Improved Nanoscale and Molecular Models for Nanostructured Carbons, and their Applications in Simulation of Confined Fluids. This project has a multitude of benefits for Australia, a key one of which is the promotion of cross-disciplinary interaction and collaboration to conduct leading edge research in a technologically important area. In addition the project will utilize two PhD students who will be trained in research, and gain a broad range of skills in this multifaceted project involving t ....Improved Nanoscale and Molecular Models for Nanostructured Carbons, and their Applications in Simulation of Confined Fluids. This project has a multitude of benefits for Australia, a key one of which is the promotion of cross-disciplinary interaction and collaboration to conduct leading edge research in a technologically important area. In addition the project will utilize two PhD students who will be trained in research, and gain a broad range of skills in this multifaceted project involving theory, simulation and experiment. The research, grounded in molecular fundamentals, will also lead to the development of advanced tools for adsorption process modelling, useful in process design and scale-up, and contribute to Goal 1 of National Priority Area 3: Frontier Technologies for Building and Transforming Australian Industries.Read moreRead less
Force Interactions in Packed and Fluidised Beds at Micro-Scale Operation. Industrial processing in the 20th century was about increasing size to gain benefit from economies of scale. This century, the focus is on micro devices like lab-on-a-chip and high speed computer processors that deliver their product directly to the consumer. There are significant obstacles facing this new technology. Mixing is reduced due to laminar flow, and a large amount of energy is needed to move the fluid through su ....Force Interactions in Packed and Fluidised Beds at Micro-Scale Operation. Industrial processing in the 20th century was about increasing size to gain benefit from economies of scale. This century, the focus is on micro devices like lab-on-a-chip and high speed computer processors that deliver their product directly to the consumer. There are significant obstacles facing this new technology. Mixing is reduced due to laminar flow, and a large amount of energy is needed to move the fluid through such small devices. Particles are often added to improve mixing and heat transfer, but their presence adds to the energy requirements. This study will help us overcome these challenges. Read moreRead less
The flow properties of proteins and other biopolymers. The living cell is an extraordinary organization with a vast variety of biomacromolecules carrying out myriads of functions with great specificity and accuracy. The key issue in cell biology is to unravel the structures of biopolymers and the deep connection that exists between structure and function. This interdisciplinary research program combines recent advances in experimental and theoretical rheology, with advances in protein science, t ....The flow properties of proteins and other biopolymers. The living cell is an extraordinary organization with a vast variety of biomacromolecules carrying out myriads of functions with great specificity and accuracy. The key issue in cell biology is to unravel the structures of biopolymers and the deep connection that exists between structure and function. This interdisciplinary research program combines recent advances in experimental and theoretical rheology, with advances in protein science, to investigate the response of biopolymers to deformation. This approach will lead to insights into the problem of protein folding, the interaction of biopolymers with surfaces, and the physical basis for the mechanical properties of biopolymers.Read moreRead less
Reactions of Coordinated Dinitrogen. The program will develop novel metal-based catalysts and reagents that will transform nitrogen gas into ammonia and other nitrogen-containing compounds (nitrogen fixation). This fundamental chemical transformation underpins major chemical industries and this new approach using organometallic catalysts will significantly improve the efficiency of ammonia production and reduce the energy and harsh reaction conditions currently required. This program will desi ....Reactions of Coordinated Dinitrogen. The program will develop novel metal-based catalysts and reagents that will transform nitrogen gas into ammonia and other nitrogen-containing compounds (nitrogen fixation). This fundamental chemical transformation underpins major chemical industries and this new approach using organometallic catalysts will significantly improve the efficiency of ammonia production and reduce the energy and harsh reaction conditions currently required. This program will design catalysts with multiple complementary metal centres tailored to bind and activate nitrogen gas to facilitate its reaction with hydrogen or other reagents.Read moreRead less
Drag Force on Bubbles and Particles in Turbulent Flows. Australian exports are dominated by the minerals, metallurgical and chemicals industries, with minerals exports worth at least $40 billion annually. Many of the production processes are underpinned by the complex interaction between particles, bubbles and liquids. It is important that we understand the complex interactions taking place. This will enable us to improve existing operations and also to design completely new technologies, especi ....Drag Force on Bubbles and Particles in Turbulent Flows. Australian exports are dominated by the minerals, metallurgical and chemicals industries, with minerals exports worth at least $40 billion annually. Many of the production processes are underpinned by the complex interaction between particles, bubbles and liquids. It is important that we understand the complex interactions taking place. This will enable us to improve existing operations and also to design completely new technologies, especially in the emerging fields of nano and biotechnology. This project is important because it adds to our knowledge in the national priority area of Transforming Australian Industries, and its success will ensure that our industries remain at the forefront of innovation and are globally competitive. Read moreRead less
Design and synthesis of novel lanthanoid complexes for the fabrication of light emitting devices. There is a huge and still growing economy centred around the design and fabrication of low-cost Light Emitting Devices (LEDs), as demonstrated by the excess of US$1.3 billion invested in this field between 2000 and 2007. Nations focused on the production of new and more efficient materials will be at the forefront of these emerging technologies. The major thrust of this proposal, the design and prep ....Design and synthesis of novel lanthanoid complexes for the fabrication of light emitting devices. There is a huge and still growing economy centred around the design and fabrication of low-cost Light Emitting Devices (LEDs), as demonstrated by the excess of US$1.3 billion invested in this field between 2000 and 2007. Nations focused on the production of new and more efficient materials will be at the forefront of these emerging technologies. The major thrust of this proposal, the design and preparation of luminescent rare earths complexes, and their use for the fabrication of LEDS, represent a good opportunity for Australia to access this growing market. Read moreRead less
Atmospheric CO2, global temperature, and surface ocean acidity response to fossil carbon burning - insights from an ancient analogue. Sequestration of anthropogenic CO2 emissions by the oceans and the impacts of resulting ocean acidification and greenhouse warming upon marine ecosystems are vital to understanding the course of future environmental change. This research will improve knowledge of the biological and chemical responses in the ocean to past changes in atmospheric CO2 levels and incre ....Atmospheric CO2, global temperature, and surface ocean acidity response to fossil carbon burning - insights from an ancient analogue. Sequestration of anthropogenic CO2 emissions by the oceans and the impacts of resulting ocean acidification and greenhouse warming upon marine ecosystems are vital to understanding the course of future environmental change. This research will improve knowledge of the biological and chemical responses in the ocean to past changes in atmospheric CO2 levels and increased ocean acidity. This will assist in predicting the consequences of different fossil fuel burning scenarios for climate and marine life, especially the future viability of organisms like corals, molluscs, and calcareous plankton that underpin key tourism and marine production systems.Read moreRead less
Friction-based modelling of the dynamics of nanoconfined fluid mixtures. This project will transform the molecular science of fluid transport in nanoconfined spaces by delivering a tool that will be critical to the development of emerging nanotechnologies. The tool will embed a novel theory in a framework for modelling transport over all scales from nano- to macroscopic. The project will have strong benefits for the advancement of leading-edge fundamental research and in its relevance to a numbe ....Friction-based modelling of the dynamics of nanoconfined fluid mixtures. This project will transform the molecular science of fluid transport in nanoconfined spaces by delivering a tool that will be critical to the development of emerging nanotechnologies. The tool will embed a novel theory in a framework for modelling transport over all scales from nano- to macroscopic. The project will have strong benefits for the advancement of leading-edge fundamental research and in its relevance to a number of novel nanotechnologies. It will be particularly relevant to scientific and industrial developments exploiting new nanomaterials such as AlPO4-25, carbon molecular sieves and carbon nanotubes, as well as in nanofluidics.Read moreRead less
Iron in the Antarctic sea ice zone and its role in the past and future climate. The Antarctic sea ice environment has remained poorly investigated for decades as it is difficult to access. Recent scientific advances have revealed that melting sea ice may provide a significant amount of the plant micro-nutrient iron to the Southern Ocean. Given that polar waters are iron-deficient and seasonal sea ice affects ~14 million square kilometres of ocean, the importance of iron fertilisation from deca ....Iron in the Antarctic sea ice zone and its role in the past and future climate. The Antarctic sea ice environment has remained poorly investigated for decades as it is difficult to access. Recent scientific advances have revealed that melting sea ice may provide a significant amount of the plant micro-nutrient iron to the Southern Ocean. Given that polar waters are iron-deficient and seasonal sea ice affects ~14 million square kilometres of ocean, the importance of iron fertilisation from decaying sea ice and its effect on global climate urgently need to be evaluated. This proposal aims at improving our understanding of Earth's complex system, and will inform future climate change policy in Australia.
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Transport Processes in Flexible Porous Materials for Gas Separation and Storage. This project seeks to understand the mechanisms of transport processes in flexible porous materials, which have great potential in gas separation and storage. Coal and natural gas are important to the Australian economy, and the potential applications of flexible porous materials, such as air separation and hydrogen storage, are crucial for Australia to use coal and natural gas cleanly. The analysis method to be dev ....Transport Processes in Flexible Porous Materials for Gas Separation and Storage. This project seeks to understand the mechanisms of transport processes in flexible porous materials, which have great potential in gas separation and storage. Coal and natural gas are important to the Australian economy, and the potential applications of flexible porous materials, such as air separation and hydrogen storage, are crucial for Australia to use coal and natural gas cleanly. The analysis method to be developed is useful not only to gas separation and storage, but also to hydrogeology and soil science in Australia.Read moreRead less