New Synthetic Routes to the Immobilisation of Mixed Valence Transition Metal Complexes on Conducting Metal Oxides. Highly coloured, electrochemically active transition metal dyes may find application electrochromic devices, where they may switch between contrasting coloured forms through a simple redox reaction. A prerequisite is that the dye be immobilised onto a solid conducting support whilst preserving the electrochemical and optical properties of the dye found in solution. This project tack ....New Synthetic Routes to the Immobilisation of Mixed Valence Transition Metal Complexes on Conducting Metal Oxides. Highly coloured, electrochemically active transition metal dyes may find application electrochromic devices, where they may switch between contrasting coloured forms through a simple redox reaction. A prerequisite is that the dye be immobilised onto a solid conducting support whilst preserving the electrochemical and optical properties of the dye found in solution. This project tackles this problem through a combination of organic and inorganic synthesis to develop new electrochromic dyes that may be attached to mesoporous titania.Read moreRead less
Special Research Initiatives - Grant ID: SR180200015
Funder
Australian Research Council
Funding Amount
$589,007.00
Summary
Combination of electrochemistry with sono to destroy and detoxify PFAS. Previously the major means of dealing with per- and poly-fluoroalkyl substances (PFAS) is by adsorption, to collect and remove PFAS from contaminated sites. However, PFAS still exist, non-degraded and waiting for destruction. Targeting slurry waste from current remediation / adsorption plants, this project aims to efficiently degrade PFAS by combining electrochemical oxidation with sono-chemistry to enhance degradation capac ....Combination of electrochemistry with sono to destroy and detoxify PFAS. Previously the major means of dealing with per- and poly-fluoroalkyl substances (PFAS) is by adsorption, to collect and remove PFAS from contaminated sites. However, PFAS still exist, non-degraded and waiting for destruction. Targeting slurry waste from current remediation / adsorption plants, this project aims to efficiently degrade PFAS by combining electrochemical oxidation with sono-chemistry to enhance degradation capacity, to accelerate PFAS desorption / transportation from slurry waste, to avoid electrode fouling and to detoxify PFAS. The expected outcome of this project is to clean up contaminated sites, including PFAS / precursors and other persistent organic pollutants, leading to significant environmental benefits.Read moreRead less