....Locally structured polar-photofunctional materials for energy conversion. This project aims to develop a novel method to engineer local chemical structures for achieving the polarity in narrow bandgap oxides via advanced thin-film growth and ion beam irradiation techniques. The developed new polar-photofunctional materials will significantly improve opto-electro-mechanical coupling and energy conversion, facilitating uses in renewable energy harvesting and smart optomechanical devices. The project expects to advance material science through a new concept and innovative methodology, achieve properties forbidden/limited by conventional strategies and expand candidate pools for new generation multifunctional materials, significantly advancing Australia’s capacity in advanced manufacturing and industry.Read moreRead less
A new energy absorption system for brain injury mitigation. This research aims to propose and investigate a next generation high-energy absorbing helmet pad that will protect the Australian Defence Force soldiers against both ballistic and blast threats. New fundamental knowledge in the area of high-energy absorbing metamaterials will be obtained by using numerical modelling and experimental studies. The expected outcomes of the project include the development of a new wearable energy absorbing ....A new energy absorption system for brain injury mitigation. This research aims to propose and investigate a next generation high-energy absorbing helmet pad that will protect the Australian Defence Force soldiers against both ballistic and blast threats. New fundamental knowledge in the area of high-energy absorbing metamaterials will be obtained by using numerical modelling and experimental studies. The expected outcomes of the project include the development of a new wearable energy absorbing pad which can be used as the next generation combat helmet liners and accessories. The novel high-performance energy absorption system will have a wide range of direct applications in future personal armour, as well as sports gears and elderly healthcare products.Read moreRead less
Fast Precision Robust Control of Resonant Flexible Systems. The project aims to produce new control system design tools to enable fast precision control of advanced engineering systems encorporating flexible structures. This should enable improved speed and accuracy in control systems for precision instruments such as atomic force microscopes along with improving control system performance in areas of precision engineering such as semiconductor manufacturing, robotics and microelectromechanical ....Fast Precision Robust Control of Resonant Flexible Systems. The project aims to produce new control system design tools to enable fast precision control of advanced engineering systems encorporating flexible structures. This should enable improved speed and accuracy in control systems for precision instruments such as atomic force microscopes along with improving control system performance in areas of precision engineering such as semiconductor manufacturing, robotics and microelectromechanical systems. The outcomes are expected to be new control system synthesis and modelling tools enabling fast and highly accurate control of industrial systems using nonlinear and switching elements and achieving high levels of robustness. This will benefit Australian precision manufacturing industries.Read moreRead less